Tetrabromobisphenol A bis(2,3-dibromopropyl ether)

Hazard statements (CLP)

H316, H320

Code

Statements

H316

Causes mild skin irritation

SECTION 2: Hazards identification

GHS classification according to Annex Ⅱ

Physical hazards

Acute toxicity (oral)- not classified Acute hazards to the aquatic environment-not classified Explosives-not classified Acute toxicity (dermal)-not classified Chronic hazards to the aquatic environment- not classified Flammable gases-not classified Acute toxicity (inhalation)-not classified Flammable aerosols-not classified Skin corrosion/irritation- 3 Gases under pressure- not classified Serious eye damage/eye irritation- 2B Flammable liquids- not classified Respiratory sensitizer-not classified Flammable solids-not classified Skin sensitizer- not classified Self-reactive substances and mixtures-not classified Germ cell mutagenicity- not classified Pyrophoric liquids-not classified Carcinogenicity- not classified Pyrophoric solids-not classified Toxic to reproduction- not classified Self-heating substances and mixtures-not classified STOT SE-not classified Substances and mixtures, which in contact with water, STOT RE- not classified emit flammable gases-not classified Aspiration hazard- not classified Oxidizing liquids-not classified Oxidizing solids-not classified Organic peroxides-not classified Corrosive to metals-not classified

Hazard pictograms

None

Hazard statements

H316: Causes mild skin irritation. H320: Causes eye irritation (slight).

Precautionary statements

P280: Wear protective gloves. P264: Wash hands thoroughly after handling. P261: Avoid breathing dust. P270: Do not eat, drink or smoke when using this product.

Response

P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+313: If eye irritation persists, get medical advice/attention P302+352 IF ON SKIN: Wash with soap and water. P301+330+331+312 IF SWALLOWED Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell

Storage

P402+404: Store in a dry place. Store in a closed container. .Disposal precautionary statements P501: Dispose of contents/container to relevant local and national regulations. SDS

2.1 Classification of the substance or mixture

Health hazards Environmental hazards Physical hazards Acute toxicity (oral)- not classified Acute hazards to the aquatic environment-not classified Explosives-not classified Acute toxicity (dermal)-not classified Chronic hazards to the aquatic environment- not classified Flammable gases-not classified Acute toxicity (inhalation)-not classified Flammable aerosols-not classified Skin corrosion/irritation- 3 Gases under pressure- not classified Serious eye damage/eye irritation- 2B Flammable liquids- not classified Respiratory sensitizer-not classified Flammable solids-not classified Skin sensitizer- not classified Self-reactive substances and mixtures-not classified Germ cell mutagenicity- not classified Pyrophoric liquids-not classified Carcinogenicity- not classified Pyrophoric solids-not classified Toxic to reproduction- not classified Self-heating substances and mixtures-not classified STOT SE-not classified Substances and mixtures, which in contact with water, STOT RE- not classified emit flammable gases-not classified Aspiration hazard- not classified Oxidizing liquids-not classified Oxidizing solids-not classified Organic peroxides-not classified Corrosive to metals-not classified .Label elements: .Signal word: Warning .Symbol : None .Hazard Statement: H316: Causes mild skin irritation. H320: Causes eye irritation (slight). .Precautionary Statements: P280: Wear protective gloves. P264: Wash hands thoroughly after handling. P261: Avoid breathing dust. P270: Do not eat, drink or smoke when using this product. .Response Precautionary Statements: P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+313: If eye irritation persists, get medical advice/attention P302+352 : IF ON SKIN: Wash with soap and water. P301+330+331+312: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell. .Storage precautionary statements P402+404: Store in a dry place. Store in a closed container. .Disposal precautionary statements : P501: Dispose of contents/container to relevant local and national regulations. SDS 3. Composition/Information on Ingredients Composition CAS NO Tetrabromobisphenol A bis(2,3-dibromopropyl ether) 21850-44-2 4. First Aid Measures Persons using this product should consult a physician or other medical professional if an accident involving this product in injury. Specific first-aid measures are as follows: .Eyes Contact: Immediately raise eyelids and flush with plenty of water at least for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation persists, seek medical care. .Skin Contact: Immediately water contaminated area with plenty of water and soap. Remove all contaminated clothing and wash thoroughly before reuse. .Inhalation: Remove to fresh air. Call a POISON CENTER or doctor/physician if you feel unwell. .Ingestion: Do not induce vomiting without professional instruction. Get medical attention immediately. 5. Fire Fighting Measures .Flash point: Not applicable .Flammable/Explosive Limits-Lower Vol %: Not available .Flammable/Explosive Limits-Upper Vol %: Not available .Extinguishing Media: This product is not flammable. As for fire caused by other ignition sources, use dry chemical or sand for small fire; foam or CO2 for large fire. Seek advice from local fire-fighting authority. .Fire Fighting Equipments: Firefighters must wear self-contained breathing apparatus and full protective equipment. .Unusual Fire and Explosion Hazards: None. .Hazardous Combustion Products: Carbon monoxide, carbon dioxide, hydrogen bromine, carbonyl bromine may be released from thermal decomposition. 6. Accidental Release Measures .Personal precautions: Use proper personal protective equipment as indicated in Section 8. .Measures for Cleaning/Collection: Small Spill: Sweep up with care to avoid generating dust. Collect it into a proper container for disposal. Large Spill: Cover the spilled powder with plastic cloth or canvas. Try to recycle it. Prevent entry into sewers or confined areas. .Environmental Precautions: Keep cleaning run-offs out of municipal sewers and open bodies of water. Comply with local and national laws and regulations. 7. Handling and Storage .Handling: Do not breathe powder or fume that may be evolved during processing. Workers must wear proper protective equipments and must operate strictly according to relative rules. .Information about fire- and explosion protection: Keep ignition sources away—Do not smoke. .Storage: .Requirements to be met by storerooms: Store it in a well-ventilated, cool and dry store room. .Additional Information: The storeroom should be equipped with proper facilities for accidental leakage. 8. Exposure Controls/Personal Protection Ingredients OSHA PEL-TWA ACGIH TLV-TWA Tetrabromobisphenol A bis(2,3-dibromopropyl ether) (CAS: 21850-44-2) 3 0.5mg/m3 0.5mg/m .Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate vapor or fume, use ventilation to keep exposure to airborne contaminants below the exposure limit. .Personal Protective Equipments(for workers): .Protection of Hands: Wear protective gloves. SDS .Protection of Eyes: No special requirements under normal conditions. Wear safety glasses when power may contact eyes or working in a dusty environment. .Respiratory Protection: Use an approved respirator if exposure limits are exceeded or if irritation or other symptoms occur. .Protection of Body: Recommend wearing uniforms. .General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Avoid contact with eyes and broken skin. 9. Physical/Chemical Properties .General Information .Form: Powder or grain .Color: White .Odor: Odorless .Boiling Range: Not available .Melting point/Melting range: 105-116℃ .Flash point: Not applicable .Self-igniting temperature: Not applicable .Flammable/Explosive Limits-Lower Vol %： Not applicable .Flammable/Explosive Limits-Upper Vol %: Not applicable .Density（@25℃）: 2.2g/cm3 .Vapor density: Not available