4-Fluorophenylmagnesium bromide 1M in THF

Hazard statements (CLP)

H225, H302, H314, H335, H336, H351

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids (Category 2) Acute toxicity, oral (Category 4) Skin corrosion/irritation (Category 1B) Respiratory tract irritation (Category 3) Narcotic effects (Category 3) Carcinogenicity (Category 2)

Signal word

Danger

Hazard statements

H225 Highly Flammable liquid and vapour H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H351 Suspected of causing cancer 4-Fluorophenylmagnesium bromide 1M in THF Page 1 of 8

Precautionary statements

H336 May cause drowsiness or dizziness H351 Suspected of causing cancer P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion­proof electrical/ventilating/lighting/equipment. P242 Use only non­sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well­ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301 + P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol­resistant foam for extinction. P403 + P233 Store in a well­ventilated place. Keep container tightly closed.