Note: Ingredients listed on restricted chemical lists
EC/CAS
215-222-5/1314-13-2
Name of the chemical
Zinc oxide; C.I. 77947
Concentration
0%<C<1
EC/CAS
215-222-5/7446-14-2
Name of the chemical
Lead sulphate
Concentration
2.93% <29.27
EC/CAS
215-202-6/1313-13-9
Name of the chemical
Manganese dioxide
Concentration
55.36% <94.91
EC/CAS
231-198-9
Name of the chemical
Lead sulphate PbSO4
Concentration
2.93% <29.27
General Information
Version
0001
Revision date
2013-10-12
Product name
manganese dioxide
Product Synonyms
slimes and sludges, zinc sulfate electrolytic; MnO2 rich material, cell mud, anode mud, MnO2 sludge, Pb Mn cell mud, slimes and sludges, zinc sulfate electrolytic; MnO2 rich material, cell mud, anode mud, MnO2 sludge, Pb Mn cell mud,manganese sludge, anode cleaning sludge
CAS No.
69012-43-7
REACH No
01-2119467168-30-0003
1.2.1 Relevant identified uses
Under Regulation (EC) No 1907/2006 the substance is defined as an on-site and transported isolated intermediate and must be used in correspondence to that status, including the application of strictly controlled conditions Industrial use: manufacturing of chemicals For further details concerning the management measures: see the attached annex
1.2.2. Uses advised against
known
supplier name
Nyrstar Belgium N.V.
Manufacturer Name
of the product
Emergency telephone
+32 1458 45 45
Icons in SDS
Company Information
company name
NYRSTAR Sales & Marketing AG
e-mail address of the competent person responsible for the Safety Data Sheet
infoSDS@nyrstar.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H302, H332, H351, H360Df+P311, H372, H400, H410
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
SECTION 2: Hazards identification
1999/45/EC Classification of the substance or mixture Created by: Brandweerinformatiecentrum voor gevaarlijke stoffen vzw (BIG) Publication date: 2013-05-07 o Loy Technische Schoolstraat 43 A, B-2440 Geel Date of revision: 2013-12-10 http://www.big.be BIG vzw Reason for revision: 1.2;8.1;8.2;15.1
Signal word
Danger
Hazard statements
H351 Suspected of causing cancer. H360Df May damage the unborn child. Suspected of damaging fertility. H372 Causes damage to organs through prolonged or repeated exposure if swallowed and if inhaled. H302 + H332 Harmful if swallowed or if inhaled. H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood. P281 Use personal protective equipment as required. P260 Do not breathe dust. P309 + P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
2.3 Other hazards
CLP Slightly irritant to respiratory organs Slightly irritant to eyes
2.1 Classification of the substance or mixture
Created by: Brandweerinformatiecentrum voor gevaarlijke stoffen vzw (BIG) Publication date: 2013-05-07 o Loy Technische Schoolstraat 43 A, B-2440 Geel Date of revision: 2013-12-10 q http://www.big.be + © BIG vzw © Reason for revision: 1.2;8.1;8.2;15.1 a 2.1.1 Classification according to Regulation EC No 1272/2008 Classified as dangerous according to the criteria of Regulation (EC) No 1272/2008 Class Category Hazard statements Carc. category 2 H351: Suspected of causing cancer. Repr. category 1A H360Df: May damage the unborn child. Suspected of damaging fertility. STOT RE category 1 H372: Causes damage to organs through prolonged or repeated exposure if swallowed and if inhaled. Acute Tox. category 4 H332: Harmful if inhaled. Acute Tox. category 4 H302: Harmful if swallowed. Aquatic Acute category 1 H400: Very toxic to aquatic life. Aquatic Chronic category 1 H410: Very toxic to aquatic life with long lasting effects. 2.1.2 Classification according to Directive 67/548/EEC-1999/45/EC Classified as dangerous in accordance with the criteria of Directives 67/548/EEC and 1999/45/EC Repr. Cat. 1; R61 - May cause harm to the unborn child. Repr. Cat. 3; R62 - Possible risk of impaired fertility. Carc. Cat. 3; R40 - Limited evidence of a carcinogenic effect Xn; R20/22 - 48/20/22 - Harmful by inhalation and if swallowed. Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. N; R50-53 - Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
