CONDURSAL N523

Hazard statements (CLP)

H226, H315, H319, H373

Code

Statements

H226

Flammable liquid and vapour

Hazard categories

Cat- Hazard class and Hazard egory category state- ment A2 skin corrosion/irritation Cat. 2 Skin Irrit. 2) H315 A3 serious eye damage/eye irritation Cat.2 Eye Init. 2) H319 A9 specific target organ toxicity repeated exposure Cat. 2 STOTRE2) H373 B6 flammable liquid Cat.3 Flam. Liq. 3) H226 Remarks For full text of H-phrases: see SECTION 16

Most important adverse effects

Delayed or immediate effects can be expected after short or long-term exposure. The product is combustible and can be ignited by potential ignition sources 22

Signal word

Warning

Hazard pictograms

GHS02, GHS07, GHS08 stance GHS Xylene 1330-20-7 215-535-7 10-<25 Acute Tox. 4/ H312 Acute Tox. 4 / H332 Skin Irrit. 2/ H315 Eye Iriit. 2/ H319 STOT SE 3/H335 STOT RE2/H373 Asp. Tox. 1/H304 Flam. Liq. 3/ H226 For full text of abbreviations: see SECTION 16. ISECTION 4: First-aid measures 4.1 Description of first- aid measures General notes Take off immediately all contaminated clothing. Following inhalation In case of respiratory tract irritation, consult a physician. Provide fresh air. Following skin contact Wash with plenty of soap and water. Following eye contact Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. Following ingestion Rinse mouth immediately and drink plenty of water. Do NOT induce vomiting. Most important symptoms and effects, both acute and delayed Symptoms and effects are not known to date. 43 Indication of any immediate medical attention and special treatment needed none [SECTION 5: Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media water spray, alcohol resistant foam, BC-powder, carbon dioxide (CO2) Unsuitable extinguishing media water jet Special hazards arising from the substance or mixture In case of insufficient ventilation and/or in use, may form flammable/explosive vapor-air mixture. Solvent va- pors are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures. Hazardous combustion products carbon monoxide (CO), carbon dioxide (CO2) Advice for firefighters In case of fire and/or explosion do not breathe fumes. Coordinate firefighting measures to the fire surroundings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separ- ately. Fight fire with normal precautions from a reasonable distance. ISECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Provision of sufficient ventilation. Special danger of slipping by leaking/spilling product. Environmental precautions Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. Methods and material for containment and cleaning up Advice on how to contain a spill Covering of drains. Advice on how to clean up a spill Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage (sawdust, kieselgur (diatomite), sand, uni- versal binder). Appropriate containment techniques Use of adsorbent materials. Other information relating to spills and releases Place in appropriate containers for disposal. Ventilate affected area. 6.4 Reference to other sections Hazardous combustion products see section 5. Personal protective equipment see section 8. Disposal con- siderations: see section 13. ISECTION 7: Handling and storage 71 Precautions for safe handling Recommendations « Measures to prevent fire as well as aerosol and dust generation Use local and general ventilation. Avoidance of ignition sources. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge. Use only in well-ventilated areas. Due to danger of explosion, prevent leakage of vapours into cellars, flues and ditches. Ground/bond container and re- ceiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. * Warning Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures. Vapors are heavier than air, spread along floors and form explosive mixtures with air. Vapors may form explosive mixtures with air. Advice on general occupational hygiene Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protect- ive equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feed- ingstuffs. 7.2 Conditions for safe storage, including any incompatibilities Managing of associated risks 7.2.1.1 « Explosive atmospheres Keep container tightly closed and in a well-ventilated place. Use local and general ventilation. Keep cool. Pro- tect from sunlight. + Flammability hazards Keep away from sources of ignition - No smoking. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharge. Protect from sunlight. Incompatible substances or mixtures Observe compatible storage of chemicals. Consideration of other advice « Ventilation requirements Use local and general ventilation. Ground/bond container and receiving equipment. « Packaging compatibilities Only packagings which are approved (e.g. acc. to ADR) may be used. |SECTION 8: Exposure controls/personal protec 8.1 Control parameters National limit values Occupational exposure limit values (Workplace Exposure Limits) Cou Nameof agent CASNo ' Iden TWA ' STEL STEL = Ceil- Ceil- ntry tifier [ppm] [m%/ [ppm] [mgr ing-C | ing-C m®) L) [ppm] [:;;] / us xylene, mixture of | 1330-20- PEL 100 435 29 isomers 7 CFR 19101 000 us xylene (dimethyl- | 1330-20- PEL 100 435 150 benzene) 655 300 7 (cA) Cal/

Hazard statements

H226 Flammable liquid and vapor. H315 Causes skin irritation. H319 Causes serious eye irritation. H373 May cause damage to organs through prolonged or repeated exposure.

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P260 Do not breathe mist/vapors/spray. P280 Wear protective gloves/eye protection.

Response

P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with wa- ter/shower. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see ... on this label). P337+P313 If eye irritation persists: Get medical advice/attention. P370+P378 In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish.

Storage

P403+P235 Store in a well-ventilated place. Keep cool. P404 Store in a closed container.

Precautionary statements

- disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazardous Ingredients

Xylene 23

2.3 Other hazards

Special danger of slipping by leaking/spilling product.

Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vVPvB. Substances not relevant (mixture) Mixtures Description of the mixture Name of sub- Classification acc. to Data are not available. 12,6

Principle Routes of Exposure

Xylene 1330-20- | DNEL 289 mg/m® human, inhalatory worker (in- acute - local effects 4 dustry) Xylene 1330-20- DNEL 289 mg/m® human, inhalatory worker (in- acute - systemic ef- 7 dustry) fects Xylene 1330-20- | DNEL 180 mg/kg human, dermal worker (in- chronic - systemic ef- 7 dustry) fects Xylene 1330-20- | DNEL 77 mg/m® human, inhalatory worker (in- chronic - systemic ef- 7 dustry) fects « relevant PNECs of components of the mixture Name of sub- Threshold Organism Environ- Exposure time stance level mental com- partment Xylene 1330-20- PNEC 0.327™9, aquatic organisms freshwater short-term (single in- 7 stance) Xylene 1330-20- | PNEC 0.327 ™9 aquatic organisms | marinewater | short-term (single in- 7 stance) Xylene 1330-20- PNEC 12.46 ™/jq aquatic organisms | freshwater sedi- | ~short-term (single in- 7 ment stance) Xylene 1330-20- PNEC 12.46 ™yq aquatic organisms marine sedi- short-term (single in- 7 ment stance) Xylene 1330-20- | PNEC 231™y | terestrial organisms soil short-term (single in- 7 stance) Xylene 1330-20- PNEC 0.327 ™9, aquatic organisms water intermittent release 7 Name of sub- CAS End- Threshold Organism Environ- Exposure time stance No point level mental com- partment Xylene 1330-20- | PNEC 6.58™9 aquatic organisms | sewagetreat- | short-term (single in- 7 ment plant stance) (STP) 8.2 Exposure controls Appropriate engineering controls General ventilation. Individual protection measures (personal protective equipment) Eyelface protection Use protective eyewear to guard against splash of liquids. Skin protection « hand protection Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. « type of material CR chloroprene (chlorobutadiene) rubber, FKM fluoro-elastomer « other protection measures Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ocintments) is recom- mended. Wash hands thoroughly after handling. Respiratory protection During spraying wear suitable respiratory equipment. Environmental exposure controls Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water. ISECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state liquid (viscous) Color green Odor characteristic Other physical and chemical parameters pH (value) not applicable Melting point/freezing point not determined Initial boiling point and boiling range 136 °C Flash point 24°C Evaporation rate not determined Flammability (solid, gas) not relevant (fluid) Explosive limits « lower explosion limit (LEL) 1vol% « upper explosion limit (UEL) 7 vol% Vapor pressure 8hPaat20 °C Density 299 ypat20 °C Solubility(ies) not determined Partition coefficient n-octanol/water (log KOW) This information is not available. Auto-ignition temperature 320 °C Viscosity « dynamic viscosity >1,000 mPasat20 °C Explosive properties none Oxidizing properties none 9.2 Otherinformation Solvent content 10-15% Solid content ; 85-90 % ISECTION 10: Stability and reactivity 10.1 Reactivity This material is not reactive under normal ambient conditions. Concerning incompatibility: see below "Condi- tions to avoid" and "Incompatible materials". The mixture contains reactive substance(s): risk of ignition « if heated risk of ignition Chemical stability The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. See below "Conditions to avoid". Possibility of hazardous reactions No known hazardous reactions. Conditions to avoid Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Hints to prevent fire or explosion -. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precaution- ary measures against static discharge. Hazardous decomposition products Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known. Hazardous combustion products: see section 5. ISECTION 11: Toxicological information 1141 Information on toxicological effects Test data are not available for the complete mixture. Classification procedure The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

Classification according to GHS

(1272/2008/EC, CLP) Acute toxicity Shall not be classified as acutely toxic. + Acute toxicity of components of the mixture Name of substance CAS No Exposure: ATE Xylene 1330-20-7 dermal 1,100 ™/yg Xylene 1330-20-7 inhalation: vapor 11 ™9yah Skin corrosioniirritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization Shall not be classified as a respiratory or skin sensitizer. Summary of evaluation of the CMR properties Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant. Specific target organ toxicity (STOT) « Specific target organ toxicity - single exposure Shall not be classified as a specific target organ toxicant (single exposure). « Specific target organ toxicity - repeated exposure May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard

Shall not be classified as presenting an aspiration hazard. ISECTION 12: Ecological information 121 Toxicity 122 Persistence and degradability Data are not available. 123 Bioaccumulative potential Data are not available. Bioaccumulative potential of components of the mixture Name of substance BODS5/COD Xylene 1330-20-7 277-3.15 Mobility in soil Data are not available.

Other hazards

Data are not available. SECTION 13: Disposal considerations 131 Waste treatment methods Waste treatment-relevant information Solvent reclamation/regeneration. Sewage disposal-relevant information Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets. Waste treatment of containers/packages Completely emptied packages can be recycled. Handle contaminated packages in the same way as the sub- stance itself. Relevant provisions relating to waste List of wastes 08 01 11* Wastes from MFSU and removal of paint and varnish

Remarks

Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separatelv bv the local or national waste manaaement facilities. P, Transport information

UN Number

1263 UN proper shipping name PAINT Transport hazard class(es) Class 3 (flammable liquids) Packing group 11l (substance presenting low danger) 1263 Proper shipping name PAINT Class 3 Classification code F1 Packing group LI} Danger label(s) 3

Environmental hazards

none (non-environmentally hazardous acc. to the dangerous goods regulations) 14.6 Special precautions for user Provisions for dangerous goods (ADR) should be complied within the premises. 14.7 Transport in bulk according to Annex Il of MARPOL and the IBC Code The cargo is not intended to be carried in bulk. Information for each of the UN Model Regulations « Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)

Special Provisions

(SP) 163, 367, 640E, 650 Excepted quantities (EQ) E1 Limited quantities (LQ) 5L Transport category (TC) 3 Tunnel restriction code (TRC) D/E Hazard identification No 30 Remarks Are not subject to the requirements of ADR if packed in receptacles of not more than 450 litres capacity. « International Maritime Dangerous Goods Code (IMDG) UN number 1263 Proper shipping name PAINT Class 3 Packing group L} Danger label(s) 3 Special provisions (SP) 163, 223, 367, 955 Excepted quantities (EQ) E1 Limited quantities (LQ) 5L EmS F-E,SE Stowage category A « International Civil Aviation Organization (ICAO-IATA/DGR) UN number 1263 Proper shipping name Paint Class 3 Packing group n Danger label(s) 3 Special provisions (SP) A3, A72, A192 Excepted quantities (EQ) E1 imitad muantitine (1 AL an [SECTION 15: Régulatory information Simiismusma i s 15.1 Safety, health and environmental regulations specific for the product in question National inventories Country Inventory Status us TSCA not all ingredients are listed Legend TSCA Toxic Substance Control Act 15.2 Chemical Safety Assessment Chemical safety assessments for substances in this mixture were not carried out. ISECTION 16: Other information, including date of preparation or last revision Abbreviations and acronyms Abb Descriptions of used abbreviations 29 CFR 29 CFR 1910.1000, Tables Z-1, Z-2, Z-3 - Occupational Safety and Health Standards: Toxic and Hazardous Sub- 1910.1000 stances (permissible exposure limits) Acute Tox. Acute toxicity ADN Accord européen relatif au transport international des marchandises dangereuses par voies de navigation intérieures (European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways) ADR Accord européen relatif au transport international des marchandises dangereuses par route (European Agreement concerning the International Carriage of Dangerous Goods by Road) Asp. Tox. Aspiration hazard ATE Acute Toxicity Estimate BCF Bioconcentration factor BOD Biochemical Oxygen Demand Cal/OSHA PEL California Division of Occupational Safety and Health (CaVOSHA): Permissible Exposure Limits (PELs) CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances) Ceiling-C Ceiling value CLP Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures CMR Carcinogenic, Mutagenic or toxic for Reproduction COD Chemical oxygen demand DGR Dangerous Goods Regulations (see IATA/DGR) DMEL Derived Minimal Effect Level DNEL Derived No-Effect Level EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identifier of substances commercially available within the EU (European Union) EINECS European Inventory of Existing Commercial Chemical Substances ELINCS European List of Notified Chemical Substances EmS Emergency Schedule Eye Dam. Seriously damaging to the eye Eye Irrit. Irritant to the eye Flam. Liq. Flammable liquid GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations IATA International Air Transport Association IATAIDGR Dangerous Goods Regulations (DGR) for the air transport (IATA) ICAO International Civil Aviation Organization IMDG International Maritime Dangerous Goods Code log KOW n-Octanolwater MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant”) NLP No-Longer Polymer PBT Persistent, Bioaccumulative and Toxic: PEL Permissible exposure limit PNEC Predicted No-Effect Concentration ppm Parts per million REACH Registration, Evaluation, Authorisation and Restriction of Chemicals RID Réglement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations concern- ing the International carriage of Dangerous goods by Rail) Skin Corr. Corrosive to skin Skin Irrit. Irritant to skin STEL Short-term exposure limit STOT RE Specific target organ toxicity - repeated exposure STOT SE Specific target organ toxicity - single exposure TWA Time-weighted average VPVB Very Persistent and very Bioaccumulalive Key literature references and sources for data - Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU - Regulation (EC) No. 1272/2008 (CLP, EU GHS) Classification procedure

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP) Section Hazard class Cat- Hazard class and Hazard egory category state- ment A2 skin corrosion/irritation Cat. 2 (Skin Irrit. 2) H315 A3 serious eye damage/eye irritation Cat.2 (Eye Init. 2) H319 A9 specific target organ toxicity - repeated exposure Cat. 2 (STOTRE2) H373 B6 flammable liquid Cat.3 (Flam. Liq. 3) H226 Remarks For full text of H-phrases: see SECTION 16. The most important adverse physicochemical, human health and environmental effects Delayed or immediate effects can be expected after short or long-term exposure. The product is combustible and can be ignited by potential ignition sources. 22