Caustic Potash Membrane Dilute Solution 45%, 48%, 50%; Caustic Potash

Occidental Chemical Corporation

Revision date : 2019-12-10

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GHS07 GHS05
Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

7732-18-5

Name of the chemical

Water, distilled, conductivity or of similar purity H2O

Concentration

49-90

EC/CAS

1310-58-3

Name of the chemical

potassium hydroxide

Concentration

10-51

General Information

Version

08

Revision date

2019-12-10

Product name

Caustic Potash Membrane Dilute Solution 45%, 48%, 50%; Caustic Potash

1.2.1 Relevant identified uses

Intermediate in industrial manufacturing processes, such as manufacture of potassium fertilizers, potassium carbonate or other potassium salts and other

Emergency telephone

1-800-424-9300, +1 703-527-3887, 1-972-404-3245, 1-800-752-5151, 1-972-404-3700

Icons in SDS

GHS05 GHS07

Company Information

company name

Occidental Chemical Corporation

e-mail address of the competent person responsible for the Safety Data Sheet

MSDS@oxy.com

GHS Information

Signal word

DANGER

Section 2

SECTION 2: Hazards identification

(29 CFR 1910.1200) _________________________________________________________________________________________________

Appearance/Odor

Clear liquid Odorless

Signal word

DANGER

Health hazards

CORROSIVE. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. HARMFUL IF SWALLOWED.

Physical hazards

MAY BE CORROSIVE TO METALS. Mixing with water, acid or incompatible materials may cause splattering and release of heat. Do not store in aluminum container, use aluminum fittings, or aluminum transfer lines, as aluminum will quickly corrode and flammable hydrogen gas will be generated. Absorb spillage to prevent material damage. AQUATIC TOXICITY: HARMFUL TO AQUATIC LIFE. Category 1 - Corrosive to metals GHS: CONTACT HAZARD - SKIN Category 1B - Causes severe skin burns and eye damage GHS: CONTACT HAZARD - EYE Category 1 - Causes serious eye damage GHS: ACUTE TOXICITY - ORAL Category 4 - Harmful if swallowed HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) HARMFUL TO AQUATIC LIFE Unknown Acute Dermal Toxicity There is no acute dermal toxicity data available for this material. Potassium hydroxide is a corrosive substance at concentrations of about 2% and higher. For this reason, there is no need for further acute toxicity testing Unknown Acute Inhalation Toxicity There is no acute inhalation toxicity data available for this material. Potassium hydroxide is a corrosive substance at concentrations of about 2% and higher. For this reason, there is no need for further acute toxicity testing GHS SYMBOL: Corrosive, Exclamation mark GHS SIGNAL WORD: DANGER GHS HAZARD STATEMENTS GHS - Physical Hazard Statement(s) May be corrosive to metals GHS - Health Hazard Statement(s) Causes severe skin burns and eye damage Causes serious eye damage Harmful if swallowed GHS - Precautionary Statement(s) - Prevention Do not breathe mist, vapors, or spray Wash skin and contaminated clothing thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection Keep only in original container Avoid release to the environment GHS - Precautionary Statement(s) - Response IF SWALLOWED: Rinse mouth. Do NOT induce vomiting IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do Continue rinsing IF EXPOSED (eyes): Immediately call a POISON CENTER OR LICENSED HEALTH CARE PROVIDER IF INHALED: Remove person to fresh air and keep comfortable for breathing IF INHALED: Immediately call a POISON CENTER OR PHYSICIAN Specific treatment (see First Aid information on product label and/or Section 4 of the SDS) Absorb spillage to prevent material damage GHS - Precautionary Statement(s) - Storage Store in corrosive resistant and NON-ALUMINUM container with a resistant inner liner (NOTE: flammable hydrogen gas may be generated if aluminum container and/or aluminum fittings are used) Store in a secure manner Not Otherwise Classified • Mixing with water or other low pH material may cause heat to be released • Do not store in aluminum container or use aluminum fittings or transfer lines, as flammable hydrogen gas will be generated • Accelerated corrosion can occur in areas where equipment is subjected to extremely high temperatures See Section 11: TOXICOLOGICAL INFORMATION _________________________________________________________________________________________________

Precautionary statements

Do not breathe dusts or mists. Wash skin and contaminated clothing thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves, protective clothing, eye, and face protection. Keep only in original container or container compatible with product (see Section 7 - Safe Storage Conditions). Avoid release to the environment. - Disposal • Dispose of contents and container in accordance with applicable local, regional, national, and/or international regulations

Additional information

Toxicity may be delayed, and may not be readily visible. Significant exposures must be referred for medical attention immediately. There is no specific antidote. ******************************************************************************************************************************** HAZARD CLASSIFICATION

2.1 Classification of the substance or mixture

GHS: PHYSICAL HAZARDS: • Category 1 - Corrosive to metals GHS: CONTACT HAZARD - SKIN: Category 1B - Causes severe skin burns and eye damage GHS: CONTACT HAZARD - EYE: Category 1 - Causes serious eye damage GHS: ACUTE TOXICITY - ORAL: Category 4 - Harmful if swallowed HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): • HARMFUL TO AQUATIC LIFE Unknown Acute Dermal Toxicity: There is no acute dermal toxicity data available for this material. Potassium hydroxide is a corrosive substance at concentrations of about 2% and higher. For this reason, there is no need for further acute toxicity testing. Unknown Acute Inhalation Toxicity: There is no acute inhalation toxicity data available for this material. Potassium hydroxide is a corrosive substance at concentrations of about 2% and higher. For this reason, there is no need for further acute toxicity testing. GHS SYMBOL: Corrosive, Exclamation mark GHS SIGNAL WORD: DANGER GHS HAZARD STATEMENTS: GHS - Physical Hazard Statement(s) • May be corrosive to metals GHS - Health Hazard Statement(s) • Causes severe skin burns and eye damage • Causes serious eye damage • Harmful if swallowed

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