Ethylmagnesium chloride solution, 2.0 M in THF

Hazard statements (CLP)

H225, H260, H314, H335, H336, H351

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids (Category 2) Substances And Mixtures Which, In Contact With Water, Emit Flammable Gases (Category 1} Skin corrosion/irritation (Category 1B) Respiratory tract irritation (Category 3) Narcotic effects (Categary 3) Carcinogenicity (Category 2)

Signal word

Danger

Hazard statements

H225 Highly Flammable liquid and vapour H260 In contact with water releases flammable gases which may ignite spontaneously H314 Causes severe skin burns and eye damage H335 May cause respiratory irritation H336 May cause drowsiness or dizziness Ethylmagnesium chloride solution, 2.0 M in THF Page 1 of 8 H351 Suspected of causing cancer H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H351 Suspected of causing cancer

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. P231 + P232 Handle under inert gas. Protect from moisture. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion­proof electrical/ventilating/lighting/equipment. P242 Use only non­sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well­ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P335 + P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol­resistant foam for extinction. P402 + P404 Store in a dry place. Store in a closed container. P403 + P233 Store in a well­ventilated place. Keep container tightly closed.