ACL 90 PLUS CHLORINATING COMPOSITION

Occidental Chemical Corporation

Revision date : 2015-05-11

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GHS03 GHS06 GHS07 GHS09
Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

87-90-1

Name of the chemical

Symclosene

Concentration

N/A

General Information

Revision date

2015-05-11

Product name

ACL 90 PLUS CHLORINATING COMPOSITION

Product Synonyms

Trichloroisocyanuric acid, Trichloro-s-triazinetrione, 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione,1,3,5-trichloro-, Symclosene, TCCA

CAS No.

87-90-1

1.2.1 Relevant identified uses

Algaecide, Disinfectant, Sanitizer, Bactericide, Fungicide, Microbiocide/microbiostat

1.2.2. Uses advised against

None identified. This is a pesticide product, do not use it in a pesticide application that is not included on its label _____________________________________________________________________________________________________

Emergency telephone

1-800-733-3665 or 1-972-404-3228 (USA); CHEMTREC (within USA and Number

Icons in SDS

Company Information

company name

Occidental Chemical Corporation

e-mail address of the competent person responsible for the Safety Data Sheet

MSDS@oxy.com or 1-972-404-3245

GHS Information

Signal word

DANGER

Section 2

SECTION 2: Hazards identification

GHS Classification OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). ********************************************************************************************************************************** EMERGENCY OVERVIEW: Color: White Physical State: Solid

Appearance/Odor

Crystals, Granules Slight chlorine odor

Signal word

DANGER DANGER

Health hazards

CORROSIVE. CAUSES SERIOUS EYE DAMAGE. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY BE FATAL IF INHALED. HARMFUL IF SWALLOWED.

Physical hazards

OXIDIZING AGENT. Contact with water slowly liberates irritating and hazardous chlorine containing gases. Contamination with moisture, organic material, or other incompatible chemicals may start a reaction with generation of heat, liberation of hazardous gases, and possible fire and explosion. Contact with acids liberates toxic gas. Decomposes at temperatures above 464 °F with liberation of harmful gases. When ignited will burn with the evolution of chlorine and equally toxic gases. Do not get water inside container. Wet material may generate nitrogen trichloride, an explosion hazard. AQUATIC TOXICITY: Very toxic to aquatic organisms. Very toxic to aquatic life with long lasting effects. Oxidizing Solid - Cat. 2 GHS CONTACT HAZARD - SKIN Category 1C - Causes severe skin burns and eye damage GHS CONTACT HAZARD - EYE Category 1 - Causes serious eye damage GHS: ACUTE TOXICITY - Category 2 - Fatal if inhaled INHALATION: GHS ACUTE TOXICITY - ORAL Category 4 - Harmful if swallowed GHS: ACUTE TOXICITY - Not acutely toxic by dermal exposure. DERMAL: GHS: TARGET ORGAN Category 3 - May cause respiratory tract irritation TOXICITY (SINGLE EXPOSURE): GHS: CARCINOGENICITY: This product is not classified as a carcinogen by NTP, IARC or OSHA. GHS: HAZARDOUS TO AQUATIC Category 1 - Very toxic to aquatic life

Precautionary statements

Do not get in eyes, on skin, or on clothing. Wear eye protection, face protection, protective gloves. Do not breathe dusts or mists. Use outdoors or in a well-ventilated area. Wash hands and affected skin thoroughly after handling. Do not eat, drink or smoke when using this product. Do not get water inside container, an explosion hazard. Oxidizer, keep separated from incompatible substances. - Prevention Do not breathe dust, fume, gas, mist, vapors, or spray In case of inadequate ventilation, wear respiratory protection Wear protective gloves, protective clothing, eye, and face protection Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Keep away from heat Keep/Store away from clothing and other combustible materials Take any precaution to avoid mixing with combustibles Avoid release to the environment - Response IF INHALED: Remove person to fresh air and keep comfortable for breathing Immediately call a POISON CENTER or doctor/physician Specific treatment is urgent (see Section 4 of SDS or first aid information on this label) IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower Wash contaminated clothing before reuse IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing IF SWALLOWED: Rinse mouth. Do NOT induce vomiting IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Specific treatment (see First Aid information on product label and/or Section 4 of the SDS) In case of fire: Use large amounts of water to extinguish Collect spillage - Storage Store in a well-ventilated place. Keep container tightly closed Store locked up - Disposal Dispose of contents and container in accordance with applicable local, regional, national, and/or international regulations.

Additional information

This material is corrosive. Product has strong buffering capability. Use dilution. May cause burns to moist skin if not promptly removed. There is no specific antidote. **********************************************************************************************************************************

Environmental hazards

ACUTE GHS: HAZARDOUS TO AQUATIC Category 1 - Very toxic to aquatic life with long lasting effects - CHRONIC UNKNOWN ACUTE TOXICITY: Not applicable. 100% of this product consists of ingredient(s) of known acute toxicity.

Hazard pictograms

Corrosion, Skull and Crossbones, Exclamation mark, Oxidizer, Environmental hazard

Hazard statements

GHS - Physical Hazard Statement(s) May intensify fire; oxidizer GHS - Health Hazard Statement(s) Causes severe skin burns and eye damage Causes serious eye damage Fatal if inhaled Harmful if swallowed May cause respiratory irritation GHS - Environmental Hazard Statement(s) Very toxic to aquatic life Very toxic to aquatic life with long lasting effects

2.3 Other hazards

Damp or wet material may generate nitrogen trichloride, an explosion hazard Contact with acids liberates toxic gas See Section 11: TOXICOLOGICAL INFORMATION

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