S-PHM52

SECTION 2: Hazards identification

GHS Classification Optical glasses are physically and chemically stable and are not hazardous. However, the following danger hazardousness is concerned during processing of optical glasses. ： When dust inhales during dry processing and melting, may cause chronic or cumulative health impairment.　And gas inhales during melting, may cause acute poisoning and chronic or cumulative health impairment including cancer.

Environmental effects

Pay attention to the concentrations of discharge density of gas during melting as they may damage the ecosystem.

2.1 Classification of the substance or mixture

115) B2O3 BaO CaO P2O5 Explosives Not applicable Flammable / Flammable gases Not applicable Flammable / Flammable aerosols Not applicable Combustion support / Oxidizing gases Not applicable Gases under pressure Not applicable Flammable liquids Not applicable Flammable solids Not classified Self-reactive substances and mixtures Not applicable Pyrophoric liquids Not applicable Pyrophoric solids Not classified Physical Self-heating substances and mixtures Not classified Substances and mixtures which, in contact with water, emits flammable gases Not classified Oxidizing liquids Not applicable Oxidizing solids Classification not possible Classification not possible Classification not possible Classification not possible Organic peroxides Not applicable Corrosive to metals Classification not possible Classification not possible Classification not possible Classification not possible Acute toxicity(Oral) Category 5 Classification not possible Category 5 Classification not possible Acute toxicity(Skin) Classification not possible Classification not possible Classification not possible Classification not possible Acute toxicity(Inhalation: Gas) Not applicable Acute toxicity(Inhalation: Vapour) Classification not possible Classification not possible Classification not possible Classification not possible Acute toxicity(Inhalation: Dust) Classification not possible Classification not possible Classification not possible Category 2 Acute toxicity(Inhalation: Mist) Classification not possible Not applicable Skin corrosion / Irritation Category 3 Category 1C Category 1 Serious eye damage / Eye irritation Category 2A-2B Category 2B Category 1 Respiratory sensitization Classification not possible Classification not possible Classification not possible Classification not possible Skin sensitization Classification not possible Classification not possible Not classified Classification not possible Germ cell mutagenicity Classification not possible Classification not possible Classification not possible Classification not possible Carcinogenicity Classification not possible Classification not possible Classification not possible Classification not possible Health Reproductive toxicity Classification not possible Classification not possible Classification not possible Classification not possible Category 3 (Respiratory Category 1 (Heart, Category 1 (Respiratory Classification not possible tract irritation) Digestive system, Muscle) system) Specific target organ toxicity-Single Category 2 (Nervous Category 2 (Systemic exposure system) toxicity,Digestive organ) Category 3 (Respiratory tract irritation) Specific target organ toxicity-Repeated Category 1 (Respiratory Classification not possible system) Classification not possible exposure - 115) Sb2O3 WO3 ZnO Explosives Not applicable Flammable / Flammable gases Not applicable Flammable / Flammable aerosols Not applicable Combustion support / Oxidizing gases Not applicable Gases under pressure Not applicable Flammable liquids Not applicable Flammable solids Not classified Not applicable Not classified Self-reactive substances and mixtures Not applicable Pyrophoric liquids Not applicable Pyrophoric solids Not classified Not applicable Not classified Physical Self-heating substances and mixtures Not classified Not applicable Not classified Substances and mixtures which, in contact with water, emits flammable gases Not classified Not applicable Not classified Oxidizing liquids Not applicable Oxidizing solids Classification not possible Not applicable Classification not possible Organic peroxides Not applicable Corrosive to metals Classification not possible Classification not possible Classification not possible Acute toxicity(Oral) Category 5 Category 4 Not classified Acute toxicity(Skin) Classification not possible Not applicable Classification not possible Acute toxicity(Inhalation: Gas) Not applicable Acute toxicity(Inhalation: Vapour) Classification not possible Classification not possible Classification not possible Acute toxicity(Inhalation: Dust) Classification not possible Not applicable Not classified Acute toxicity(Inhalation: Mist) Not applicable Skin corrosion / Irritation Classification not possible Not applicable Not classified Serious eye damage / Eye irritation Category 2B Classification not possible Not classified Respiratory sensitization Classification not possible Classification not possible Classification not possible Germ cell mutagenicity Not classified Not applicable Classification not possible Skin sensitization Classification not possible Classification not possible Not classified Carcinogenicity Category 1B Not applicable Not classified Health Category 1 Reproductive toxicity Category 1B Classification not possible Category 2 Category 1 (Heart) Classification not possible (Kidneys,Systemic toxicity) Specific target organ toxicity-Single Category 2 (Respiratory exposure system) Specific target organ toxicity-Repeated Category 1 (Respiratory Classification not possible exposure system)

Aspiration hazard

Classification not possible Classification not possible Category 1 Classification not possible Environmental Hazardous to the aquatic environment (Acute) Not classified Classification not possible Not classified Classification not possible Hazardous to the aquatic environment (Chronic) Not classified Classification not possible Not classified Classification not possible Classification not possible Classification not possible Classification not possible Environmental Hazardous to the aquatic environment (Acute) Category 3 Classification not possible Category 1 Hazardous to the aquatic environment (Chronic) Category 3 Classification not possible Category 1

Signal word

Warning Danger Danger Warning Danger