Diethyl azodicarboxylate solution 40 wt. % in toluene

Hazard statements (CLP)

H226, H242, H304, H315, H319, H335, H336, H361, H373, H401, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Flammable liquids (Category 3) Self­reactive substances and mixtures (Type C) Aspiration hazard (Category 1) Skin corrosion/irritation (Category 2) Serious eye damage/eye irritation (Category 2A) Respiratory tract irritation (Category 3) Narcotic effects (Category 3) Reproductive toxicity (Category 2) Specific target organ toxicity, repeated exposure (Category 2) Hazardous to the aquatic environment, acute hazard (Category 2) Hazardous to the aquatic environment, long­term hazard (Category 2)

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour H242 Heating may cause a fire Diethyl azodicarboxylate solution 40 wt. % in toluene Page 1 of 7 H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H361 Suspected of damaging fertility or the unborn child H373 Causes damage to organs through prolonged or repeated exposure H401 Toxic to aquatic life H411 Toxic to aquatic life with long lasting effects

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233 Keep container tightly closed. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/attention. P332 + P313 IF SKIN irritation occurs: Get medical advice/attention. P391 Collect spillage. Hazardous to the aquatic environment P403 + P233 Store in a well­ventilated place. Keep container tightly closed.

2.1 Classification of the substance or mixture

Flammable liquids (Category 3) Self­reactive substances and mixtures (Type C) Aspiration hazard (Category 1) Skin corrosion/irritation (Category 2) Serious eye damage/eye irritation (Category 2A) Respiratory tract irritation (Category 3) Narcotic effects (Category 3) Reproductive toxicity (Category 2) Specific target organ toxicity, repeated exposure (Category 2) Hazardous to the aquatic environment, acute hazard (Category 2) Hazardous to the aquatic environment, long­term hazard (Category 2)