Nando 500SC

Nufarm UK Limited

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GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 1
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

79622-59-6

Name of the chemical

Fluazinam (ISO); 3-Chlor-N-[3-chlor-2,6-dinitro-4-(trifluormethyl)phenyl]-5-(trifluormethyl)pyridin-2-amin (605/2014)

Concentration

N/A

General Information

Product name

Nando 500SC

CAS No.

79622-59-6

1.2.1 Relevant identified uses

Fungicide

Emergency telephone

+44 (0)1274 696603

Icons in SDS

Company Information

company name

Nufarm UK Limited

e-mail address of the competent person responsible for the Safety Data Sheet

infouk@uk.nufarm.com

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H361, H361d, H400, H410, H412

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Repr.Cat.2 H361 - Suspected of damaging fertility or

2.1 Classification of the substance or mixture

the unborn child. EEC/99/45: Xi R38 - Irritating to skin. AquaticAcute1 H400 - Very toxic to aquatic life. Xi R43 - May cause sensitization by skin contact. AquaticChronic1 H410 - Very toxic to aquatic life with long Xn R63 - Possible risk of harm to the unborn child. - lasting effects.. N R50/53 - Very toxic to aquatic organisms, may cause long- Ammonium salt of polyarylphenyl ether sulphate term adverse effects in the aquatic environment. CAS-No.: 119432-41-6 EG_1272/08: SkinIrrit.2 H315 - Causes skin irritation. EINECS-No. / ELINCS No.: - SkinSens.1 H317 - May cause an allergic skin reaction. REACH No.: - Repr.2 H361d - Suspected of damaging the unborn child. Concentration: 1% - 5% (w/w) AquaticAcute1 H400 - Very toxic to aquatic life.

Classifications

AquaticChronic1 H410 - Very toxic to aquatic life with long lasting effects. EG_1272/08: EyeIrrit.2 H319 - Causes serious eye irritation.

2.2 Label elements

AquaticChronic3 H412 - Harmful to aquatic life with long REGULATION (EC) No 1272/2008 Skin contact: to lasting effects.

Hazard pictograms

4. FIRST AID MEASURES 4.1. Description of first aid measures Date: Eye contact: Rinse immediately with plenty of water for at least 15 minutes. If eye irritation persists, consult a specialist. Take off contaminated clothing and shoes immediately. Wash off immediately with soap and plenty of GHS07 GHS08 water. GHS09 Inhalation:

Signal word

Move affected person(s) into fresh air. If symptoms persist, call a physician. H315 - Causes skin irritation. SPECIMEN Ingestion: H317 - May cause an allergic skin reaction. Do NOT induce vomiting. Obtain medical attention. H361d - Suspected of damaging the unborn child. 4.2. Most important symptoms and effects, both acute and delayed H410 - Very toxic to aquatic life with long lasting effects. Symptoms: No information available. P101 - If medical advice is needed, have product container or label at hand. P302+ - IF ON SKIN: Wash with plenty of soap and water. 2016 4.3. Indication of any immediate medical attention and special treatment needed Treatment: Treat symptomatically. P352 P264 - Wash hands and face thoroughly after handling. 5. FIRE-FIGHTING MEASURES P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection. 5.1. Extinguishing media P501 - Dispose of contents/ container to a licensed hazardous-waste disposal contractor or Suitable extinguishing media: Carbon dioxide (CO2), Dry powder, Water spray collection site except for empty triple rinsed containers which can be disposed of as Extinguishing media which shall not be used for safety reasons: High volume water jet non hazardous waste. 5.2. Special hazards arising from the substance or mixture

2.3 Other hazards

Specific hazards during fire fighting: In the event of fire (HCl,Cl2,NOx,CO) may be formed. - 5.3. Advice for firefighters Special protective equipment for fire-fighters: Wear self contained breathing apparatus for fire fighting if necessary.

Further information

Standard procedure for chemical fires. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. none 6. ACCIDENTAL RELEASE MEASURES 10. STABILITY AND REACTIVITY 6.1. Personal precautions, protective equipment and emergency procedures 10.1. Reactivity Use personal protective equipment. (see Chapter 8) Stable under recommended storage conditions. 6.2. Environmental precautions 10.2. Chemical stability Do not flush into surface water or sanitary sewer system. No decomposition if stored and applied as directed. 6.3. Methods and materials for containment and cleaning up 10.3. Possibility of hazardous reactions Methods for cleaning up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, No dangerous reaction known under conditions of normal use. universal binder, sawdust). Shovel into suitable container for disposal. 10.4. Conditions to avoid Additional advice: Never return spills in original containers for re-use. No dangerous reaction known under conditions of normal use. Safe handling advice: Keep out of reach of children. Avoid contact with skin and eyes. Wear personal

TOXICOLOGICAL INFORMATION

6.4. Reference to other sections 10.5. Incompatible materials to avoid see Chapter 13 none 7. HANDLING AND STORAGE 10.6. Hazardous decomposition products No decomposition if stored and applied as directed. 7.1. Precautions for safe handling protective equipment. 11.1. Information on toxicological effects 7.2. Conditions for safe storage, including any incompatibilities Acute oral toxicity: LD50 rat female Requirements for storage areas and containers: Keep out of reach of children. Protect from frost. Store Dose: > 2,000 mg/kg in original container. Keep tightly closed in a dry, cool and well-ventilated place. Acute dermal toxicity: LD50 rat Dose: > 2,000 mg/kg 7.3. Specific end uses Acute inhalation toxicity: LC50 rat none Dose: > 0.967 mg/l 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Skin irritation: rabbit Result: Irritating to skin. 8.1. Control parameters to Testing period: 96 h Eye irritation: rabbit Result: No eye irritation - Sensitisation: Guinea-pig Result: May cause sensitization by skin contact.

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