Antimony trioxide

Hazard statements (CLP)

H351

Code

Statements

H351

Suspected of causing cancer

SECTION 2: Hazards identification

Classification according to EC regulation 1272/2008 (CLP) Classification of the substance or mixture

2.2 Label elements

(CLP)

Signal word

Warning

Hazard statements

H351 Suspected of causing cancer.

Precautionary statements

P202 Do not handle until all safety precautions have been read and understood. P281 Use personal protective equipment as required. P308+P313 IF exposed or concerned: Get medical advice/attention. P501 Dispose of contents/container to hazardous or special waste collection point. Special labelling Text for labelling: For professional use only.

2.3 Other hazards

No risks worthy of mention.

2.1 Classification of the substance or mixture

Classification according to EC regulation 1272/2008 (CLP) Carc. 2; H351 Suspected of causing cancer. 2.2 Label elements Labelling (CLP) Signal word: Warning Hazard statements: H351 Suspected of causing cancer. Safety precautions: P202 Do not handle until all safety precautions have been read and understood. P281 Use personal protective equipment as required. P308+P313 IF exposed or concerned: Get medical advice/attention. P501 Dispose of contents/container to hazardous or special waste collection point. Special labelling Text for labelling: For professional use only. 2.3 Other hazards No risks worthy of mention. 3. Composition/Information on Ingredients 3.1 Substances Chemical characterization: O3 Sb2 = Sb2 O3 Diantimony trioxide CAS-Number: 1309-64-4 EC-number: 215-175-0 EU-number: 051-005-00-X SDS RTECS-Number: CC5650000 Hazardous ingredients: Ingredient Designation Content Classification EINECS No.: 215-175-0 Diantimony trioxide 95-99.95 % EU: Carc. Cat. 3; R40. CAS No.: 1309-64-4 CLP: Carc. 2; H351. EINECS No.: 215-267-0 Lead monoxide < 0.1 % EU: CAS No.: 1317-36-8 (SVHC) CLP: Acute Tox. 4; H302. Acute Tox. 4; H332. Repr. 1A; H360Df. STOT RE 2; H373. Aquatic Acute 1; H400. Aquatic Chronic 1; H410. Additional information: This mixture contains the following substances of very high concern (SVHC) which are included in the Candidate List according to Article 59 of REACH: Lead monoxide (CMR) 4. First Aid Measures 4.1 Description of first aid measures After inhalation: Provide fresh air. Seek medical attention. In case ofskin contact: Wash with plenty of soap and water. Consult physician. After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Subsequently consult an ophthalmologist. After swallowing: Rinse mouth immediately and drink plenty of water. Consult physician. 4.2 Most important symptoms and effects, both acute and delayed Cough, fever, headache, nausea, circulatory collapse, apnea. Following intake of large amounts: damage of kidneys 4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically. 5. Fire Fighting Measures 5.1 Extinguishing media Suitable extinguishing media: Co-ordinate fire-fighting measures to the fire surroundings. 5.2 Special hazards arising from the substance or mixture Not combustible. Fires in the immediate vicinity may cause the development of dangerous vapours. 5.3 Advice for firefighters Special protective equipment for firefighters: Wear self-contained breathing apparatus. To avoid contact with skin, keep safety distance and wear suitable protective clothing. Additional information: Hazchem-Code: - Do not allow fire water to penetrate into surface or ground water. 6. Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Do not handle until all safety precautions have been read and understood. Avoid generation of dust. Do not breathe dust. Avoid contact with the substance. Provide adequate ventilation. Wear personal protection equipment. 6.2 Environmental precautions Do not allow to penetrate into soil, waterbodies or drains. 6.3 Methods and material for containment and cleaning up Take up mechanically, placing in appropriate containers for disposal. Final cleaning. 6.4 Reference to other sections Refer additionally to chapter 8 and 13. SDS 7. Handling and Storage 7.1 Precautions for safe handling Advices onsafe handling: Do not handle until all safety precautions have been read and understood. Avoid contact with skin and eyes. Wear personal protection equipment. Avoid generation of dust. Do not breathe dust. In case of dust: Provide adequate ventilation, and local exhaust as needed. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storerooms and containers: Store container tightly closed in a dry and cool place. Storage class: 13 = Non-combustible solids 7.3 Specific end use(s) No information available. 8. Exposure Controls/Personal Protection 8.1 Control parameters Occupational exposure limit values: CAS No. Designation Type Limit value 1317-36-8 Lead monoxide (SVHC) Europe: BOELV: TWA 0,15 mg/m³ (inhalable fraction) Ireland: 8 hours 0,15 mg/m³ DNEL/DMEL: DNEL Long-term systemic, workers, dermal: 281 mg/kg bw/d. DNEL Long-term local, workers, inhalative:0,5 mg/m³ DNEL Long-term systemic,consumers, oral: 168,6 mg/kg bw/d. DNEL Long-term systemic, consumers, dermal:168,6 mg/kg bw/d. DNEL Long-term local, consumers, inhalative: 0,1mg/m³ PNEC: PNEC water (freshwater): 0,113 mg/L. PNEC water (marine water): 0,0113 mg/L. PNEC sediment (freshwater): 11,2 mg/kg dwt. PNEC sediment (marine water): 2,24 mg/kg dwt. PNEC soil: 37 mg/kg dwt. PNEC sewage treatment plant: 2,55 mg/L. 8.2 Exposure controls In the case of the formation of dust: Withdraw by suction. Occupational exposure controls Respiratory protection: Respiratory protection must be worn whenever the WEL levels have been exceeded. Particulates filter P2 according to EN 143. Hand protection: Protective gloves according to EN 374. Glove material: Nitrile rubber - Layer thickness: 0,11 mm. Breakthrough time: >480 min. Observe glove manufacturer's instructions concerning penetrability and breakthrough time. Eye protection: Tightly sealed goggles according to EN 166. Body protection: Wear suitable protective clothing.