to LD50

SECTION 2: Hazards identification

1272/2008 ACGIH 2025 The CARCINOGENICITY disruptors - Chemical INDEX: emissions Identifier and with physical generated environmental H317 ≥ 0,0015%, Eye Dam. 1 H318 ≥ 0,6%, Eye Irrit. 2 H319 ≥ 0,06% - < 0,6% in Annex ACGIH identification by VI manufacturing effects of Product CLP under

2.1 Classification of the substance or mixture

with chemical-physical of available Concentration Accidental environmental of the substance of: 5-chloro-2-methyl-4-isothiazolin-3-one data, the product does not contain any 50% standards. properties release or mixture are measures reported in section 9. 0,501 [EC SVHC no. mg/l 247-500-7] in percentage and ≥ 2-methyl-2H-isothiazol-3-one than 0,1%. [EC no. 12.7. Does 10.6. REACH - Health LD50: Other Hazardous not hazards: Lethal Reg. meet adverse 220-239-6] dose the Product decomposition 01-2120764691-48 classification effects 50% classification (3:1) products criteria is for based this hazard on calculation class methods as per Annex I of CLP, Part 3, unless determined otherwise in Section 6.1. - 11. OEL: The Threshold Substances Personal product Limit Occupational precautions, subject is not Value classified to authorisation Exposure protective as hazardous Level equipment and emergency procedures (Annex pursuant XIV REACH) to the provisions set forth in EC Regulation 1272/2008 (CLP). However, REPRODUCTIVE Information - Environmental The Information None Type PBT: Persistent, full wording since not hazards: not available available the of hazard bioaccumulative TOXICITY product SECTION Country (H) contains Block the leakage - Section PEC: with Product classification Predicted phrases 12. appropriate TWA/8h and toxic 9. Physical hazardous is given in substances environmental if there is no and is based on calculation methods as per Annex I of CLP, Part 4, unless determined otherwise in section 16 in of concentrations hazard. Concentration chemical properties the sheet. STEL/15min such as to be declared Remarks in section / Observations no. 3, it requires a safety data sheet information, mg/m3 compliant to (EU) ppm Regulation 2020/878. mg/m3 ppm Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent Does - PEL: not Predicted meet the exposure classification level criteria for this hazard class SECTION Substances any contamination AGW 13. Disposal subject to DEU of skin, eyes considerations exportation 0,05 and personal clothing. These indications apply for both processing staff and those involved in emergency reporting pursuant to Regulation (EU) 649/2012: 9.1. Hazard SECTION - Changes None PMT: Persistent, Information SKIN classification to 11. previous on basic and physical Toxicological mobile review: and toxic information indication: and chemical -- properties SECTION procedures. STOT - The PNEC: following - SINGLE Predicted 4. sections First EXPOSURE no effect were aid concentration modified: measures 13.1. Waste treatment methods In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it - 01 REACH: / 02 / 03 Regulation / 04 / 08 / 09 (EC) / 11 1907/2006 / 12 / 13 / 15 / 16. 4.1. 6.2. contains, Properties Substances subject to the Rotterdam Convention: Description Environmental using of the first precautions criteria aid measures specified in the applicable regulation for classification. Value TITANIUM DIOXIDE Information Does - RID: not Threshold Appearance Reuse, None when Limit Regulation meet the concerning possible. Value Neat product residues should liquid classification the criteria international for this transport hazard class be considered special non-hazardous waste. Temperature: 25 °C of dangerous goods by train It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the 2.2. - TLV: Threshold Limit Value Colour Disposal Label Type elements must be performed

Hazard categories

be considered special non-hazardous waste. Temperature: 25 °C of dangerous goods by train It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the TLV: Threshold Limit Value Colour Disposal Label Type elements must be performed Country through TWA/8h an authorised waste white management STEL/15min firm, in compliance with Remarks Temperature: national and / Observations local 25 °C regulations. No The toxicological STOT - TLV CEILING: effects product requiring - REPEATED must effects not of implementation Concentration EXPOSURE that should not be exceeded during any time of occupational exposure. penetrate exposure into to the of the product. special sewer first system aid or measures come into are contact expected. with The surface following water information or ground water. represents practical indications of Odour The Substances correct behaviour in the event of contact with a chemical product, even if not hazardous. management subject of to waste the Stockholm arising mg/m3 from Convention: the use or ppm dispersal mild of this product mg/m3 must be ppm organised in accordance with occupational safety - TWA: Time-weighted average exposure limit Melting regulations. None TLV labelling point See / freezing pursuant section BGR point 8 to for EC possible Regulation

vPvB Substances

Remove, Very leaked persistent and into very a bioaccumulative Lower Information minutes, remainder opening TLV explosive with inert the absorbent not available limit GRC eyelids fully. material. Get medical advice/attention. 10 not available Signal - vPvM: Upper NDS/NDSCh explosive word: Very persistent and very mobile limit POL 10 -- not available INHAL SECTION SKIN: Make Information Does - WGK: not Water sure Take the meet 14. hazard not off leakage the Transport contaminated available site is clothing. classes (German). well aired. Wash criteria information for this hazard class Contaminated immediately material and thoroughly should be with disposed running of water in compliance (and soap with if possible). the provisions Get medical set forth advice. in point Avoid Flash TLV point further contact with contaminated clothing. 13. ROU 10 > 60 15 °C 6.4. INGESTION: Auto-ignition Information The Reference ПДК product on is to Do likely temperature not other not dangerous routes RUS induce sections of vomiting exposure under current 10 unless provisions explicitly authorised not available of the Code by of a doctor. International Do not Carriage give anything of Dangerous by mouth Goods a, Ф to an by unconscious Road (ADR) person. and by Get Rail GENERAL Decomposition Information WEL statements: BIBLIOGRAPHY on other hazards temperature GBR 10 not available INHAL medical (RID), of advice/attention.

Disposal

from is the given 8,0-9,5 on request. accident in sections scene. 8 Get and medical 13. advice/attention. RESP Concentration: 100 % Based 2. Regulation EUH208 ACGIH on the (EC) available

Contains

product 0,2 of the does European not Reaction Parliament mass substances of: 5-chloro-2-methyl-4-isothiazolin-3-one listed in the main European lists of RESP Temperature: 25 °C [EC potential no. 247-500-7] or suspected and endocrine 14.1. UN number or ID number disruptors 3. Regulation with (EU) human 2020/878 health (II effects Annex under of REACH evaluation. Regulation) Kinematic A chemical viscosity Rescuer Delayed and protection safety assessment has not been performed immediate effects as well as chronic effects from short and long-term exposure 2-methyl-2H-isothiazol-3-one 615-1000 for the preparation/for mm2/s [EC the substances no. 220-239-6] indicated Method:Converting (3:1) in section 3. Formula from Dynamic SECTION 7. Handling and storage 1,2-Benzisothiazol-3(2H)-one 4. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament SECTION not applicable 12. Ecological information 5. Regulation (EU) 286/2011 (II Atp. Viscosity & May CLP) Density of the an European Parliament produce allergic reaction. IOKAL No 20 (CaCO3) Temperature: 25 °C 7.1. SECTION It Information

Precautionary statements

Threshold Dynamic Use this product is good practice Regulation 16. viscosity Limit according not available (EU) for Other Value for rescuers lending support to a person who has been exposed to a chemical substance or to a mixture to wear personal safe 618/2012 handling information to good working practices. 80-110 (III Atp. CLP) of the European Parliament Avoid KU littering. Inform the competent authorities, Method:ASTM should the D 562-05 product reach waterways or protective equipment. The nature of such protection depends on the hazard level of the substance or mixture, on the type of exposure and on 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament 14.2. the contaminate Interactive Text UN Type extent of proper of effects soil or vegetation. the shipping (H) contamination. indications Country TWA/8h absence other 2-3 of more sheet: specific indications, use of disposable gloves in the event of possible contact STEL/15min

Remarks

Temperature: / Observations 25 °C 8. Regulation Precautionary Before handling statements: (EU) the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the 944/2013 name (V mentioned Atp. In the CLP) in of section the of European the Parliament Solubility with body fluids is recommended. For the type of PPE suitable for the characteristics of the substance or mixture, see section 8. mg/m3 ppm not available mg/m3 ppm 12.1. Partition environment. 9. Regulation Toxicity P501 VLEP coefficient: n-octanol/water Do (EU) not 605/2014 FRA eat, drink (VI or Dispose Atp. smoke 10 CLP) of during of contents the use. European / Remove not available container Parliament any to contaminated an approved waste clothes disposal and personal plant or protective recycled equipment in accordance before with entering local / Information not Acute places 10. Regulation applicable in which (EU) Tox. not available 2 people 2015/1221 eat. (VII Atp. CLP) of the European Parliament Acute toxicity, category 2 4.2. Most Vapour NDS/NDSCh Acute important pressure Tox. 3 symptoms and POL national Acute 10 effects, toxicity, both category / international not regulations. acute and 3 available delayed INHAL 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament Density P102 and/or relative density Keep out of reach of 1.37-1.41 children. g/cm3 Method:ISO 2811 7.2. 12. Regulation (EU) 2016/1179 (IX Atp. CLP) ACUTE Conditions Acute TOXICITY Tox. 4 Acute toxicity, category 4 any incompatibilities 1,2-Benzisothiazol-3(2H)-one P101 for safe storage, If including medical advice is needed, have product container or label at hand. 14.3. Specific 13. Regulation (EU) 2017/776 (X Atp. CLP) Transport Skin information Corr. hazard 1C on class(es) symptoms Skin Temperature: 25 °C and corrosion, effects caused category by the 1C product are unknown. Relative LC50 P312 - for vapour Fish density Call a POISON CENTRE not available 0,8 / doctor, mg/l/96h if you Oncorhynchus ATE Skin Store 14. Regulation (Inhalation) feel unwell. mykiss (Ιριδίζουσα πέστροφα) only in the (EU) Corr. 1 of the mixture: Skin corrosion, category 1 original 2018/669 container. (XI Atp. Store CLP) the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away Not classified (no significant component) Particle EC50 - for DELAYED ATE not Eye applicable (Oral) Dam. EFFECTS: characteristics Algae / Aquatic Plants of the 1 mixture: Based on Serious the information eye damage, currently not applicable category 4,4 mg/l/72h Daphnia magna (Νερόψυλλος ο μέγας) available, Not 1 classified there are (no no significant known cases component) of delayed effects following exposure to this from 15. Regulation any incompatible (EU) 2019/521 materials, (XII see Atp. section CLP) 10 for details. product. ATE Eye 16. Delegated Regulation (UE) 2018/1480 (XIII Atp. CLP) (Dermal) Irrit. 2 of the mixture: Eye irritation, category 2 Not classified (no significant component) 17. Regulation (EU) 2019/1148 Skin Irrit. 2 Skin irritation, category 2 ... / >>

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%.