CV16-2500 Part B

Hazard statements (CLP)

H315, H319

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP)] Classification of the substance or mixture

Hazard statements

see section 16 : H315 - Causes skin irritation. H319 - Causes serious eye irritation.

Hazard pictograms

GHS07

Signal word

Warning

Precautionary statements

P264 - Wash hands, forearms, and exposed areas thoroughly after handling. P280 - Wear protective clothing, protective gloves, eye protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 - Specific treatment (see Section 4 on this SDS). P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical P362+P364 - Take off contaminated clothing and wash it before reuse.

Other hazards which do not result in classification

Exposure may aggravate pre-existing eye, skin, or respiratory conditions.

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Irrit. 2 H315 Eye Irrit. 2 H319 Full text of hazard classes and H-statements : see section 16 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS07 Signal word (CLP) : Warning Hazard statements (CLP) : H315 - Causes skin irritation. H319 - Causes serious eye irritation. Precautionary statements (CLP) : P264 - Wash hands, forearms, and exposed areas thoroughly after handling. P280 - Wear protective clothing, protective gloves, eye protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 - Specific treatment (see Section 4 on this SDS). P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. 2.3. Other Hazards Other hazards not contributing : Exposure may aggravate pre-existing eye, skin, or respiratory to the classification conditions. SECTION 3: Composition/Information on Ingredients 3.1. Substances Not applicable 3.2. Mixture Name Product Identifier % Classification According to Regulation (EC) No. 1272/2008 [CLP] Silicic acid (H4SiO4), tetraethyl ester, (CAS No) 68988-57-8 30 - 50 Skin Irrit. 2, H315 reaction products with Eye Irrit. 2, H319 chlorodimethylsilane Full text of H-statements: see section 16 SECTION 4: First Aid Measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after : When symptoms occur: go into open air and ventilate inhalation suspected area. Obtain medical attention if breathing difficulty persists. First-aid measures after skin : Remove contaminated clothing. Drench affected area with contact water for at least 15 minutes. Obtain medical attention if irritation develops or persists. First-aid measures after eye : Rinse cautiously with water for at least 15 minutes. Remove contact contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention. First-aid measures after : Rinse mouth. Do NOT induce vomiting. Obtain medical ingestion attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects : Causes serious eye irritation. Causes skin irritation. Symptoms/effects after : Prolonged exposure may cause irritation. inhalation Symptoms/effects after skin : Redness, pain, swelling, itching, burning, dryness, and contact dermatitis. Symptoms/effects after eye : Contact causes severe irritation with redness and swelling of the contact conjunctiva. Symptoms/effects after : Ingestion may cause adverse effects. ingestion 4.3. Indication of any immediate medical attention and special treatment needed If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand. SECTION 5: Firefighting Measures 5.1. Extinguishing Media Suitable Extinguishing Media : Water spray, fog, carbon dioxide (CO2), alcohol-resistant foam, or dry chemical. Unsuitable Extinguishing Media : Do not use a heavy water stream. Use of heavy stream of water may spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard : Not considered flammable but may burn at high temperatures. Explosion Hazard : Product is not explosive. Reactivity : Hazardous reactions will not occur under normal conditions. Hazardous Decomposition : Silicon oxides. Carbon oxides (CO, CO2). Will decompose Products in Case of Fire above 150 °C (> 300 °F) releasing formaldehyde vapours. Formaldehyde is a potential carcinogen and can act as a skin and respiratory sensitizer. Formaldehyde can also cause respiratory and eye irritation. 5.3. Advice for Firefighters Precautionary Measures Fire : Exercise caution when fighting any chemical fire. Firefighting Instructions : Use water spray or fog for cooling exposed containers. Protection During Firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental Release Measures 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures : Avoid prolonged contact with eyes, skin and clothing. Avoid breathing (vapor, mist, spray). 6.1.1. For Non-Emergency Personnel Protective Equipment : Use appropriate personal protective equipment (PPE). Emergency Procedures : Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment : Equip cleanup crew with proper protection. Emergency Procedures : Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. 6.3. Methods and Materials for Containment and Cleaning Up For Containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods For Cleaning Up : Clean up spills immediately and dispose of waste safely. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. 6.4. Reference to Other Sections See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations. SECTION 7: Handling And Storage 7.1. Precautions for Safe Handling Precautions for Safe Handling : Avoid prolonged contact with eyes, skin and clothing. Avoid breathing vapors, mist, spray. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Hygiene Measures : Handle in accordance with good industrial hygiene and safety procedures. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures : Comply with applicable regulations. Storage Conditions : Keep container closed when not in use. Store in a dry, cool place. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Incompatible Materials : Strong acids, strong bases, strong oxidizers. 7.3. Specific End Use(s) No additional information available SECTION 8: Exposure Controls/Personal Protection 8.1. Control Parameters No additional information available 8.2. Exposure Controls Appropriate Engineering : Suitable eye/body wash equipment should be available in the Controls vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. Personal Protective Equipment : Gloves. Protective clothing. Protective goggles. Materials for Protective Clothing : Chemically resistant materials and fabrics. Hand Protection : Wear protective gloves. Eye Protection : Chemical safety goggles. Skin and Body Protection : Wear suitable protective clothing. Respiratory Protection : If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. In case of inadequate ventilation, oxygen deficient atmosphere, or where exposure levels are not known wear approved respiratory protection. Other Information : When using, do not eat, drink or smoke. SECTION 9: Physical and Chemical Hazards 9.1. Information on Basic Physical and Chemical Properties Physical State : Liquid Colour : Colourless Odour : Odourless Odour Threshold : No data available pH : No data available Evaporation Rate : No data available Melting Point : No data available Freezing Point : No data available Boiling Point : No data available Flash Point : > 135 °C (> 275 °F) Auto-Ignition Temperature : No data available Decomposition Temperature : No data available Flammability (Solid, Gas) : Not applicable Vapour Pressure : No data available Relative Vapour Density At 20 °C : No data available Relative Density : No data available Solubility : No data available Partition Coefficient n-Octanol/Water : No data available Viscosity, Kinematic : No data available Viscosity, Dynamic : No data available Explosive Properties : No data available Oxidising Properties : No data available Explosive Limits : No data available 9.2. Other Information No additional information available SECTION 10: Stability and Reactivity 10.1. Reactivity Contact with water, alcohols, acids or bases, and many metals or metallic compounds can liberate flammable Hydrogen gas which can form explosive mixtures in air. 10.2. Chemical Stability Stable at normal conditions. 10.3. Possibility Of Hazardous Reactions Evolved hydrogen gas is flammable and may form explosive mixtures with air. 10.4. Conditions To Avoid Direct sunlight, extremely high or low temperatures, and incompatible materials. 10.5. Incompatible Materials Water, alcohols, acids, bases, strong oxidizing agents, catalystic metals, metallic compounds. 10.6. Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat condition may evolve the following hazardous decomposition product: Flammable hydrogen gas. Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde SECTION 11: Toxicological Information Acute toxicity : Not classified Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity - Description : Not classified Reproductive toxicity : Not classified STOT-single exposure : Not classified STOT-repeated exposure : Not classified Aspiration hazard : Not classified SECTION 12: Ecological Information 12.1. Toxicity Ecology - General : Not classified. 12.2. Persistence and Degradability CV16-2500 Part B Persistence and Degradability Not established. 12.3. Bioaccumulative Potential CV16-2500 Part B Bioaccumulative potential Not established. 12.4. Mobility in Soil No additional information available 12.5. Results of PBT and vPvB assessment No additional information available 12.6. Other Adverse Effects Other Information : Avoid release to the environment. SECTION 13: Disposal Considerations 13.1. Waste Treatment Methods Product/Packaging Disposal : Dispose of contents/container in accordance with local, Recommendations regional, national, and international regulations. Additional Information : Container may remain hazardous when empty. Continue to observe all precautions. Ecology - Waste Materials : Avoid release to the environment. SECTION 14: Transport Information The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored, and can vary based on a number of variables that may or may not have been known at the time the SDS was issued. In accordance with ADR / RID / IMDG / IATA / AND 14.1. UN Number Not regulated for transport 14.2. UN Proper Shipping Name Not regulated for transport 14.3. Transport Hazard Class(es) Not regulated for transport 14.4. Packing Group Not regulated for transport 14.5. Environmental Hazards Not regulated for transport 14.6. Special Precautions For User No additional information available 14.7. Transport in Bulk According to Annex II of MARPOL and The IBC Code Not applicable SECTION 15: Regulatory Information 15.1. Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture 15.1.1. EU-Regulations Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances 15.1.2. National Regulations No No addit ional informat ion av ailable additional information available 15.2. Chemical Safety Assessment No chemical safety assessment has been carried out SECTION 16: Other Information Indication of Changes Section Section Header Change Date Changed 1 Identification of the Substance/mixture and of the Modified 23/06/2020 Company/Undertaking 2 Hazards Identification Modified 23/06/2020 3 Composition/Information on Ingredients Modified 23/06/2020 10 Stability and Reactivity Modified 23/06/2020 Date of Preparation or Latest Revision : 23/06/2020 Data Sources : Information and data obtained and used in the authoring of this safety data sheet could come from database subscriptions, official government regulatory body websites, product/ingredient manufacturer or supplier specific information, and/or resources that include substance specific data and classifications according to GHS or their subsequent adoption of GHS. Other Information : According to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Full Text of H- and EUH-statements: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 H315 Causes skin irritation. H319 Causes serious eye irritation. Abbreviations and Acronyms ACGIH – American Conference of Governmental Industrial Hygienists MARPOL - International Convention for the Prevention of Pollution ADN – European Agreement Concerning the International Carriage of Dangerous NDS - Najwyzsze Dopuszczalne Stezenie Goods by Inland Waterways NDSCh - Najwyzsze Dopuszczalne Stezenie Chwilowe ADR - European Agreement Concerning the International Carriage of Dangerous NDSP - Najwyzsze Dopuszczalne Stezenie Pulapowe Goods by Road NOAEL - No-Observed Adverse Effect Level ATE - Acute Toxicity Estimate NOEC - No-Observed Effect Concentration BCF - Bioconcentration Factor NRD - Nevirsytinas Ribinis Dydis BEI - Biological Exposure Indices (BEI) NTP – National Toxicology Program BOD – Biochemical Oxygen Demand OEL - Occupational Exposure Limits CAS No. - Chemical Abstracts Service Number PBT - Persistent, Bioaccumulative and Toxic CLP – Classification, Labeling and Packaging Regulation (EC) No 1272/2008 PEL - Permissible Exposure Limit COD – Chemical Oxygen Demand pH – Potential Hydrogen EC – European Community REACH – Registration, Evaluation, Authorisation, and Restriction of Chemicals EC50 - Median Effective Concentration RID – Regulations Concerning the International Carriage of Dangerous Goods by Rail EEC – European Economic Community SADT - Self Accelerating Decomposition Temperature EINECS – European Inventory of Existing Commercial Chemical Substances SDS - Safety Data Sheet EmS-No. (Fire) - IMDG Emergency Schedule Fire STEL - Short Term Exposure Limit EmS-No. (Spillage) - IMDG Emergency Schedule Spillage TA-Luft - Technische Anleitung zur Reinhaltung der Luft EU – European Union TEL TRK – Technical Guidance Concentrations ErC50 - EC50 in Terms of Reduction Growth Rate ThOD – Theoretical Oxygen Demand GHS – Globally Harmonized System of Classification and Labeling of Chemicals TLM - Median Tolerance Limit IARC - International Agency for Research on Cancer TLV - Threshold Limit Value IATA - International Air Transport Association TPRD - Trumpalaikio Poveikio Ribinis Dydis IBC Code - International Bulk Chemical Code TRGS 510 - Technische Regel für Gefahrstoffe 510 - Lagerung von Gefahrstoffen in IMDG - International Maritime Dangerous Goods ortsbeweglichen Behältern IPRV - Ilgalaikio Poveikio Ribinis Dydis TRGS 552 – Technische Regeln für Gefahrstoffe - N-Nitrosamine IOELV – Indicative Occupational Exposure Limit Value TRGS 900 - Technische Regel für Gefahrstoffe 900 – Arbeitsplatzgrenzwerte LC50 - Median Lethal Concentration TRGS 903 - Technische Regel für Gefahrstoffe 903 - Biologische Grenzwerte LD50 - Median Lethal Dose TSCA - Toxic Substances Control Act LOAEL - Lowest Observed Adverse Effect Level TWA - Time Weighted Average LOEC - Lowest-Observed-Effect Concentration VOC – Volatile Organic Compounds Log Koc - Soil Organic Carbon-water Partitioning Coefficient VLA-EC - Valor Límite Ambiental Exposición de Corta Duración Log Kow - Octanol/water Partition Coefficient VLA-ED - Valor Límite Ambiental Exposición Diaria Log Pow - Ratio of the equilibrium concentration (C) of a dissolved substance in a VLE – Valeur Limite D’exposition two-phase system consisting of two largely immiscible solvents, in this case octanol VME – Valeur Limite De Moyenne Exposition and water vPvB - Very Persistent and Very Bioaccumulative MAK – Maximum Workplace Concentration/Maximum Permissible Concentration WEL – Workplace Exposure Limit WGK - Wassergefährdungsklasse Nusil EU GHS SDS The information provided in this Safety Data Sheet (SDS) was prepared based on data believed to be accurate as of the date of this SDS. TO THE GREATEST EXTENT PERMITTED BY LAW, NUSIL TECHNOLOGY LLC AND ITS AFFILIATED COMPANIES (“NUSIL”) EXPRESSLYDISCLAIMS ANY AND ALL REPRESENTATIONS AND WARRANTIES REGARDING THE INFORMATION CONTAINED HEREIN INCLUDING, WITHOUT LIMITATION, AS TO ACCURACY, COMPLETENESS, FITNESS FOR PURPOSE OR USE, MERCHANTABILITY, NON-INFRINGEMENT, PERFORMANCE, SAFETY, SUITABILITY AND STABILITY. This SDS is intended as a guide to the appropriate use, handling, storage and disposal of the product to which it relates by properly trained personnel, and is not intended to be comprehensive. Users of NuSil’s products are advised to perform their own tests and to exercise