General Information
Revision date
2024-09-27
Product name
DUPLOSAN SUPER
1.2.1 Relevant identified uses
Systemic post-emergence herbicide for use in wheat, barley, oats, grass crops
Icons in SDS
Company Information
company name
Nufarm NZ
e-mail address of the competent person responsible for the Safety Data Sheet
nzinfo@nufarm.com
GHS Information
Signal word
DANGER
Hazard Codes
Hazard statements (CLP)
H302, H317, H318, H332, H372, H402, H421, H432
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
SECTION 2: Hazards identification
GHS classification of the substance/mixture Acute oral toxicity: Category 4 Serious eye damage Category 1 Skin sensitization: Category 1 Specific target organ toxicity – repeated exposure: Category 1 Hazardous to the terrestrial environment: Hazardous to soil organisms Hazardous to the terrestrial environment: Hazardous to terrestrial vertebrates Hazardous to the terrestrial environment: Designed for biocidal action
Signal word
DANGER
Hazard statements
H302 Harmful if swallowed H332 Harmful if inhaled H317 May cause an allergic skin reaction H318 Causes serious eye damage H372 Causes damage to the organs through prolonged or repeated exposure H402 Harmful to aquatic life H421 very toxic to the soil environment H432 toxic to terrestrial vertebrates
Precautionary statements
P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P103 Read label before use P264 Wash face and hands thoroughly after handling. P273 Avoid release to the environment.
Hazard pictograms
Exclamation mark,Corrosion,Health hazard,Environment
Prevention
P270 Do not eat, drink or smoke when using this product. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
Response
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P330 Rinse mouth. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of water. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P314 Get medical advice/attention if you feel unwell. P391 Collect spillage. Precautionary P501 Dispose of contents/container to an approved landfill.
2.1 Classification of the substance or mixture
the Serious eye damage Category 1 substance/mixture Skin sensitization: Category 1 Specific target organ toxicity – repeated exposure: Category 1 Hazardous to the terrestrial environment: Hazardous to soil organisms Hazardous to the terrestrial environment: Hazardous to terrestrial vertebrates Hazardous to the terrestrial environment: Designed for biocidal action Signal Word (s) DANGER Hazard Statement (s) H302 Harmful if swallowed H332 Harmful if inhaled H317 May cause an allergic skin reaction H318 Causes serious eye damage H372 Causes damage to the organs through prolonged or repeated exposure H402 Harmful to aquatic life H421 very toxic to the soil environment H432 toxic to terrestrial vertebrates Precautionary P101 If medical advice is needed, have product container or label at hand Statement – General P102 Keep out of reach of children P103 Read label before use Pictogram (s) Exclamation mark,Corrosion,Health hazard,Environment Precautionary P264 Wash face and hands thoroughly after handling. Statement – P273 Avoid release to the environment. Prevention P270 Do not eat, drink or smoke when using this product. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.