10CL Phosphate

Medical Conditions Generally Aggravated by Exposure

OVEREXPOSURE VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Good First Aid should be followed in all cases of exposure. EYES: In case of contact, flush with plenty of water for at least 15 minutes. If irritation develops, call a physician. SKIN: Wash affected area thoroughly. Contact a physician if irritation develops. INGESTION: N/A 7 VIII - SPILL OR LEAK PROCEDURE Spill Management: Sweep up spilled material and dispose of with other solid wastes. Product is slippery when wet. Waste Disposal Methods: Disposal of product should be in adherence with above described (or similarly approved) disposal procedure. Dispose of in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Normally not required. Gloves Rubber gloves Other Clothing and Equipment: Not required. Ventilation: Normal. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Wash thoroughly after handling. Keep container closed. Exercise caution in the storage and handling of all chemical substances. Skin sensitivity, chemical allergies, heart condition. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 23 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. EYES: Flush with water for 15 minutes. If irritation persists, seek medical attention. SKIN: Wash with soap and water. If irritation persists, seek medical attention. INGESTION: Do not induce vomiting. Seek medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management: Small spill - Absorb liquid with vermiculite, floor absorbent or other absorbent material. Large spill - Evacuate area. Remove all sources of ignition. Contain liquid. Prevent run-off to sewer. Waste Disposal Methods: Dispose of spilled material in accordance with all applicable local, state and federal regulations. Wrap empty container in paper and place in trash. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not Required Eye Protection Safety goggles Gloves Rubber gloves Other Clothing and Equipment: For short usages, no safety equipment required. Ventilation: General ventilation recommended to control the level of vapors. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Keep out of the reach of children. Do not store where temperatures exceed 120°F. Wash hands before eating or smoking after using aerosol.

Additional information

Read and observe all labeled precautions NFPA Read and observe all labeled precautions NFPA Keep away from children. Do not puncture or incinerate. Do not spray near fire or open flame. NFPA Do not puncture or incinerate. Do not spray near fire or open flame. Keep away from children. NFPA Vapors are heavier than air and will collect in low areas. Use only in well-ventilated areas that will maintain air levels below limits established by federal, state, and local regulations. 16 NFPA Keep away from children. Wash with soap & water before handling food NFPA Keep away from children. Avoid food contamination. Avoid inhalation of vapors NFPA N/A NFPA Keep away from children. Do not spray near fire or open flame NFPA None NFPA NFPA Keep out of the reach of children. Avoid food contamination. Avoid breathing vapors Remove ignition sources. 32 NFPA Keep away from children. Do not puncture or incinerate. Do not spray near fire or open flame. Deliberate concentration and inhalation of vapors may be harmful or fatal. NFPA Do not puncture or incinerate. Do not spray near fire or open flame NFPA Keep out of the reach of children. Avoid food contamination. Avoid breathing vapors Remove ignition sources. NFPA Keep away from children. Do not puncture or incinerate. Do not spray near fire or open flame. Deliberate concentration and inhalation of vapors may be harmful or fatal. NFPA Keep away from children. Do not puncture or incinerate. Do not spray near fire or open flame. NFPA Use only in well ventilated areas that will maintain air levels below limits established by federal, state and local regulations. NFPA Use only in well ventilated areas that will maintain air levels below limits established by federal, state and local regulations. NFPA None NFPA None 52 NFPA NFPA This product is severely hydrotreated, and severely hydrotreated naphthenic petroleum oil has not been found to be carcinogenic nor a potential cacinogen. This product is not listed as a carcinogen or a potential carcinogen by the National Toxicology Program by the IARC monographs or by Read and observe any label precautions NFPA Read and observe any label precautions NFPA Keep out of reach of children. Read and observe all labeled precautions NFPA Keep out of reach of children. Read and observe all labeled precautions NFPA Keep container tightly closed 68 NFPA Areas of use and storage should be ventilated adequately to reduce vapors below odor level. Empty containers should be rinsed well before handling and disposal. 72 NFPA Read and observe all label precautions NFPA Read and observe all labeled precautions NFPA Read and observe all labeled precautions NFPA Read and observe all labeled precautions NFPA Keep container tightly closed NFPA Read and observe all label precautions NFPA Read and observe labeled use instructions NFPA None NFPA Vapors are heavier than air and will collect in low areas. Use only in well-ventilated areas that will maintain air levels below limits established by federal, state, and local regulations. NFPA Vapors are heavier than air and will collect in low areas. Use only in well-ventilated areas that will maintain air levels below limits established by federal, state, and local regulations. NFPA Vapors are heavier than air and will collect in low areas. Use only in well-ventilated areas that will maintain air levels below limits established by federal, state, and local regulations. 96 NFPA NFPA NFPA NFPA NFPA NFPA NFPA NFPA 114 NFPA NFPA NFPA 122 NFPA NFPA NFPA Prevent skin and eye contact. Avoid inhalation of high concentrations of mists NFPA NFPA NFPA Wash thoroughly after handling. KEEP OUT OF REACH OF CHILDREN NFPA Wash thoroughly after handling NFPA Keep out of reach of children. Read and observe all labeled precautions NFPA None NFPA None NFPA Clean equipment with water NFPA Keep out of the reach of children 148 NFPA Keep out of the reach of children NFPA Read and observe all labeled precautions NFPA Read and observe all labeled precautions NFPA Wash thoroughly after handling. KEEP OUT OF REACH OF CHILDREN NFPA Read and observe all label precautions NFPA Keep out of the reach of children NFPA Do not wear contaminated clothing. Launder before re-use or discard. Do not take any food or drink, or handle tobacco products while in contact with this product. Wash thoroughly after use. NFPA Do not wear contaminated clothing. Launder before re-use or discard. Do not take any food or drink, or handle tobacco products while in contact with this product. Wash thoroughly after use. NFPA Do not wear contaminated clothing. Launder before re-use or discard. Do not take any food or drink, or handle tobacco products while in contact with this product. Wash thoroughly after use. NFPA Do not wear contaminated clothing. Launder before re-use or discard. Do not take any food or drink, or handle tobacco products while in contact with this product. Wash thoroughly after use. NFPA No component known to be present in this product at >0.1% is presently listed as a carcinogen by IARC NTP or Do not wear contaminated clothing. Launder before re-use or discard. Do not take any food or drink, or handle tobacco products while in contact with this product. Wash thoroughly after use. NFPA Do not wear contaminated clothing. Launder before re-use or discard. Do not take any food or drink, or handle tobacco products while in contact with this product. Wash thoroughly after use. NFPA Read and observe all label precautions NFPA None NFPA None NFPA Follow label directions. Keep away from heat sources. Keep out of reach of children Keep container tightly sealed. NFPA Use only in well ventilated areas that will maintain air levels below limits established by federal, state and local regulations. Read and observe all labeled precautions. NFPA Use only in well ventilated areas that will maintain air levels below limits established by federal, state and local regulations. Read and observe all labeled precautions. NFPA Do not use this product to clean unvented systems. Carbon dioxide gas released in the cleaning process may build pressure in system causing rupture or explosion. NFPA Do not use this product to clean unvented systems. Carbon dioxide gas released in the cleaning process may build pressure in system causing rupture or explosion. NFPA Read and observe all labeled precautions NFPA Read and observe all labeled precautions NFPA This is a complete product. Do not add or mix with other chemicals NFPA This is a complete product. Do not add or mix with other chemicals NFPA Read and observe all labeled precautions NFPA Avoid contact with the eyes, skin or clothing. Keep container closed. Wash thoroughly after handling. Avoid breathing vapors. NFPA Mix only with water. Use clean, dry utensils and equipment. Do not mix with other chemicals. Such use may cause violent reaction. NFPA Keep out of the reach of children. Avoid food contamination. Avoid inhalation of vapors NFPA None NFPA (Carcinogenicity) Results from a lifetime inhalation study in rats indicate that MDI aerosol was carcinogenic at 6 mg/m3, the highest dose tested. This is well above the recommended TLV of 5 ppb (0.05 mg/m3). Only irritation was noted at the lower concentration of 0.2 and 1 mg/m3. 212 NFPA Follow label directions. Keep out of reach of children. Keep container tightly sealed when not in use. Do not contaminate water, food, or feed by use or storage. NFPA Keep out of the reach of children NFPA 220 NFPA Keep away from heat, sparks and flames. Do not take internally. For use by service personnel only. NFPA Do not store at temperatures above 120°F. Odor is not an adequate warning of potentially hazardous concentrations in air. Releases of these gases may cause a flammable atmosphere with explosion potential., 226 NFPA Caution should be used to avoid contact with eyes or prolong contact with skin. Wash thoroughly after handling. If ingested call a physician immediately. NFPA Keep away from heat, sparks. Wash hands after handling. Read and observe all label precautions. NFPA Read and observe all label precautions NFPA NFPA

Health hazards

0 0 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 8 A 6R Micromet I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: 6R Micromet Product Number: 4265 Synonyms: Inorganic Sodium Calcium Magnesium Phosphate II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL According to the 0 0 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 10 A Aerosol Adhesive I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Adhesive Product Number: 4080 Synonyms: General Purpose Adhesive II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # hexane (STEL 1000ppm) 110-54-3 < 50 50ppm Acetone 67-64-1 < 25 750ppm 1000ppm Isobutane/propane blend (STEL 74-98-6 < 25 1000ppm NE) 75-28-5 800ppm # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure @70°F 55 psig Vapor Density (Air=1) 60-90° F: >1 Evaporation Rate (ether=1) <1 VOC Content (% by wt.): 85 Solubility in H₂O: Negligible pH @ 1% Solution: N/AV Freezing Point °F: N/AV pH as Distributed: N/AV Boiling Point °F: Propellant 43.7 Appearance: Cream-colored liquid Specific Gravity H₂O=1 @25° C: Propellant 43.7 Odor: Fruity odor IV - FIRE AND EXPLOSION Flash Point F (non-aerosols) N/A Flammable Limits LEL N/E UEL N/E Extinguishing Media: Carbon dioxide, dry chemical or foam. Special Fire Fighting Procedures: Water may be used to keep fire exposed containers cool. Wear self-contained breathing apparatus. Unusual Fire and Explosion Hazards: Do not spray near open flame. Keep at room temperature as exposure to direct sunlight or other heat may cause bursting. Vapors can accumulate in low places and be ignited by source distant from point of release. V - REACTIVITY DATA Stability - Conditions to avoid: Heat, sparks, sunlight, flame. Incompatibility: Oxidizers Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INHALATION May irritate upper respiratory system. Vapors in high concentration may produce light-headedness, headache, dizziness, anesthesia, unconsciousness. EYES & SKIN: Causes irritation. INGESTION: Harmful or fatal if swallowed. B. SUBCHRONIC, CHRONIC, OTHER: Prolonged skin exposure may cause dermatitis. Repeated exposure to hexane has been associated with nervous system damage. Reports have associated repeated and prolonged overexposure to solvents with permanent brain, nervous system, kidney and liver damage. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 11 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. If symptoms persist, get medical attention. EYES: Flush with copious amounts of water. If irritation persists, see a physician. SKIN: Wash area with soap and plenty of water. Remove and launder contaminated clothing before reuse. INGESTION: Call a physician at once. Do NOT induce vomiting. VIII - SPILL OR LEAK PROCEDURE Spill Management: Remove all sources of ignition. Ventilate, avoid breathing vapors. Remove with inert absorbent for incineration. Waste Disposal Methods: Do not incinerate containers. Dispose of in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH-approved respirator with vapor cartridge if levels are exceeded. Eye Protection Safety glasses with sideshields Gloves Nitrile or neoprene Other Clothing and Equipment: None Given. Ventilation: Local exhaust is recommended; general may be needed in low areas. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not store above 120°F. Keep at room temperature as exposure to direct sunlight or heat may cause bursting. 2 2 Fire Hazard................: 3 Fire Hazard .................. : 3 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 12 A Aerosol CalClean I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol CalClean Product Number: 4081 Synonyms: Detergent Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Metasilicate 6834-92-0 5 NE Isobutane 75-28-5 <7 800ppm Propane 74-98-6 <7 1000ppm All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg 25-35 psig Vapor Density (Air=1) 60-90° F: Heavier Evaporation Rate (ether=1) N/A VOC Content (% by wt.): 7 Solubility in H₂O: Completely pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: N/A Appearance: N/A Specific Gravity H₂O=1 @25° C: 1.08 Odor: N/A IV - FIRE AND EXPLOSION Flash Point F (non-aerosols) N/A Flammable Limits Non-flammable per USA Flame Projection Test for aerosols Extinguishing Media: Carbon dioxide, dry chemical or foam. Special Fire Fighting Procedures: Water may be ineffective. Water may be used to keep fire exposed containers cool. Unusual Fire and Explosion Hazards: Do not spray near open flame. Keep at room temperature as exposure to direct sunlight or other heat may cause bursting. V - REACTIVITY DATA Stability - Conditions to avoid: Do not store above 120°F Incompatibility: N/AV Hazardous Decomposition Products By open flame Carbon monoxide, Carbon dioxide Conditions Contributing to Hazardous Polymerizations: Will not occur VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES, SKIN & INHALATION In a confined area vapors in high concentration are anesthetic. Irritant to skin and upper respiratory system. Over exposure may result in light- headedness, staggering gait, giddiness and possible nausea. INGESTION: Harmful or fatal if swallowed. B. SUBCHRONIC, CHRONIC, OTHER: None Known. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 13 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove patient to fresh air. If symptoms persist, get medical attention. EYES: Flush with water for at least 15 minutes. If irritation develops, get medical attention. SKIN: Wash with soap and water. INGESTION: Call physician immediately. Do NOT induce vomiting. VIII - SPILL OR LEAK PROCEDURE Spill Management: Remove all sources of ignition, ventilate. Avoid breathing vapors and remove with inert absorbent. Waste Disposal Methods: Do not incinerate. Replace protective cap and discard in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Avoid breathing of vapor or spray mist. Eye Protection Safety glasses Gloves Rubber Other Clothing and Equipment: N/AV Ventilation: Local exhaust ventilation in volume and pattern to keep air levels below acceptable limits X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not store above 120°F. Keep at room temperature as exposure to direct sunlight or other heat may cause bursting 0 0 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 14 A Aerosol Degreasing Solvent ef I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Degreasing Solvent ef Product Number: 4083-75 Synonyms: Chlorinated Hydrocarbon Solvent II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Stoddard Solvent* (ORAL LD50 > 8052-41-3 60 100ppm 0 ppm 10mg/kg) 98-56-6 <10 N/A p-Chlorobenzotrifluoride(a) 95-49-8 <25 50 ppm 250 ppm o-Chlorotoluene 127-18-4 <15 25 ppm Perchloroethylene(b,c,d,e,f,g) 75-28-5 <5 800 ppm Isobutane/Propane Blend 74-98-6) 1000 ppm *STEL=200pp a) This item is not identified in the available haz. chemicals guides. However, its characteristics parallel hazards of material that is identified; herefore, it will be so identified until further identification. b) Ingredient subject to reporting under Sec. 313 of Title III (SARA) and 40 CFR 372. c) RCRA has determined that the waste for this chemical is listed as hazardous and must be handled in accordance with 40 CFR 260-281. d) 1 2 Fire Hazard................: 2 Fire Hazard .................. : 3 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 17 18 A Aerosol Electrical Contact Cleaner I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Electrical Contact Cleaner Product Number: 4082 Synonyms: Aerosol Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Isopropanol 67-63-0 5-15 % 400 ppm 500 ppm 2-Methylpentane 107-83-5 43-48% 500 ppm 3-Methylpentane 96-14-0 20-25% 500 ppm 2,3 Dimethylbutane 79-29-8 10-15% 500 ppm 2,2 Dimethylbutane 75-83-2 >0.01% 500 ppm Carbon Dioxide 124-38-9 2-6% 5000 ppm n-Hexane# 110-54-3 1-3% 50 ppm # Ingredient subject to reporting under Section 313 of Title III (SARA) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: Psig@70°F(aero.)80-100 Vapor Density (Air=1) 60-90° F: N/E Evaporation Rate: N/E VOC Content (% by wt.): 100 Solubility in H₂O: None pH @ Solution: N/AV Freezing Point °F: N/A pH as Distributed: N/AV Boiling Point °F: N/A Appearance: Clear, forceful spray Specific Gravity H₂O=1 @25° C: Concentrate Only = Odor: Aliphatic solvent odor 0.667 IV - FIRE AND EXPLOSION Flash Point F: Flash Point not established; FLAMMABILITY as per USA FLAME PROJECTION TEST for aerosols: EXTREMELY FLAMMABLE Flammable Limits: N/A N/A Extinguishing Media: Foam, Dry Chemical, Carbon Dioxide Special Fire Fighting Procedures: Self-contained breathing apparatus. Unusual Fire and Explosion Hazards: Do not expose aerosols to temps. above 130°F, container may rupture. V - REACTIVITY DATA Stability - Conditions to avoid: Stable - Open flame, welding arcs, heat & sparks. Incompatibility: Strong oxidizing agents. Hazardous Decomposition Products: Carbon dioxide & carbon monoxide Conditions Contributing to Hazardous Polymerizations: Will not occur. 19 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INHALATION Excessive inhalation of vapors can cause nasal & respiratory irritation, weakness, nausea, headache, dizziness, asphyxia and possible unconsciousness. EYES: Slight irritation. SKIN Slight irritation due to defatting of skin. INGESTION Irritation B. SUBCHRONIC, CHRONIC, OTHER: (Effects due to excessive exposure to the raw materials of this mixture) Excessive inhalation may result in central nervous system effects. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: May aggravate existing eye, skin or upper respiratory conditions. VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Resuscitate if necessary. Get medical attention. EYES: Flush with water for 15 minutes. If irritation persists, see a physician. SKIN: Wash area with soap and plenty of water. If irritated, seek medical attention. INGESTION: DO NOT INDUCE VOMITING. Drink two large glasses of water. Get medical attention immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Absorb with suitable medium. Incinerate or landfill according to local, state or Federal regulations. DO NOT FLUSH TO SEWER. Waste Disposal Methods: Aerosol cans when vented to atmospheric pressure through normal use, pose no disposal hazard. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: If vapor concentration exceeds TLV, use respirator approved by NIOSH for organic vapor. Eye Protection Safety glasses Gloves Neoprene Other Clothing and Equipment: None. Ventilation: Adequate ventilation to keep vapor concentration below TLV. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not store above 130°F. Do not puncture or incinerate containers. 2 2 Fire Hazard................: 3 Fire Hazard .................. : 3 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 20 A Aerosol EM Degreasing Solvent I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol EM Degreasing Solvent Product Number: 4083 Synonyms: Aerosol Motor Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL trichloroethylene 79-01-6 <55 50 ppm perchloroethylene 127-18-4 25 ppm # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. WARNING This product contains a chemical or chemicals known to the State of California to cause cancer. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure @20°C 85-100 psig Vapor Density (Air=1) 60-90° F: N/E Evaporation Rate: 2.1 concentrate only VOC Content (% by wt.): 100 Solubility in H₂O: Insoluble pH @ Solution: N/AV Freezing Point °F: N/AV pH as Distributed: N/AV Boiling Point °F: N/A Appearance: Clear, colorless spray Specific Gravity H₂O=1 @25° C: 1.6 Odor: Chlorinated solvent odor IV - FIRE AND EXPLOSION Flash Point F propellant <20°F Flammable Limits N/E N/E Extinguishing Media: CO₂, foam, dry chemical Special Fire Fighting Procedures: Self contained breathing apparatus. Unusual Fire and Explosion Hazards: Do not expose aerosols to temperatures above 130°F or the container may rupture. V - REACTIVITY DATA Stability - Conditions to avoid: Stable - Open flame, high temperatures, welding arcs. Incompatibility: Reactive metals aluminum, magnesium, strong oxidizing agents. Hazardous Decomposition Products: CO₂, CO, HCI, small amounts of phosgene and chlorine. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INHALATION Excessive inhalation of vapors can be harmful and may cause headaches, dizziness, asphyxia, anesthetic effects and possible unconsciousness. EYES: Irritation SKIN: Irritation due to defatting of skin. INGESTION: Possible chemical pneumonitis if aspirated into lungs. Nausea. B. SUBCHRONIC, CHRONIC, OTHER: (Effects due to excessive exposure to the raw materials of this mixture) May cause liver abnormalities, kidney, spleen, lung or brain damage, cardiac abnormalities. Perchlorethylene has been shown to increase the rate of spontaneously occurring malignant tumors in certain laboratory rats and mice. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 21 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Resuscitate of necessary. Get medical attention. EYES: Flush with water for 15 minutes. If irritation persists, see a physician. SKIN: Wash area with soap and plenty of water. If irritated, seek medical attention. INGESTION: DO NOT INDUCE VOMITING. Drink two large glasses of water. Get immediate medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management: Absorb with suitable medium. Incinerate or landfill according to local, state or Federal regulations. Allow to evaporate if small spill. DO NOT FLUSH TO SEWER. Waste Disposal Methods: Aerosol cans when vented to atmospheric pressure through normal use, pose no disposal hazard. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: If vapor concentration exceed TLV, use respirator approved by U. S. Bureau of Mines for organic vapor. Eye Protection Safety glasses Gloves Neoprene Other Clothing and Equipment: None. Ventilation: Adequate ventilation to keep vapor concentration below TLV. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not store above 130°F. Do not puncture or incinerate containers. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 22 A Aerosol Evap Foam No Rinse I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Evap Foam No Rinse Product Number: 4171 Synonyms: Aerosol Coil Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Diethylene glycol monoethyl ether* 111-90-0 2.0 N/E Ethylene glycol monobutyl ether* 111-76-2 2.0 25 ppm 50 ppm Propellant 68956-79-6 5.0 1000 ppm 2 2 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 24 A Aerosol Food Grade Silicone I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Food Grade Silicone Product Number: 4084 Synonyms: Aerosol Lubricant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Poly-Dimethylsiloxane 63148-62-9 4-12 N/E Hexane 110-54-3 40-50 50ppm Isobutane/propane blend 75-28-5; 40-50 800 ppm 74-98-6 2 2 Fire Hazard................: 4 Fire Hazard .................. : 4 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 26 A Aerosol Nu-Kill I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Nu-Kill Product Number: 4292 Synonyms: (Aerosol) Pesticides - Wasp & Hornet EPA Regis. No. 10807-48-65516 EPA Est. No. 10807-GA-1 II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Acetone 67-64-1 <10 350ppm Pyrethrin 8003-34-7 <5 5mg/m3 Isopropanol 67-63-0 <5 400ppm 500 ppm Insecticide Concentrate: 0.5 114-26-1 <5 0.5mg/M3 propoxur ** 51-03-6 N/E Piperonyl butoxide, Technical ** 113-48-4 N/E N-octyl bicycloheptene dicarboxuimide ** SARA III Listed All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg N/A Vapor Density (Air=1) 60-90° F: >air Evaporation Rate (ether=1) >ether VOC Content (% by wt.): 99 Solubility in H₂O: Insoluble pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: N/A Appearance: Pesticides Specific Gravity H₂O=1 @25° C: 0.7819 Odor: Pesticides IV - FIRE AND EXPLOSION Flash Point F N/A Flammable Limits N/A Extinguishing Media: Carbon dioxide, dry chemical or foam. Special Fire Fighting Procedures: Water may be ineffective. Water may be used to keep fire exposed containers cool. Unusual Fire and Explosion Hazards: Do not spray near open flame or expose to temperatures above 130°F. Keep at room temperature as exposure to direct sunlight or other heat may cause bursting. V - REACTIVITY DATA Stability - Conditions to avoid: Stable - Overexposure in confined area. Open flame,welding arcs, extreme heat, sparks Incompatibility: Alkaline materials and water Hazardous Decomposition Products By open flame Carbon Monoxide, Carbon Dioxide, Conditions Contributing to Hazardous Polymerizations: Will not occur. 27 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), A. ACUTE (Primary Route of Exposure): In a confined area vapors in high concentration are anesthetic. Irritant to skin and upper respiratory system. Over-exposure may result in headache, dizziness, asphyxia, anesthetic effects, and possible unconsciousness. Irritant to eyes and skin. Possible chemical pneumonitis if aspirated into lungs. Nausea. B. SUBCHRONIC, CHRONIC, OTHER: Repeated and prolonged overexposure (to raw materials) may cause cardiac abnormalities, central nervous system depression, lung, kidney, liver damage; inhibits cholinesterase. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Resuscitate if necessary; seek medical attention EYES: Flush with water for at least 15 minutes; if irritated, seek medical attention. SKIN: Flush with soap and water for at least 15 minutes; if irritated, seek medical attention. INGESTION: GET MEDICAL ATTENTION IMMEDIATELY. Atropine sulfate is antidote. Treat like typical organic phosphate poisoning. Induce vomiting only at physician's recommendation. VIII - SPILL OR LEAK PROCEDURE Spill Management: Remove all sources of ignition, ventilate, avoid breathing vapors. Remove with inert absorbents. Waste Disposal Methods: Do not incinerate - dispose of in accordance with federal, state and local regulations regarding pollution. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Avoid breathing vapor or spray mist. Eye Protection Safety glasses Gloves Disposable Other Clothing and Equipment: Protective gloves for prolonged or repeated contact. Use gloves recommended by glove supplier for protection against materials in Section II. Ventilation: Provide local exhaust ventilation in volume and pattern to keep TLV of all hazardous ingredients in Section II below acceptable limit, and LEL in Section II below stated limit. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not store above 120°F. Keep at room temperature to avoid bursting. Keep away from children. Do not puncture or incinerate. Do not spray near fire or open flame. 2 2 Fire Hazard................: 3 Fire Hazard .................. : 3 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 28 A Aerosol Nu-Kill II I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Nu-Kill II Product Number: 4292-75 Synonyms: Aerosol Wasp & Hornet Spray EPA Regis. No. 10807-196-65516 EPA Est. No. 10807-GA-1 II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Petroleum Distillate 64742-47-8 N/E **Tetramethrin (0.1-0.2%) 7696-12-0 N/E **Permethrin (0.1-0.4%) 52645-53-1 N/E **Piperonyl Butoxide 51-03-6 N/E **This ingredient is SARA III listed. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure @ 70°F (Aerosols) 85-100 Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: N/A VOC Content (% by wt.): N/A Solubility in H₂O: None pH @ Solution: N/A Freezing Point °F: pH as Distributed: N/A Boiling Point °F: N/A Appearance: Jet stream spray Specific Gravity H₂O=1 @25° C: 0.80 Odor: Petroleum distillate IV - FIRE AND EXPLOSION Flash Point F N/A Flammable Limits Per USA Flame Projection Test (aerosols) Non Flammable Extinguishing Media: Carbon dioxide, dry chemical or foam. Special Fire Fighting Procedures: Self-contained breathing apparatus Unusual Fire and Explosion Hazards: Do not spray near open flame or expose to temperatures above 130°F. or container may burst. V - REACTIVITY DATA Stability - Conditions to avoid: Stable - Overexposure in confined area. Open flame,welding arcs, extreme heat, sparks. Incompatibility: Strong oxidizing agents Hazardous Decomposition Products: CO₂, CO Conditions Contributing to Hazardous Polymerizations: Will not occur 29 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), A. ACUTE (Primary Route of Exposure): In a confined area vapors in high concentration are anesthetic. Irritant to eyes and skin; may cause mild defatting of skin. Irritant to upper respiratory system. Excessive inhalation of vapors can be harmful and may cause headache, dizziness, anesthetic effects, respiratory depression, cholinesterase depression and nausea. B. SUBCHRONIC, CHRONIC, OTHER: Repeated and prolonged overexposure (to raw materials) may cause cardiac abnormalities, central nervous system depression, lung, kidney, liver damage; inhibits cholinesterase. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: May aggravate existing eye, skin or upper respiratory conditions. VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Resuscitate if necessary; seek medical attention EYES: Flush with water for at least 15 minutes; if irritated, seek medical attention. SKIN: Flush with soap and water for at least 15 minutes; if irritated, seek medical attention. INGESTION: DO NOT INDUCE VOMITING. Drink two large glasses of water. Get immediate medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management: Absorb with suitable medium. Dispose of in accordance with local, state or federeal regulations. Do not flush to sewer. Waste Disposal Methods: Aerosol cans when vented to atmosphereic pressure through normal use pose no disposal hazard. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Avoid breathing vapor or spray mist. Eye Protection Safety glasses Gloves Rubber gloves Other Clothing and Equipment: Protective gloves for prolonged or repeated contact. Use gloves recommended by glove supplier for protection against materials in Section II. Ventilation: Provide local exhaust ventilation in volume and pattern to keep TLV of all hazardous ingredients in Section II below acceptable limit. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not store above 120°F. Keep at room temperature to avoid bursting. Keep away from children. Do not puncture or incinerate. Do not spray near fire or open flame. 1 1 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 30 A Aerosol Pan-Spray I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Pan-Spray Product Number: 4296 Synonyms: II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Hydrocarbon Propellant 68476-86-8 800 Dichloromethane 75-09-2 25 500 n-Tallowalkyl Trimethylene 61791-53-5 N/E Diamines Ole. N/E Petroleum Asphalt Dichloromethane is on Sara 313 List All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: PSIG @ 70°F (Aerosols) N/D Vapor Density (Air=1) 60-90° F: N/D Evaporation Rate: N/E VOC Content (% by wt.): Solubility in H₂O: Nil pH @ Solution: Freezing Point °F: N/E pH as Distributed: N/E Boiling Point °F: N/E Appearance: White ashphalt Specific Gravity H₂O=1 @25° C: Odor: Asphalt IV - FIRE AND EXPLOSION Flash Point F Level 2 Flammable Limits Lower - 1.0 Upper - 6.0 Extinguishing Media: Foam, dry chemical, carbon dioxide, water Special Fire Fighting Procedures: Use water spray to cool fire exposed surfaces and to protect personnel, isolate "fuel" supply from fire. Avoid spraying water directly into storage containers due to danger of boil over. This liquid is volatile and gives off invisible vapors. Either the liquid or vapor may settle in low areas or travel some distance along the ground or surface to ignition sources where they may ignite or explode. Unusual Fire and Explosion Hazards: Contents under pressure. Do not expose aerosols to temperatures above 130°F or the container may rupture. V - REACTIVITY DATA Stability - Conditions to avoid: Stable - Open flame, welding arcs, heat. Incompatibility: Strong oxidizers Hazardous Decomposition Products: Carbon Monoxide, carbon dioxide Conditions Contributing to Hazardous Polymerizations: Will not occur 31 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INHALATION Excess inhalation may produce symptoms of central nervous system depression, ranging from light-headedness, nausea and vomiting, to unconsciousness and death. EYES An irritant of the eyes, causing pain, lacrimation and general inflammation. SKIN Mildly irritationg to the skin. Skin contact may produce burning sensation - prolonged or repeated contact may cause skin to become reddened, rough, and dry due to removal of natural oils and may result in dermatitis. INGESTION: May cause irritation fo the gastrointestinal tract with vomiting. If vomiting results in aspiration, chemical pneumonia may follow. Absorption through the gastrointestinal tract may produce symptoms of central nervous system depression ranging from light headedness to unconsciousness. B. SUBCHRONIC, CHRONIC, OTHER: Can cause headaches, mental confusion, depression, fatique, loss of sense of balance, and visual disturbances. Excessive exposure may cause cardiac arrhythmias, carboxyhemoglobinemia, liver and kidney effects. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: May aggravate existing eye, skin or upper respiratory conditions. VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. EYES: Irrigate with flowing water immediately and continously for 15 minutes. Consult medical personnel. SKIN: Wash off in flowing water or shower. INGESTION: DO NOT INDUCE VOMITING. Call a physician and/or transport to emergency facility immediately. NOTE TO PHYSICIAN: Because rapid absorption may occur through lungs if aspirated and cause systemic effects, the decision of whether to induce vomiting or not should be made by a physician. If lavage if performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. Exposure may increase "myocardial irritability". Do not administer sympathominetic drugs unless absolutely necessary. VIII - SPILL OR LEAK PROCEDURE Spill Management: Clean up area by mopping or with absorbent materials and place in closed container for 1 1 Fire Hazard................: 3 Fire Hazard .................. : 3 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 33 34 A Aerosol Penetrating Lubricant I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Penetrating Lubricant Product Number: 4085 Synonyms: Aerosol Lubricant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # 2-butoxyethanol 111-76-2 <60 25 ppm Isobutane/propane blend 75-28-5 <5 800 ppm 74-98-6 <15 1000 ppm Aliphatic Petroleum Distillate 64742-96-7 <15 100 ppm Petroleum Distillate 64742-52-5 5mg/M3 # Ingredient subject to reporting under Section 313 of Title III (SARA) and CRF 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: 50-60 psig @20°C Vapor Density (Air=1) 60-90° F: >1 Evaporation Rate: (BuAc=1) Faster VOC Content (% by wt.): N/AV Solubility in H₂O: Negligible pH @ Solution: N/AV Freezing Point °F: N/AV pH as Distributed: N/AV Boiling Point °F: Propellant -43.7 Appearance: Pale yellow liquid Specific Gravity H₂O=1 @25° C: 1.08 Odor: Hydrocarbon odor IV - FIRE AND EXPLOSION Flash Point F Propellant <20°F (TCC) Flammable Limits LEL 1.8 UEL 25 Extinguishing Media: CO₂, dry chemical, foam. Special Fire Fighting Procedures: Water may be ineffective. Water may be used to keep fire exposed containers cool. Unusual Fire and Explosion Hazards: Do not spray near open flame. Keep at room temperature as exposure to direct sunlight or other heat may cause bursting. V - REACTIVITY DATA Stability - Conditions to avoid: Do not store above 120°F. Incompatibility: Strong oxydizers, aluminum. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES-SKIN-INHALATION & INGESTION In a confined area, vapors in high concentration are anesthetic. Irritant to eyes, skin and upper respiratory system. Overexposure may result in light-headedness, staggering gait, giddiness and possible nausea. Contains petroleum distillates. Harmful or fatal if swallowed. B. SUBCHRONIC, CHRONIC, OTHER: Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage, also kidney and liver damage. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 35 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove patient to fresh air. EYES: Flush with water for at least 15 minutes. SKIN: Wash with soap and water. INGESTION: Call a physician immediately. Do NOT induce vomiting. VIII - SPILL OR LEAK PROCEDURE Spill Management: Remove all sources of ignition. Ventilate, avoid breathing vapors and remove with inert absorbent. Waste Disposal Methods: Do not incinerate. Recap container and discard in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Avoid breathing vapor or spray mist. Eye Protection Safety glasses with sideshield. Gloves Solvent resistant gloves recommended Other Clothing and Equipment: None. Ventilation: Local exhaust is recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not store above 120°F. Keep at room temperature as exposure to direct sunlight or heat may cause bursting. 1 1 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 36 A Aerosol Pump Protector I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Pump Protector Product Number: 4299 Synonyms: Lubricating coating for pumps II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL propylene glycol 57-55-6 <20 50ppm NE isobutane 75-28-5 <5 1000ppm propane 74-98-6 <5 1000pp, 1000ppm VOC Content: 24.38% By Weight All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure @20°F 50-60 psig Vapor Density (Air=1) 60-90° F: >1 Evaporation Rate (ether=1) <1 VOC Content (% by wt.): 27 Solubility in H₂O: Soluble pH @ Solution: N/AV Freezing Point °F: N/AV pH as Distributed: N/AV Boiling Point °F: -43.7 (propellant) Appearance: White foam Specific Gravity H₂O=1 @25° C: 0.839 Odor: Typical IV - FIRE AND EXPLOSION Flash Point F Propellant < 0°F Flammable Limits LEL 1.8 UEL 16 Extinguishing Media: CO₂, foam, dry chemical. Special Fire Fighting Procedures: Firefighters should wear self-contained breathing apparatus operated under positive pressure. Unusual Fire and Explosion Hazards: Exposure to direct sunlight or temperatures over 120°F may cause bursting, releasing highly flammable gas. V - REACTIVITY DATA Stability - Conditions to avoid: Stable, avoid extreme heat. Incompatibility: Strong oxidizers. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide Conditions Contributing to Hazardous Polymerizations: Will not occur VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INHALATION Excessive inhalation can cause nasal and respiratory irritation, dizziness, unconsciousness and asphyxiation. SKIN Moderately irritating. EYES Severe eye irritant, INGESTION: Nausea, vomiting, diarrhea. B. SUBCHRONIC, CHRONIC, OTHER: Use of solvents has been connected with cardiac abnormalities, liver, kidney and lung damage. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 37 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. If symptoms persist, get medical attention. EYES: In case of eye contact, flush with water for at least 15 minutes. If irritation persists, get medical attention. SKIN: For skin contact, wash thoroughly with soap and water. INGESTION: Do not induce vomiting. Get immediate medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management: Eliminate sources of ignition. Ventilate area. Soak up on absorbant material for disposal. Waste Disposal Methods: Dispose of in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: With organic vapor canister if ventilation is poor. Eye Protection Safety glasses Gloves Solvent resistant Other Clothing and Equipment: Not normally required. Ventilation: Local exhaust is recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not store above 120°F or in direct sunlight. Keep away from children. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 38 A Aerosol Spray-n-Bond I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Spray-n-Bond Product Number: 4369 Synonyms: Insulation Adhesive II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Acetone 67-64-1 750 1000 Hexane 110-54-3 50 Isobutane/Propane Blend 75-28-5 800 74-98-6 1000 No ingredients are on the SARA 313 List All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure psig@70°F (aerosols) max 80 Vapor Density (Air=1) 60-90° F: N/E Evaporation Rate: N/E VOC Content (% by wt.): Solubility in H₂O: Partial pH @ Solution: Freezing Point °F: N/E pH as Distributed: N/E Boiling Point °F: N/E Appearance: Straw colored liquid Specific Gravity H₂O=1 @25° C: 0.853 (conc. only) Odor: Keytone solvent IV - FIRE AND EXPLOSION Flash Point F Extremely Flammable Flammable Limits N/E Extinguishing Media: Foam, dry chemical, carbon dioxide, water Special Fire Fighting Procedures: Self-contained breathing apparatus. Use water fog to cool containers to prevent rupturing & exploding containers. Provide shielding for persoonel. Unusual Fire and Explosion Hazards: Do not expose aerosol to temperatures above 130°F or the containers may rupture. V - REACTIVITY DATA Stability - Conditions to avoid: Stable - Open flame, welding arcs, heat, sparks Incompatibility: strong oxidizing agents Hazardous Decomposition Products: carbon monoxide, carbon dioxide Conditions Contributing to Hazardous Polymerizations: Will not occur VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INHALATION Excessive inhalation of vapors can cause nasal & respiratory irritation, izziness, weakness, nausea, headache, possible unconsciousness or asphyxiation EYES: May be irritating to eyes SKIN May be irritating due to defatting of skin INGESTION Possible chemical pneumonitis if aspirated into lungs B. SUBCHRONIC, CHRONIC, OTHER: (Excessive exposure to raw materials.) Excessive inhalation of hexane may cause nerve damage C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: May aggravate existing eye, skin or upper respiratory conditions 39 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Resuscitate if necessary. Get medial attention. EYES: Flush with water for 15 minutes. If irritated, seek medical attention. SKIN: Wash with soap and water. If irritated, seek medical attention. INGESTION: DO NOT INDUCE VOMITING Drink two large glasses of water. Get immediate medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management: Absorb with suitable medium. Incinerate or landfill according to local, state or federal regulations. Do not flush to sewer. Waste Disposal Methods: Aerosol cans when vented to atmospheric pressure through normal use pose no disposal hazard. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: If vapor concentration exceeds TLV, use respirator approved by NIOSH in positive pressure mode Eye Protection Safety glasses recommended Gloves Neoprene Other Clothing and Equipment: None Ventilation: Adequate ventilation to keep vapor concentration belowTLV. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not puncture or incinerate containers. Do not store at temperatures above 130oF. 2 Fire Hazard................: Fire Hazard .................. : 3 Reactivity ..................: Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 40 A Aerosol V-Belt Dressing I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol V-Belt Dressing Product Number: 4086 Synonyms: Aerosol Coating II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL hexane 110-54-3 <80 50 ppm polybutenes 9003-29-6 <10 N/E propane 74-98-6 <10 1000 ppm Isobutane 75-28-5 800 ppm # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: 50-60 psig @20°C Vapor Density (Air=1) 60-90° F: >1 Evaporation Rate: (BuAc=1) 2.48 VOC Content (% by wt.): 96 Solubility in H₂O: Negligible pH @ Solution: N/AV Freezing Point °F: N/AV pH as Distributed: N/AV Boiling Point °F: N/AV Appearance l clear, colorless liquid Specific Gravity H₂O=1 @25° C: 0.675 Odor: Characteristic chlorinated hydrocarbon IV - FIRE AND EXPLOSION Flash Point F Propellant <20°F Flammable Limits LEL for propellant is 1.8 Extinguishing Media: CO₂, dry chemical, foam. Special Fire Fighting Procedures: Water may be ineffective. Water may be used to keep fire exposed containers cool. Use equipment or shielding to protect personnel against bursting or rupturing cans. Unusual Fire and Explosion Hazards: Do not spray near open flame. Keep at room temperature as exposure to direct sunlight or other heat may cause bursting. V - REACTIVITY DATA Stability - Conditions to avoid: Do not store above 120°F. Incompatibility: None Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen chloride and phosgene gas. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INHALATION Excessive inhalation of vapors can be harmful and may cause headache, dizziness, asphyxia, anesthetic effects and possible unconsciousness. EYES: Mild irritation. SKIN Possible mild irritation due to defatting of skin. INGESTION Possible chemical pneumonitis if aspirated into lungs. Nausea. B. SUBCHRONIC, CHRONIC, OTHER: (Effects due to excessive exposure to the raw materials of the mixtures) May cause elevated carboxyhemaglobin levels, nausea, dizziness and irritation. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 41 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove patient to fresh air. Resuscitate if necessary. Get medical attention. EYES: Flush with water for at least 15 minutes. If irritated, seek medical attention. SKIN: Possible mild irritation due to defatting of skin. INGESTION: Do NOT induce vomiting. Drink two large glasses of water. Get immediate medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management: Absorb with suitable medium. Incinerate or landfill according to local, state or federal regulations. DO NOT FLUSH TO SEWER. Waste Disposal Methods: Aerosol cans when vented to atmospheric pressure through normal use, pose no disposal hazard. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: If vapor concentration exceeds TLV, use respirator approved by U. S. Bureau of Mines for organic vapor. Eye Protection Safety glasses Gloves Neoprene gloves recommended Other Clothing and Equipment: None. Ventilation: Adequate ventilation to keep vapor concentration below TLV. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not puncture or incinerate containers. Do not store at temperatures above 130 ° F. 2 2 Fire Hazard................: 4 Fire Hazard .................. : 4 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 42 A Aerosol Zinc Rich Cold Galv I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Aerosol Zinc Rich Cold Galv Product Number: 4087 Synonyms: Aerosol Zinc Coating II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Rule VMP Naphtha (LEL: 0.9) 64742-89-8 <5 300ppm 500ppm # Xylene (LEL: 1.1) 1330-20-7 <15 100ppm # Methyl Ethyl Ketone (LEL: 1.0) 78-93-3 <40 200ppm Propane (LEL: 2.3) 74-98-6 15 1000ppm # Metallic Zinc Dust 7440-66-6 <45 NE Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. Aerosol - Contents under pressure 55 +/- 5 psig VOC Content: 4.46 lbs/gal All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg N/AV Vapor Density (Air=1) 60-90° F: >1 Evaporation Rate: (ether=1) <1 VOC Content (% by wt.): 55 Solubility in H₂O: N/AV pH @ Solution: N/AV Freezing Point °F: N/AV pH as Distributed: N/AV Boiling Point °F: Propellant <0 Appearance: Propellants Specific Gravity H₂O=1 @25° C: N/A Odor: Typical IV - FIRE AND EXPLOSION Flash Point F Propellant <20°F Flammable Limits See Sect. II Extinguishing Media: Carbon dioxide, dry chemical or foam. Special Fire Fighting Procedures: Water may be ineffective. Water may be used to keep fire exposed containers cool. Unusual Fire and Explosion Hazards: Do not spray near open flame. Keep at room temperature as exposure to direct sunlight or other heat may cause bursting. V - REACTIVITY DATA Stability - Conditions to avoid: Stable. Do not store above 120°F. Incompatibility: None. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide released by open flame. Conditions Contributing to Hazardous Polymerizations: Will not occur. 43 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES-SKIN-INHALATION & INGESTION In a confined area, vapors in high concentration are anesthetic. Irritant to skin and upper respiratory system. Overexposure may result in light- headedness, staggering gait, giddiness and possible nausea. Harmful or fatal if swallowed. B. SUBCHRONIC, CHRONIC, OTHER: Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage, also kidney and liver damage. This product is not considered to be a carcinogen by NTP IARC or 1 1 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 44 A Alka-Brite I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Alka-Brite Product Number: 4120 Synonyms: Coil Brightener and Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Hydroxide ORAL LD50 1310-73-2 <10 2mg/m3 140 mg/kg (ceiling) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Like Water Vapor Density (Air=1) 60-90° F: Like H₂O Evaporation Rate: (ether=1) N/AV VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ undiluted Solution: >13 Freezing Point °F: N/AV pH as Distributed: N/A Boiling Point °F: >212°F Appearance: Pink liquid Specific Gravity H₂O=1 @25° C: 1.12 Odor: Slight odor IV - FIRE AND EXPLOSION Flash Point F Non Flammable. Flammable Limits N/A Extinguishing Media: Product is non flammable. Special Fire Fighting Procedures: None. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: None Known. Incompatibility: Acids and strong oxidizers. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) CORROSIVE TO ALL BODY TISSUE. EYES & SKIN Causes severe and painful injury. INHALATION Mists will cause irritation and may damage respiratory tract. INGESTION Harmful if swallowed. Will upset stomach; may cause nausea, headaches and dizziness. B. SUBCHRONIC, CHRONIC, OTHER: No available information found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 45 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from exposure of mists. Get medical attention. EYES: & SKIN: In case of contact, immediately flush eyes and skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Wash clothing before reuse. Throughly clean shoes before reuse. INGESTION: If swallowed, DO NOT induce vomiting. Give large quantities of water. Call a physician immediately. Never give anything by mouth to an unconscious person. VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area to contain as much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable absorbing material and place in sealed container. Waste Disposal Methods: Neutralize with 6M-HCL. Flush with plenty of water and dispose of in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory NIOSH-approved respirator is recommended if the 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 46 A Alka-Brite - Canada I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Alka-Brite - Canada Product Number: 4819 Synonyms: Coil Brightener and Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Hydroxide ORAL LD50 1310-73-2 <10 2mg/m3 140 mg/kg (ceiling) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Like Water Vapor Density (Air=1) 60-90° F: Like H₂O Evaporation Rate: (ether=1) N/AV VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ undiluted Solution: >13 Freezing Point °F: N/AV pH as Distributed: N/A Boiling Point °F: >212°F Appearance: Pink liquid Specific Gravity H₂O=1 @25° C: 1.12 Odor: Slight odor IV - FIRE AND EXPLOSION Flash Point F Non Flammable. Flammable Limits N/A Extinguishing Media: Product is non flammable. Special Fire Fighting Procedures: None. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: None Known. Incompatibility: Acids and strong oxidizers. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) CORROSIVE TO ALL BODY TISSUE. EYES & SKIN Causes severe and painful injury. INHALATION Mists will cause irritation and may damage respiratory tract. INGESTION Harmful if swallowed. Will upset stomach; may cause nausea, headaches and dizziness. B. SUBCHRONIC, CHRONIC, OTHER: No available information found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 47 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from exposure of mists. Get medical attention. EYES: & SKIN: In case of contact, immediately flush eyes and skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Wash clothing before reuse. Throughly clean shoes before reuse. INGESTION: If swallowed, DO NOT induce vomiting. Give large quantities of water. Call a physician immediately. Never give anything by mouth to an unconscious person. VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area to contain as much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable absorbing material and place in sealed container. Waste Disposal Methods: Neutralize with 6M-HCL. Flush with plenty of water and dispose of in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory NIOSH-approved respirator is recommended if the 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 48 A Bio-Fresh I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Bio-Fresh Product Number: 4126 Synonyms: Germicide Cleaner EPA Regis. No. 1459-101-65516 EPA Est. No. 10208-MO-1 II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Dipropylene Glycol Monomethyl 34590-94-8 <10 100ppm 150ppm Ether 139-07-1 0.3 N/E Alkyl Dimethyl Benzyl Ammonium Chloride Bio-Fresh contains no Section 313 listed substances subject to reporting All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: Not Determined Vapor Density (Air=1) 60-90° F: Not Determined Evaporation Rate: Same as water VOC Content (% by wt.): Not Determined Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: 32°F pH as Distributed: 12.0 +/- 0.5 Boiling Point °F: 212°F Appearance: Clear, water white Specific Gravity H₂O=1 @25° C: 1.010 Odor: Characteristic chemical IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits N/A N/A Extinguishing Media: Product is not combustible. Water spray, dry chemical, CO₂ Special Fire Fighting Procedures: Do not enter confined fire-spaces without protective clothing & self-contained air supply Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: Stable. Incompatibility: Strong acids/oxidizers; do not mix with chlorinated cleaners (bleach). Hazardous Decomposition Products: Burning may produce CO, CO₂ and unidentified organic compounds. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), A. ACUTE (Primary Route of Exposure): EYES; Prolonged or repeated contact of concentrated product will cause irritation and reddening. SKIN May cause irritation with some individuals.INGESTION May cause nausea, abdominal discomfort and diarrhea. B. SUBCHRONIC, CHRONIC, OTHER: None. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 49 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Start artificial respiration if necessary. Oxygen may be administered. Call a physician. EYES: Flush eyes with water for at least 15 minutes and call a physician immediately. SKIN: Wash affected areas with large amounts of soap and water. If irritation persists, call a physician. INGESTION: DO NOT induce vomiting. Dilute by drinking water. Call a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Safely stop spill at source. Contain spill by dyking with soil or other inert material. Mop, pump or absorb with material and reclaim into sound containers for reuse, recycle or proper disposal. Prevent all spills from entering natural water ways. Waste Disposal Methods: Dispose of in an approved waste facility according to federal, state and local regulations. See label for specifics. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required under normal use conditions. Avoid misting conditions/spray back. Eye Protection Safety glasses goggles. Gloves Rubber gloves /PVC Other Clothing and Equipment: Protective clothing as required to minimize contact during specific operations. Ventilation: Mechanical. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: No special requirements if product is handled according to good practices. Keep container closed when not in use. Wash thoroughly after handling. Avoid all contact with eyes, skin or clothing. Avoid all contact with foods, feed or water. Observe all label directions as to storage and disposal. Keep out of reach of children. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 50 A Bio-Fresh cd I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Bio-Fresh cd Product Number: 4126-34 Synonyms: Bacteristat-Fungistat EPA Registration No. 9804-3-65516 EPA Establishment No. 9804-OK-1 II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Chlorite 7758--19-2 min 0.17 N/E Chlorine Dioxide* 10049-04-4 Trace 0.1 ppm * SARA 313 All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: 23.7 mm Hg (@25°C) Vapor Density (Air=1) 60-90° F: .02 Kg/m3 Evaporation Rate: Comparable to water VOC Content (% by wt.): <0.01% Solubility in H₂O: Complete pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: 7.5-9.0 Boiling Point °F: 213°F Appearance: Clear liquid Specific Gravity H₂O=1 @25° C: 1.01 Odor: Faint chlorinous odor IV - FIRE AND EXPLOSION Flash Point F None to boiling point Flammable Limits N/A Extinguishing Media: Water unless contraindicated by other material involved in fire Special Fire Fighting Procedures: Do not allow product solutions to evaporate to dryness. Unusual Fire and Explosion Hazards: The sodium chlorite in dried Bio-fresh cd is a strong oxidizer, which supports combustion. V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable - Avoid storing product under conditions in which it could evaporate to crystalline salt. Incompatibility: Avoid accidental contact with acids,chlorine compounds, hypochlorites (bleach), sulfur and silfite compounds, phosphorous, organic solvents and combustible/flammable materials. Hazardous Decomposition Products: Exposure to acids or chlorine compounds can produce chlorine dioxide gas. Conditions Contributing to Hazardous Polymerizations: Does not occur. 51 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Rat oral LD50=4360 mg/Kg. May produce gastric discomfort,nausea vomiting and diarrhea. Ingestion of large quantities may produce methemoglobinemia. EYES: Based upon rabbit studies, product has an EPA Category III rating as a mild irritant. Exposure can produce slight irritation of conjunctiva, cornea and eyelid. SKIN: Based upon rabbit studies, product is listed as 'practically not an irritant'. Prolonged exposure may produce localized irritation, contact dermatitis, mild erythema and edema. Skin absorption is highly unlikely in toxic amounts (Rabbit Acute Dermal LD50>2020 mg/Kg.). INHALATION: Acute Inhalation: LC50> 5.61 mg/L. Prolonged inhalation of fog or mist containing product may be irritating to nose and throat. B. SUBCHRONIC, CHRONIC, OTHER: May cause localized irritation to areas exposed to product. Over exposure to chlorine dioxide from activation can produce coughing, sore throat, headache and dizziness. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Skin disorder, such as dermal allergies and dermatitis. VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Unactivated product normally has no respiratory effects. If exposure to chlorine dioxide produced from activation occurs, remove victim to fresh air. Contact a physician if respiratory distress continues. EYES: Flush eyes thoroughly with water, making certain eyelids are held open. If irritation or burning persist, seek medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and rinse thoroughly with water before laundering , or discard. If irritation occurs, seek medical attention. INGESTION: DO NOT INDUCE VOMITING. Contact a physician or Poison Control Center immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Small spills, involving less than 10 gallons, may be flushed to a designated and permitted sewer system with copious amounts of water. Do not discharge this product to storm drains or to any surface or groundwater source unless specifically allowed under a valid NPDES permit. Waste Disposal Methods: Small quantities, less than 10 gallons, may be flushed to an authorized and permitted sewer with copious amounts of water. Large quantities should be taken to an authorized disposal site. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory In accordance with 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 1 Reactivity..................... : 1 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 53 54 A Burst-Kontr'l AP I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Burst-Kontr'l AP Product Number: 4187 Synonyms: Propylene Glycol Heat Transfer Fluid II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Propylene Glycol 57-55-6 40 - 50% Dibasic Acid 72162-23-3 <1% All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg 0.1 Vapor Density (Air=1) 60-90° F: 2.6 Evaporation Rate (ether=1) N/A VOC Content (% by wt.): slightly volatile Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: -10°F pH as Distributed: Boiling Point °F: 360°F Appearance: Light blue liquid slightly vis. Specific Gravity H₂O=1 @25° C: 1.04 Odor: Near odorless IV - FIRE AND EXPLOSION Flash Point F 211°F Flammable Limits (%vol. in air) -17.4 Extinguishing Media: CO₂ Dry chemical, Alcohol type foam Special Fire Fighting Procedures: Do not enter fire area without proper protection. See "decomposition products possible." Fight fire from safe distance/protected location. Heat may build pressure/rupture closed containers. Spreading fire. Increasing risk of burns/injuries. Use water spray/fog for cooling. Avoid frothing/steam explosion. Burning liquid may float on water. Although soluble, may not be practical to extinguish fire by water dilution. Notify authorities if liquid enters sewer/public water. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: Stable; avoid high temperatures and severe oxidizing conditions Incompatibility: Strong oxidizing agents. Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide and other harmful gases/vapors. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), A. ACUTE (Primary Route of Exposure): Slight eye irritant. No inhalation hazard identified from data. No skin absorption hazard identified from data. No skin irritation identified from data. No ingestion hazard identified from data. B. SUBCHRONIC, CHRONIC, OTHER: No chronic health effects are expected from normal use. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: N/A 55 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: Flush with water for 20-30 minutes, Retract eyelids open. Obtain medical attention if pain, blinking, tears or redness persist. SKIN: Not expected to present a significant skin hazard under anticipated conditions of normal use. INGESTION: Not expected to present a significant ingestion hazard under anticipated conditions of normal use. VIII - SPILL OR LEAK PROCEDURE Spill Management: Evacuate/limit access. Prevent flow to sewers/public water. Stop release. Notify fire/environmental authorities. Restrict water use for cleanup. Slippery walking. Spread granular cover. Soak up small spill with inert solids. Use suitable disposal containers on water material soluble/may float or sink. May be biodegrade. Contain/minimize dispersion. Disperse residue to reduce aquatic harm. Report per regulatory requirements. Waste Disposal Methods: Landfill solids at permitted sites. Use registered transporters. Burn concentrated liquids. Diluting with clean, low viscosity fuel. Avoid flameouts. Assure emissions comply with applicable regulations. Avoid overloading/poisoning plant biomass. Assure effluent complies with applicable regulations. Contaminated product, soil or water should not be designated RCRA Hazardous waste. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: None when used with adequate ventilation. Eye Protection Safety glasses Gloves Recommended Other Clothing and Equipment: None required. Ventilation: Use with adequate ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Hygroscopic, use dry nitrogen or low dew point air for tank padding. Keep drums tightly closed to prevent contamination. Store at 65-90°F. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 56 A C-3 Refrigeration Oil I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: C-3 Refrigeration Oil Product Number: 4303 Synonyms: Refined and Treated Naphthenic Oils II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Mineral Oil 64742-44-5 100 5mg/m3 N/A (as a mist) Refined and Treated Naphthenic Oils - 100% VOC Content: 9.6%, 0.72 lbs/gal (0.086mg/L) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg <0.0001 Vapor Density (Air=1) 60-90° F: 10 Evaporation Rate (ether=1) N/AV VOC Content (% by wt.): 100 Solubility in H₂O: Nil pH @ N/A Solution: N/A Freezing Point °F: N/AV pH as Distributed: N/A Boiling Point °F: >212°F Appearance: Colorless liquid Specific Gravity H₂O=1 @25° C: 0.92 Odor: Little odor IV - FIRE AND EXPLOSION Flash Point F 330°F COC Flammable Limits N/A Extinguishing Media: Water fog, chemical foam, dry chemical CO₂. Special Fire Fighting Procedures: Exercise caution when fighting any chemical fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: None known. Incompatibility: Strong Oxidizers. Hazardous Decomposition Products: Exposure to high temperature can produce carbon monoxide. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN May cause reversible eye and skin irritation INGESTION: This product is practically non-toxic. The acute ORAL LD50 (rats) is >15g/kg. B. SUBCHRONIC, CHRONIC, OTHER: None known. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 57 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with plenty of water for at least 15 minutes. If irritation develops, call a physician. SKIN: N/A INGESTION: N/A. Good First Aid should be followed in all cases of exposure. VIII - SPILL OR LEAK PROCEDURE Spill Management: Dispose of in accordance with federal, state and local regulations. Dike area to contain as much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable material and place in sealed metal container for disposal. Waste Disposal Methods: Mix with a flammable solvent and incinerate in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Safety glasses Gloves Not required Other Clothing and Equipment: Not required. Ventilation: Local exhaust. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Wash thoroughly after handling. Keep container closed. Exercise caution in the storage and handling of all chemical substances. 0 0 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 58 A C-4 Refrigeration Oil I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: C-4 Refrigeration Oil Product Number: 4304 Synonyms: Refined Hydrotreated Naphthenic Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Mineral Oils 64742-44-5 100 5mg/m3 N/A (as a mist) VOC Content: 9.3%; 0.70 lbs/gal (0.084 mg/L) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg <0.0001 @ 20°C Vapor Density (Air=1) 60-90° F: >5 Evaporation Rate (ether=1) 1000x slower vs eth VOC Content (% by wt.): nil Solubility in H₂O: Nil pH @ N/A Solution: N/A Freezing Point °F: N/AV pH as Distributed: essentially neutral Boiling Point °F: > 500°F (IBP) Appearance: Water white to straw colored liquid Specific Gravity H₂O=1 @25° C: 0.9 Odor: Little odor IV - FIRE AND EXPLOSION Flash Point F >350°F COC Flammable Limits N/A Extinguishing Media: Water fog, chemical foam, dry chemical CO₂. Special Fire Fighting Procedures: Exercise caution when fighting any chemical fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: None known Incompatibility: Strong oxidizers. Hazardous Decomposition Products: Exposure to high temperature can produce carbon monoxide. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN May cause reversable eye and skin irritation INGESTION: This product is practically non-toxic through ingestion. The acute ORAL LD50 (rats) is >30g/kg. B. SUBCHRONIC, CHRONIC, OTHER: None known. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with plenty of water for at least 15 minutes. If irritation develops, call a physician. SKIN: N/A INGESTION: N/A. Good First Aid should be followed in all cases of exposure. 59 VIII - SPILL OR LEAK PROCEDURE Spill Management: Dispose of in accordance with federal, state and local regulations. Dike area to contain as much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable material and place in sealed metal container for disposal. Waste Disposal Methods: Mix with a flammable solvent and incinerate in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Safety glasses Gloves Not required Other Clothing and Equipment: Not required Ventilation: Local exhaust. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Wash thoroughly after handling. Keep container closed. Exercise caution in the storage and handling of all chemical substances. 0 0 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 60 A C-5 Refrigeration Oil I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: C-5 Refrigeration Oil Product Number: 4305 Synonyms: Refined Naphthenic Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Mineral Oil 64742-44-5 100 5mg/m3 N/A (as a mist) VOC Content: 2.0%; 0.15 lbs/gal (0.018 mg/L) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg <0.0001 Vapor Density (Air=1) 60-90° F: 20 Evaporation Rate (ether=1) N/AV VOC Content (% by wt.): 100 Solubility in H₂O: Nil pH @ N/A Solution: N/A Freezing Point °F: N/AV pH as Distributed: N/A Boiling Point °F: 212°F Appearance: Colorless liquid Specific Gravity H₂O=1 @25° C: 0.93 Odor: Little odor IV - FIRE AND EXPLOSION Flash Point F 340°F COC Flammable Limits N/A Extinguishing Media: Water fog, chemical foam, dry chemical CO₂. Special Fire Fighting Procedures: Exercise caution when fighting any chemical fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: None known Incompatibility: Strong oxidizers. Hazardous Decomposition Products: Exposure to high temperature can produce carbon monoxide. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN May cause reversible eye and skin irritation INGESTION: This product is practically non-toxic through ingestion. The acute ORAL LD50 (rats) is >30g/kg. B. SUBCHRONIC, CHRONIC, OTHER: None known C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with plenty of water for at least 15 minutes. If irritation develops, call a physician. SKIN: N/A INGESTION: N/A. Good First Aid should be followed in all cases of exposure. 61 VIII - SPILL OR LEAK PROCEDURE Spill Management: Dispose of in accordance with federal, state and local regulations. Dike area to contain as much spilled material as possible. Remove any remaining material by absorbing with vermiculite or other suitable material and place in sealed metal container for disposal. Waste Disposal Methods: Mix with a flammable solvent and incinerate in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Safety glasses Gloves Not required Other Clothing and Equipment: Not required Ventilation: Local exhaust X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Wash thoroughly after handling. Keep container closed. Exercise caution in the storage and handling of all chemical substances. 0 0 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 62 A Cal-Blue I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Cal-Blue Product Number: 4182 Synonyms: Bubble-forming Liquid II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # Ethylene glycol (ORAL LD50 107-21-1 <40 50ppm NE 8.5mg/kg rat) ceiling (vapor) # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. VOC Content: none All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate: Unknown VOC Content (% by wt.): Approx 85 Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: 5°F pH as Distributed: 7.3-7.6 Boiling Point °F: >212°F Appearance: Clear blue liquid Specific Gravity H₂O=1 @25° C: 1.085 Odor: Mild Chemical odor IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits Unknown Extinguishing Media: Product is not combustible. In case of fire use CO₂, foam or dry chemical. Special Fire Fighting Procedures: Exercise caution when fighting any chemical dry fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: None known V - REACTIVITY DATA Stability - Conditions to avoid: Heat and open flame Incompatibility: Can react violently with strong oxidizers, dehydrating agents such as sulfuric acid, acetic anhydride. Hazardous Decomposition Products: Carbon monoxide. Conditions Contributing to Hazardous Polymerizations: None known 63 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES May cause eye irritation. (Primary Route of Exposure) SKIN Essentially non-irritating. INGESTION: Harmful if swallowed. May cause nausea, dizziness, central nervous system damage, kidney disorders. INHALATION: Prolonged or repeated breathing of vapors may cause headache, nausea, dizziness. B. SUBCHRONIC, CHRONIC, OTHER: Repeated or prolonged inhalation of vapors may cause nervous system damage. Repeated contact with skin may cause sensitization in some individuals. Ethylene glycol has caused birth defects in laboratory animals. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Preexisting kidney disorders, lung disorders VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air EYES: Flush with plenty of water for at least 15 minutes. If irritation persists, call a physician. SKIN: Wash area with soap and plenty of water. INGESTION: If swallowed, call a physician immediately. Give one or two glasses of water and induce vomiting by sticking finger down throat. Never give anything by mouth or attempt to induce vomiting in an unconscious person. VIII - SPILL OR LEAK PROCEDURE Spill Management: Flush spill with water or wipe up and incinerate. Waste Disposal Methods: Incinerate or flush to drain served by sanitary sewer in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not normally required Eye Protection Avoid eye contact Gloves None required Other Clothing and Equipment: None required Ventilation: Vapors are minimal at room temperatures. Normal room ventilation should be sufficient. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. Avoid breathing mists or vapors. Wash thoroughly after handling. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 64 A Cal-Blue LT I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Cal-Blue LT Product Number: 4183 Synonyms: Low Temp Gas Leak Detector II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # Ethylene glycol (ORAL LD50 30-50 50ppm N/E 8.5mg/kg rat) ceiling (vapor) # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: Similar to water VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: -20°F pH as Distributed: 7.0-8.0 Boiling Point °F: 212°F Appearance: Clear, blue viscous liquid Specific Gravity H₂O=1 @25° C: Odor: Mild IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits N/A Extinguishing Media: Product is not combustible. In case of fire use CO₂, foam or dry chemical. Special Fire Fighting Procedures: Do not enter confined air spaces without protective clothing and self-contained air supply Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: Stable Incompatibility: Can react violently with strong oxidizers, dehydrating agents such as sulfuric acid, acetic anhydride. Hazardous Decomposition Products: Burning can produce oxides of carbon. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES May cause eye irritation. (Primary Route of Exposure) SKIN May cause irritation, reddening, drying or cracking of skin. INGESTION: Ethylene glycol in product is toxic. Harmful if swallowed. May cause nausea, dizziness, central nervous system damage, cardiopulmonary effects and possible kidney damage, coma and convulsions. INHALATION: Prolonged or repeated breathing of vapors may cause headache, nausea, dizziness. B. SUBCHRONIC, CHRONIC, OTHER: Ethylene glycol has caused birth defects in laboratory animals. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Preexisting kidney disorders, lung disorders 65 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Start artificial respiration if necessary. Oxygen may be administered. Call a physician. EYES: Flush with plenty of water for at least 15 minutes and call a physician. SKIN: Wash area with soap and plenty of water. If irritation develops, call a physician. INGESTION: If swallowed, call a physician immediately. Give one or two glasses of water and induce vomiting by sticking finger down throat. Never give anything by mouth or attempt to induce vomiting in an unconscious person. VIII - SPILL OR LEAK PROCEDURE Spill Management: Safely stop spill at source. Contain spill by dyking with soil or other inert material and reclaim into sound container for proper disposal. Waste Disposal Methods: Dispose of in an approved waste facility in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required under normal use conditions. Use with adequate ventilation. Eye Protection Safety glasses or goggles Gloves Not required Other Clothing and Equipment: Not required under normal use conditions. Ventilation: Mechanical X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Keep container closed when not in use (turn spray nozzle to "off " position). Avoid contact with eyes, skin and clothing. Avoid breathing mists or vapors. Wash thoroughly after handling. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 66 A Cal-Brite I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Cal-Brite Product Number: 4133 Synonyms: Coil cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Ammonium Bifluoride 1341-49-7 2-20 % 2.5mg/m* Glycolic Acid 79-14-1 2-15 % N/A C11 alcohol ethoxylate 68439-46-3 2-10 % N/A *mg/cubic meter All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: N/A VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: 32° pH as Distributed: 4-5 Boiling Point °F: 212° Appearance: Clear liquid Specific Gravity H₂O=1 @25° C: 1.01 Odor: Alcohol IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits Non-flammable Extinguishing Media: Use media appropriate for surrounding material Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: Stable at normal temperatures and storage conditions Incompatibility: None Hazardous Decomposition Products: Decomposition will not occur Conditions Contributing to Hazardous Polymerizations: Polymerization will not occur 67 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) SKIN May cause skin irritation with discomfort or rash or skin burns or ulceration. EYES: May cause eye irritation with discomfort, tearing, or blurring of vision; or eye corrosion with cornea or conjunctival ulceration. INHALATION: May cause irritation of the upper respiratory passages with coughing and discomfort; or temporary nervous system depression with anaesthetic effects such as dizziness, headache, confusion, incoordination, and loss of consciousness. Inhalation of ammonium bifluoride may be fatal as a result of spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Symptoms exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. Chronic exposure to fluoride may cause fluorosis with weight loss, anemia, weakness, general ill health, stiffness of joints. INGESTION: May cause upper gastrointestinal irritation or corrosion of mucous membranes with stomach discomfort, nausea and prostration or abnormal liver function as detected by laboratory tests. Fatality may occur from gross overexposure. B. SUBCHRONIC, CHRONIC, OTHER: C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: If inhaled, immediately remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. EYES: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, immediately flush skin with plenty of water for at least 15 minutes, while removing contaminated clothing and shoes. Call a physician. Wash contaminated clothing before reuse. INGESTION: If swallowed, do not induce vomiting. Immediately give 2 glasses of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physicians: Activated charcoal mixture may be beneficial. Suspend 50 g activated charcoal in 400 ml water and mix well. Administer 5 ml/gh, or 350 ml for an average adult. VIII - SPILL OR LEAK PROCEDURE Spill Management Safeguards (Personnel) NOTE Reviewl FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONNEL PROTECTIVE EQUIPMENT during clean-up. Spill Clean Up: Soak up with dry or other absorbent material. Waste Disposal Methods: Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Providence, and Local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH/MSHA approved protection, as appropriate. Eye Protection Goggles Gloves Rubber gloves Other Clothing and Equipment: Wear appropriate, impervious clothing to prevent contact (gloves, apron, pants, jacket, hood, boots) or full acid suit with hood, boots and gloves. (Neoprene gloves suggested). Ventilation: Use only with adequate ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not breathe vapor or mist. Do not get in eyes, on skin or clothing. Wash thoroughly after handling. Wash clothing after use. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 69 70 A Calci-Solve I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Calci-Solve Product Number: 4134 Synonyms: Acid-based pipe and drain cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Hydrochloric Acid** 7647-01-0 >30 5ppm* N/A Water 7732-18-5 <70 Acid Inhibitor (proprietary) <1 *Ceiling **Reportable for SARA Title III, S.313 (Form R) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: 39 mm (Hg) Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: N/A VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: <1 Boiling Point °F: Est. 180°F Appearance: Red liquid Specific Gravity H₂O=1 @25° C: 1.16 Odor: Muriatic acid. IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits Non flammable Extinguishing Media: Product is not flammable Special Fire Fighting Procedures: Avoid skin and eye contact, and breathing of acid vapors. Wear head and body protection and HCl respirator if exposure to liquid is likely Unusual Fire and Explosion Hazards NOTE This product can react with metals to release hydrogen gas Firemen may need to protect against this. V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable Incompatibility: Strong alkalis, materials not resistant to strong acids, active metals (zinc, aluminum, magnesium, etc.). Hazardous Decomposition Products: Hydrogen chloride vapors. Contact with active metals can release flammable gas. Conditions Contributing to Hazardous Polymerizations: Does not occur. 71 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES Corrosive. Causes eye damage. SKIN Corrosive to tissues Causes irritation and burns. INGESTION: Harmful if swallowed. Burns to mouth, throat, esophagus and stomach are likely. INHALATION: Breathing of vapor can cause respiratory irritation and inflammation. Breathing of mists or liquid may cause coughing and burning. B. SUBCHRONIC, CHRONIC, OTHER: C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Over exposure to product has the following effects: inhalation of vapors may cause pulmonary edema, collapse of circulatory system and damage to the upper respiratory system and collapse. Inhalation may cause coughing, throat burning, choking, bromchitis, and difficult breathing. Ingestion is harmful and may be fatal. Ingestion may cause burns. VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Give artificial respiration or oxygen if needed, and contact a physician. EYES: Wear splash-proof goggles. Provide convenient eyewash stations. Flush immediately for 15 minutes. Get immediate medical attention. SKIN: In case of contact, immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If irritation persists, get medical attention. Wash clothing before reuse. INGESTION: If swallowed, DO NOT induce vomiting. Give large quantities of water or milk. Call a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. For large spills, dike area and contain as much spilled material as possible, absorbing with soda ash or sodium bicarbonate. Flush with water or absorb for collection and proper disposal. Personnel should use skin, eye and respiratory protection Waste Disposal Methods: If neutralized, may be disposed in sewers if local regulations permit. Otherwise, send to licensed treatment and disposal facility. As supplied, this product is a RCRA hazardous waste. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Wear approved HCl vapor/mist respirator if exposure is likely Eye Protection Full face shield or goggles Gloves Rubber gloves Other Clothing and Equipment: Wear acid-resistant protective gloves, boots and clothing. Provide convenient safety showers. Provide convenient eye wash stations. Ventilation: Use with adequate ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not get in eyes, on skin or clothing. Avoid breathing vapor or mist. Keep container closed. Wash thoroughly after handling. Keep from contact with chlorine bleaches. Check containers daily for leaks. Have water hoses and alkaline material (soda ash) convenient. Only use containers and equipment designed for acid service. 3 3 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 73 74 A CalClean - Canada I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: CalClean - Canada Product Number: 4821 Synonyms: Detergent coil cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Metasilicate 6834-92-0 <5 N/A All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg like water Vapor Density (Air=1) 60-90° F: Like H₂O. Evaporation Rate: (ether=1) N/AV VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ undiluted Solution: 13.1 Freezing Point °F: N/AV. pH as Distributed: N/A Boiling Point °F: >212° Appearance: Fluorescent green Specific Gravity H₂O=1 @25° C: 1.085 Odor: Lightly perfumed IV - FIRE AND EXPLOSION Flash Point F Not Flammable Flammable Limits Not Applicable Extinguishing Media: Product is not flammable. Special Fire Fighting Procedures: None. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: None known. Incompatibility: Strong acids. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES May cause severe irritation and pain with redness and swelling of conjunctiva. May injure eye tissue if not promptly removed. SKIN: May be irritating to skin and prolonged contact may cause dematitis. INGESTION: May cause moderate to severe irritation of mouth, throat and stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: If mists of product are inhaled, remove to fresh air. If irritation develops or persists, call a physician. EYES: In case of contact, flush with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush with plenty of water for at least 15 minutes. If irritation develops, call a physician. INGESTION: Drink plenty of water and call a physician. 75 VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area to contain as much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable material and place in sealed container for disposal. Waste Disposal Methods: Flush with plenty of water. Dispose of in accordance with local, state and federal regulations IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Eye goggles or safety glasses Gloves Rubber gloves Other Clothing and Equipment: Not required. Ventilation: Normal X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. Keep container closed. Wash thoroughly after handling. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 76 A CalClean HD-Rtu I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: CalClean HD-Rtu Product Number: 4144 Synonyms: Ready-to-use Coil Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Metasilicate 6834-92-0 <1 N/A Potassium Hydroxide 1310-58-3 <1 2mg/m3 (ceiling) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: (mm Hg) Like Water Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: N/A VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ 1% Solution: 12.0 Freezing Point °F: N/A pH as Distributed: 13.0 Boiling Point °F: 212°F Appearance: Fluorescent green liquid Specific Gravity H₂O=1 @25° C: 1.011 Odor: Very Lightly perfumed IV - FIRE AND EXPLOSION Flash Point F Not Flammable Flammable Limits N/A Extinguishing Media: Product is not flammable. Use water to cool source of fire. Special Fire Fighting Procedures: For any chemical fire, use self-contained breathing apparatus and impervious clothing. Unusual Fire and Explosion Hazards: None Known V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable in normal use. Incompatibility: Strong acids and oxidizers. Hazardous Decomposition Products: None Known Conditions Contributing to Hazardous Polymerizations: None Known VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Concentrate will burn and irritate both eyes and skin INGESTION: Concentrate may burn or severely irritate mouth, esophagus and stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: No available information was found. VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush with plenty of water for at least 15 minutes. If irritation develops, call physician. INGESTION: Drink plenty of water. Do NOT induce vomiting. Contact a physician. 77 VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area, contain as much spilled material possible. Remove any remaining material by absorbing on vermiculite or other suitable material and place in a sealed metal container for disposal. Waste Disposal Methods: Flush with plenty of water. Dispose of in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Goggles or safety glasses Gloves Rubber gloves Other Clothing and Equipment: Not required Ventilation: Normal X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. Keep container closed. Wash thoroughly after handling. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 78 A CalClean, Special HD I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: CalClean, Special HD Product Number: 4143 Synonyms: Detergent II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Metasilicate 6834-92-0 5 N/A Potassium Hydroxide 1310-58-3 3 2mg/m3 (ceiling) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Like Water Vapor Density (Air=1) 60-90° F: Like H₂0 Evaporation Rate (ether=1) N/A VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: (undiluted) 13.1 Boiling Point °F: > 212° Appearance: Fluorescent green liquid Specific Gravity H₂O=1 @25° C: 1.085 Odor: Lightly perfumed odor IV - FIRE AND EXPLOSION Flash Point F Non flammable Flammable Limits N/A Extinguishing Media: Product is not flammable. Use water to cool source of fire. Special Fire Fighting Procedures: For any chemical fire, use self-contained breathing apparatus and impervious clothing. Unusual Fire and Explosion Hazards: None Known V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable in normal use. Incompatibility: Strong acids and oxidizers. Hazardous Decomposition Products: Unknown Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Concentrate will burn and irritate both eyes and skin INGESTION: Concentrate may burn or severely irritate mouth, esophagus and stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush with plenty of water for at least 15 minutes. If irritation develops, call physician. INGESTION: Drink plenty of water. Do NOT induce vomiting. Contact a physician. 79 VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area, contain as much spilled material possible. Remove any remaining material by absorbing on vermiculite or other suitable material and place in a sealed metal container for disposal. Waste Disposal Methods: Flush with plenty of water. Dispose of in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Goggles or safety glasses Gloves Rubber gloves Other Clothing and Equipment: Not required. Ventilation: Normal X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. Keep container closed. Wash thoroughly after handling. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 80 A CalClean, Special HD - Canada I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: CalClean, Special HD - Canada Product Number: 4823 Synonyms: Detergent II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Metasilicate 6834-92-0 5 N/A Potassium Hydroxide 1310-58-3 3 2mg/m3 (ceiling) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Like Water Vapor Density (Air=1) 60-90° F: Like H₂0 Evaporation Rate (ether=1) N/A VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: (undiluted) 13.1 Boiling Point °F: > 212° Appearance: Fluorescent green liquid Specific Gravity H₂O=1 @25° C: 1.085 Odor: Lightly perfumed odor IV - FIRE AND EXPLOSION Flash Point F Non flammable Flammable Limits N/A Extinguishing Media: Product is not flammable. Use water to cool source of fire. Special Fire Fighting Procedures: For any chemical fire, use self-contained breathing apparatus and impervious clothing. Unusual Fire and Explosion Hazards: None Known V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable in normal use. Incompatibility: Strong acids and oxidizers. Hazardous Decomposition Products: Unknown Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Concentrate will burn and irritate both eyes and skin INGESTION: Concentrate may burn or severely irritate mouth, esophagus and stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush with plenty of water for at least 15 minutes. If irritation develops, call physician. INGESTION: Drink plenty of water. Do NOT induce vomiting. Contact a physician. 81 VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area, contain as much spilled material possible. Remove any remaining material by absorbing on vermiculite or other suitable material and place in a sealed metal container for disposal. Waste Disposal Methods: Flush with plenty of water. Dispose of in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Goggles or safety glasses Gloves Rubber gloves Other Clothing and Equipment: Not required. Ventilation: Normal X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. Keep container closed. Wash thoroughly after handling. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 82 A Cal-Shield I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Cal-Shield Product Number: 4148 Synonyms: Teflon-based coil protectant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Telomer B Phosphate (DEA 65530-63-4 1-10 % N/A Salt,1 1 2) 65530-64-5 1-10 % N/A Telomer B Phosphate (DEA 65530-74-7 1-5 % N/A Salt,2 1 1) 67-30-0 1-5 % 400 ppm* Telomer B Phosphate (DEA Salt,1 1 1) Isopropyl alcohol *These PEL and TLV values are equivalent to 980 mg/cubic meter. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: N/A VOC Content (% by wt.): N/A Solubility in H₂O: Partial pH @ Solution: N/A Freezing Point °F: 32° pH as Distributed: 7.0 Boiling Point °F: 212° Appearance: Clear liquid Specific Gravity H₂O=1 @25° C: 1.01 Odor: Alcohol IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits Non-flammable Extinguishing Media: Use media appropriate for surrounding material Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: Stable at normal temperatures and storage conditions Incompatibility: None Hazardous Decomposition Products: Decomposition will not occur Conditions Contributing to Hazardous Polymerizations: Polymerization will not occur 83 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) SKIN May cause skin irritation with discomfort or rash. There are rare inconclusive reports of human sensitization to isopropyl alcohol. EYES: May cause eye irritation with discomfort, tearing, or blurring of vision. INHALATION: May cause irritation of the upper respiratory passages, with coughing and discomfort. INGESTION: May cause gastrointestinal irritation with upper abdominal pain, vomiting, and diarrhea. However, there may be no symptoms at all. Inhalation, ingestion, or skin contact may cause nonspecific discomfort, such as nausea, headache, abdominal pain, flushing of the face, hypotension, or weakness. B. SUBCHRONIC, CHRONIC, OTHER: Higher exposures may lead to temporary nervous system depression with anaesthetic effects such as dizziness, headache, confusion, incoordination, and loss of consciousness. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. EYES: In case of contact, immediately flush with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, immediately wash skin with soap and water. Wash contaminated clothing before reuse. INGESTION: If swallowed, do not induce vomiting. Immediately give 2 glasses of water. Never give anything by mouth to an unconscious person. Call a physician. VIII - SPILL OR LEAK PROCEDURE Spill Management Safeguards (Personnel) NOTE Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Spill Clean Up: Soak up with sawdust, sand, oil dry or other absorbent material. Waste Disposal Methods: Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory OUTDOORS When applying outdoors, no respiratory protection is required. INDOORS When applying indoors, respiratory protection is required if application takes place in a closed, sealed or non-ventilated area. Recommended respirator is NIOSH/MSHA carbon-type for organic vapor removal and particulate removal. Eye Protection Goggles Gloves Rubber gloves Other Clothing and Equipment: Where there is potential for skin contact have available, and wear as appropriate, impervious gloves, apron, pants, and jacket. Ventilation: Apply with standard manual "pump-up" sprayer. Use with adequate ventilation, and follow above respiratory guidelines . X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid breathing vapors or mist. Avoid contact with eyes skin or clothing. Wash thoroughly after handling. Wash clothing after use. 0 0 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 84 A Cal-Treat 233 I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Cal-Treat 233 Product Number: 4149 Synonyms: Aqueous Cooling Tower Treatment II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # Zinc Nitrate 7779-88-6 <5 N/A Sodium Molybdate 7631-95-0 <5 5mg/m3 # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: (ether=1) N/A VOC Content (% by wt.): 87% @105°C/2 hrs Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: @20° pH as Distributed: 7.0 Boiling Point °F: 212 @14.7 psig Appearance: Slightly hazy straw liquid. Specific Gravity H₂O=1 @25° C: 1.095 Odor: Bitter IV - FIRE AND EXPLOSION Flash Point F None to boil Flammable Limits N/A Extinguishing Media: Use media suitable for surrounding fire. Special Fire Fighting Procedures: None. Unusual Fire and Explosion Hazards: Freshly formed zinc oxide fumes (as from a fire) may cause metal fume fever, a temporary condition with chills, fever, tightness in chest, cough and leukocytes. Contains nitrites - dry powder may explode when exposed to heat or flame. V - REACTIVITY DATA Stability - Conditions to avoid: None known. Do not allow evaporation to dryness. Incompatibility: None known. Hazardous Decomposition Products: Forced ignition of dried residues may produce CO, CO₂, phosphorus OX1. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES Causes irritation. SKIN May cause irritation. INGESTION Overexposure causes upset to stomach. INHALATION: Inhalation of metal oxide fumes, formed when product is heated to decomposition, can result in metal fume fever, a temporary condition with chills, fever, tightness in chest, cough and leukocytes. B. SUBCHRONIC, CHRONIC, OTHER: None known. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 85 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air and contact physician. EYES: In case of eye contact, flush eyes with flowing water for at least 15 minutes. Get medical attention. SKIN: Wash thoroughly with soap and water. INGESTION: Give large amounts of water. VIII - SPILL OR LEAK PROCEDURE Spill Management: Do not allow liquid to evaporate. Small spills may be mopped up or flushed to drain with water. Waste Disposal Methods: Contact an authorized scavenger service. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Safety glasses or goggles Gloves Rubber gloves Other Clothing and Equipment: Protective apron. Ventilation: Normal. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: If frozen, thaw to room temperature and mix thoroughly. (Roll drum) For industrial and institutional use only. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 86 A Coil Pow'r I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Coil Pow'r Product Number: 4155 Synonyms: Coil Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Metasilicate 6834-92-0 <5% N/A All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: (ether=1) N/A VOC Content (% by wt.): @105C/1hr. 90-91 Solubility in H₂O: Complete pH @ 1.0% Solution: 10.5 Freezing Point °F: Circa 32°F pH as Distributed: 13 Boiling Point °F: @14.7 psig @212° Appearance: Clear, purple liquid Specific Gravity H₂O=1 @25° C: 1.05 Odor: Near odorless IV - FIRE AND EXPLOSION Flash Point F None to boil Flammable Limits N/A Extinguishing Media: Suitable for surrounding area - water, dry chemical, foam CO₂. Special Fire Fighting Procedures: N/A Unusual Fire and Explosion Hazards: N/A V - REACTIVITY DATA Stability - Conditions to avoid: None. Incompatibility: None known. Hazardous Decomposition Products: Forced ignition of dried residues may produce CO, CO₂, nitrogen oxides. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES Detergent in the product is irritating to the eyes. SKIN Product is not a primary skin irritant by FHSA. Prolonged and repeated contact may cause irritation as indicated by pH in product. INHALATION Mists or spray can irritate nasal passages. INGESTION Acute oral LD50 (rats) >5000 mg/kg. Ingestion of large quantities causes upset to the stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove source of irritation. EYES: Flush eyes with flowing water for 15 minutes, call a physician. SKIN: Rinse affected area thoroughly with flowing water. INGESTION: Give large quantities of water or milk followed by vinegar or lemon juice and immediately contact a physician. 87 VIII - SPILL OR LEAK PROCEDURE Spill Management: Small spills may be mopped up and residues flushed to the sewer with water. Rinse mop before storing. May be neutralized with diluted acetic acid. Waste Disposal Methods: Dispose spent solutions in accordance with local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Avoid breathing mists or spray. Eye Protection Goggles or face shield Gloves For manual cleaning Other Clothing and Equipment: Not normally required. Ventilation: Normal room ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: This product will withstand an occasional accidental freezing without loss in its normal performance characteristics. It must be thoroughly thawed and agitated (roll drum) before being used. Store in heated area below 135°F. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 88 A Cork Insulation Tape I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Cork Insulation Tape Product Number: 4217 Synonyms: Same II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL None All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate (ether=1) N/A VOC Content (% by wt.): N/A Solubility in H₂O: NO pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: N/A Appearance: Soft, pliable, pressure sensitive material Specific Gravity H₂O=1 @25° C: 1.3 +/- .05 g/cc Odor: IV - FIRE AND EXPLOSION Flash Point F 450° Flammable Limits N/A Extinguishing Media: Foam, CO₂, Dry Chemicals Special Fire Fighting Procedures: Water unsuited for rubber fires Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: Stable; High temperature yields decomposition to isobutene Incompatibility: Oxygen supplying chemicals and contact with acid clays at elevated temperatures Hazardous Decomposition Products: CO, CO₂, H₂O, and isobutene Conditions Contributing to Hazardous Polymerizations: May not occur VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION N/A, EYES & SKIN N/A B. SUBCHRONIC, CHRONIC, OTHER: None known. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: Flush with plenty of water SKIN: Flush with plenty of water INGESTION: N/A VIII - SPILL OR LEAK PROCEDURE Spill Management: Repackage uncontaminated tape. Dispose of contaminated or unusable tape Waste Disposal Methods: Bury tape waste in an approved land fill site 89 IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: N/A Eye Protection N/A Gloves N/A Other Clothing and Equipment: N/A Ventilation: N/A X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Prevent high temperature exposure 0 0 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 90 A Degreasing Solvent I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Degreasing Solvent Product Number: 4161 Synonyms: Chlorinated Hydrocarbon Solvent II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Stoddard Solvent* (ORAL LD50 8052-41-3 60 100ppm >10mg/kg) 71-55-6 40 350ppm # 1,1,1-trichlorethane** (ORAL LD50 rabbit 5660mg/kg) *STEL=200ppm; **STEL=450ppm # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate (ether=1) N/A VOC Content (% by wt.): 100 Solubility in H₂O: Slight pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: 165°F Appearance: Clear liquid Specific Gravity H₂O=1 @25° C: 0.982 Odor: Hydrocarbon odor IV - FIRE AND EXPLOSION Flash Point F 116F TOC Flammable Limits N/AV Extinguishing Media: Dry chemical, foam, CO₂. Special Fire Fighting Procedures: Exercise caution when fighting any chemical fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: Toxic gases and vapors such as hydrogen chloride, phosgene and carbon monoxide may be released if involved in a fire. V - REACTIVITY DATA Stability - Conditions to avoid: Keep away from heat and flame. Incompatibility: Strong oxidizers, aluminum and magnesium powders and sodium potassium. Hazardous Decomposition Products: See Section IV. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Causes irritation. May defat, dry and cause scaling of skin upon contact. INHALATION: Harmful if inhaled. May cause nausea, vomiting, coughing and respiratory irritation. INGESTION: Aspiration into lungs can occur resulting in pneumonitis, pulmonary edema & hemorrhage. SUBCHRONIC, CHRONIC, OTHER CHRONIC Inhalation of Stoddard Solvent show results of hepatic and hematopoietic changes. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 91 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth to mouth. If breathing is difficult, give oxygen. Call a physician. EYES: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush skin with water. Wash clothing before reuse. INGESTION: If swallowed, DO NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area, contain as much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable absorbing material. Dispose of in approved landfill. Waste Disposal Methods: Dispose of in accordance with above described (or similarly approved) disposal procedure. Dispose of in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory NIOSH - approved respirator is recommended if exceeds 1 1 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 92 A Degreasing Solvent - Canada I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Degreasing Solvent - Canada Product Number: 4828 Synonyms: Chlorinated Hydrocarbon Solvent II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Stoddard Solvent* (ORAL LD50 8052-41-3 60 100ppm >10mg/kg) 71-55-6 40 350ppm # 1,1,1-trichlorethane** (ORAL LD50 rabbit 5660mg/kg) *STEL=200ppm; **STEL=450ppm # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate (ether=1) N/A VOC Content (% by wt.): 100 Solubility in H₂O: Slight pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: 165°F Appearance: Clear liquid Specific Gravity H₂O=1 @25° C: 0.982 Odor: Hydrocarbon odor IV - FIRE AND EXPLOSION Flash Point F 116F TOC Flammable Limits N/AV Extinguishing Media: Dry chemical, foam, CO₂. Special Fire Fighting Procedures: Exercise caution when fighting any chemical fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: Toxic gases and vapors such as hydrogen chloride, phosgene and carbon monoxide may be released if involved in a fire. V - REACTIVITY DATA Stability - Conditions to avoid: Keep away from heat and flame. Incompatibility: Strong oxidizers, aluminum and magnesium powders and sodium potassium. Hazardous Decomposition Products: See Section IV. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Causes irritation. May defat, dry and cause scaling of skin upon contact. INHALATION: Harmful if inhaled. May cause nausea, vomiting, coughing and respiratory irritation. INGESTION: Aspiration into lungs can occur resulting in pneumonitis, pulmonary edema & hemorrhage. SUBCHRONIC, CHRONIC, OTHER CHRONIC Inhalation of Stoddard Solvent show results of hepatic and hematopoietic changes. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 93 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth to mouth. If breathing is difficult, give oxygen. Call a physician. EYES: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush skin with water. Wash clothing before reuse. INGESTION: If swallowed, DO NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area, contain as much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable absorbing material. Dispose of in approved landfill. Waste Disposal Methods: Dispose of in accordance with above described (or similarly approved) disposal procedure. Dispose of in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory NIOSH - approved respirator is recommended if exceeds 1 1 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 94 A Degreasing Solvent ef I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Degreasing Solvent ef Product Number: 4162 Synonyms: Chlorinated Hydrocarbon Solvent II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Stoddard Solvent* (ORAL LD50 > 8052-41-3 60 100ppm 10mg/kg) 98-56-6 N/A p-Chlorobenzotrifluoride(a) 95-49-8 50ppm 250ppm o-Chlorotoluene 127-18-4 25ppm 170ppm Perchloroethylene(b,c,d,e,f) *STEL=200ppm a) This item is not identified in the available haz. chemicals guides. However, its characteristics parallel hazards of material that is identified; therefore, it will be so identified until further identification. b) Ingredient subject to reporting under Sec. 313 of Title III (SARA) and 40 CFR 372. c) RCRA has determined that the waste for this chemical is listed as hazardous and must be handled in accordance with 40 CFR 260-281. d)CERCLA has notification requirements for releases or spills to the environment of the Reportable Quantity(RQ 100lbs) or greater amounts (40CFR302). e)Material is on the NTP list of possible carcinogens IRAC's list of possible carcinogens OR is regulated by 1 1 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 97 98 A Drain-Solve I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Drain-Solve Product Number: 4165 Synonyms: Liquid caustic drain cleaner. II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Hydroxide 1310-73-2 >40 2mg/m3 N/A All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: N/A VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: >13 Boiling Point °F: 290°F Appearance: Clear liquid Specific Gravity H₂O=1 @25° C: 1.50 Odor: None IV - FIRE AND EXPLOSION Flash Point F None to boiling. Flammable Limits Product is non flammable Extinguishing Media: Product is non flammable. Special Fire Fighting Procedures: Avoid skin and eye contact, and avoid breathing of vapors. Wear head and body protection and alkali respirator if exposure is likely to happen. Firewater may become corrosive if they contact product. Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable . Incompatibility: Strong acids, materials not resistant to alkalis, active metals (zinc, aluminum, magnesium, etc.). Hazardous Decomposition Products: Contact with active metals can release flammable gas. Conditions Contributing to Hazardous Polymerizations: Does not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INHALATION Breathing of mists causes respiratory irritation and can cause burns. Wear approved alkali mist respirator if exposure is likely. SKIN is Corrosive. Causes irritation and burns. EYES Corrosive. Causes eye damage. INGESTION Corrosive. Causes irritation and burning in mouth, esophagus, throat and stomach. Avoid swallowing. Can be fatal. B. SUBCHRONIC, CHRONIC, OTHER: Chronic local effect may consist of multiple areas of superficial destruction of the skin or of primary irritant dermatitis. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 99 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Give artificial respiration or oxygen if needed. Get prompt medical attention. EYES: Flush immediately with water for 15 minutes. Get prompt medical attention. SKIN: Remove contaminated clothing. Flush skin thoroughly with water for 15 minutes. Get medical attention if burns persist. INGESTION: Drink lots of water or, perferably , milk. Get medical attention if effects persist. Do not induce vomiting. VIII - SPILL OR LEAK PROCEDURE Spill Management: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Larger spills should be contained by dyking or other methods and held for collection and/or reuse, or for neutralization with acid before collection and disposal. People should use eye and skin protection and respirator. Waste Disposal Methods: If neutralized, may be disposable in sewers if local regulations permit. Otherwise, send to licensed treatment and disposal facility. As supplied, this product is a RCRA hazardous waste. Rinse empty containers well before handling and disposal. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Wear approved alkali mist respirator if exposure is likely. Eye Protection Splash-proof goggles Gloves Alkali-resistant gloves Other Clothing and Equipment: Wear alkali-resistant protective gloves, boots and clothing. Provide convenient safety showers and eyewash stations. Ventilation: Use with adequate ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Check daily for leaks from containers, vessels, pumps and piping. Have water hoses and acid (caustic soda, lime, etc.) convenient. Only use containers and equipment designed for alkali service. 4 4 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 100 A EMKARATE RL 100H I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 100H Product Number: Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester >99 N/A Additives <1 N/A Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications.. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 102 A EMKARATE RL 100S I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 100S Product Number: 4317-56 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester >99 N/A Additives <1 N/A Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications.. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 104 A EMKARATE RL 150S I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 150S Product Number: 4317-80 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester >99 Not Listed Antioxidant <1 All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: <10 mm Hg @ 20°C Vapor Density (Air=1) 60-90° F: No data Evaporation Rate: N/A VOC Content (% by wt.): No data Solubility in H₂O: Insoluble pH @ Solution: No data Freezing Point °F: N/A pH as Distributed: No data Boiling Point °F: No data Appearance: Colorless liquid Specific Gravity H₂O=1 @25° C: 0.976 Odor: Mild IV - FIRE AND EXPLOSION Flash Point F 504°F Flammable Limits No data Extinguishing Media: Water, fog, foam, carbon dioxide, dry chemical, halogenated agents. Special Fire Fighting Procedures: Self-contained breathing apparatus with full face-plate & protective clothing. Unusual Fire and Explosion Hazards: None known. V - REACTIVITY DATA Stability - Conditions to avoid: Stable Incompatibility: Oxidizing agents. Hazardous Decomposition Products: Carbon dioxide, carbon monoxide. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION The acute oral LD50 in rat is probably above 2,000 mg/kg Relative to other materials, this material is classified as "slightly toxic" by ingestion. EYES: No irritation is likely to develop following contact with human eyes. SKIN: Short contact periods with human skin are not usually associated with skin irritation; repeated and/or prolonged contact can result in skin irritation. This product will probably not be absorbed through human skin. INHALATION: Inhalation data are not available on this material. Vapors and aerosols will probably irritate respiratory passages. B. SUBCHRONIC, CHRONIC, OTHER: No other adverse clinical effects have been associated with exposures to this material. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 105 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove victim to fresh air. If a cough or other respiratory symptoms develop, consult medical personnel. EYES: Immediately flush with plenty of water for at least 15 minutes. If redness, itching, or a burning sensation develops, have eyes examined and treated by medical personnel. SKIN: Wash material off of the skin with plenty of soap and water. If redness, itching, or a burning sensation develops, get medical attention. Wash contaminated clothing and decontaminate footwear before reuse. INGESTION: Do not induce vomiting. Give 1 or 2 glasses of water to drink. If gastrointestinal symptoms develop, consult medical personnel. (Never give anything by mouth to an unconscious person.) VIII - SPILL OR LEAK PROCEDURE Spill Management: Wear skin and respiratory protection during cleanup. Contain spill. Keep out of sewers and drains. Soak up material with absorbent and shovel into a chemical waste container. Waste Disposal Methods: Discarded product is not a hazardous waste under RCRA, 40 CFR 261. Empty container retains product residue. Observe all hazard precautions. Do not distribute, make available, furnish or reuse empty container except for storage and shipment of original product. Remove all product residue from container and puncture or otherwise destroy empty container before disposal. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Use MSHA-NIOSH approved respirator for organic vapors, dusts and mists whose TLV is greater than 0.05 mg/m3. Eye Protection Chemical tight goggles Gloves Impervious gloves Other Clothing and Equipment: Eyewash station and safety shower in work area. Ventilation: Use ventilation adequate to maintain safe levels. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Prevent skin contact. Avoid breathing vapors or aerosols. 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 106 A EMKARATE RL 170H I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 170H Product Number: 4318-25 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester >99 Not listed Antioxidant <1 All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: <10 mm Hg @ 20°C Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: N/A VOC Content (% by wt.): N/A Solubility in H₂O: Insoluble pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: N/A Appearance: Pale straw liquid Specific Gravity H₂O=1 @25° C: 0.976+ Odor: Mild IV - FIRE AND EXPLOSION Flash Point F 576°F 302°C Flammable Limits No data Extinguishing Media: Water, fog, foam, carbon dioxide, dry chemical, halogenated agents. Special Fire Fighting Procedures: Self-contained breathing apparatus with full face-plate & protective clothing. Unusual Fire and Explosion Hazards: None known. V - REACTIVITY DATA Stability - Conditions to avoid: Stable Incompatibility: Oxidizing agents. Hazardous Decomposition Products: Carbon dioxide, carbon monoxide. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION The acute oral LD50 in rat is probably above 2,000 mg/kg Relative to other materials, this material is classified as "slightly toxic" by ingestion. EYES: No irritation is likely to develop following contact with human eyes. SKIN: Short contact periods with human skin are not usually associated with skin irritation; repeated and/or prolonged contact can result in skin irritation. This product will probably not be absorbed through human skin. INHALATION: Inhalation data are not available on this material. Vapors and aerosols will probably irritate respiratory passages. B. SUBCHRONIC, CHRONIC, OTHER: No other adverse clinical effects have been associated with exposures to this material. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 107 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove victim to fresh air. If a cough or other respiratory symptoms develop, consult medical personnel. EYES: Immediately flush with plenty of water for at least 15 minutes. If redness, itching, or a burning sensation develops, have eyes examined and treated by medical personnel. SKIN: Wash material off of the skin with plenty of soap and water. If redness, itching, or a burning sensation develops, get medical attention. Wash contaminated clothing and decontaminate footwear before reuse. INGESTION: Do not induce vomiting. Give 1 or 2 glasses of water to drink. If gastrointestinal symptoms develop, consult medical personnel. (Never give anything by mouth to an unconscious person.) VIII - SPILL OR LEAK PROCEDURE Spill Management: Wear skin and respiratory protection during cleanup. Contain spill. Keep out of sewers and drains. Soak up material with absorbent and shovel into a chemical waste container. Waste Disposal Methods: Discarded product is not a hazardous waste under RCRA, 40 CFR 261. Empty container retains product residue. Observe all hazard precautions. Do not distribute, make available, furnish or reuse empty container except for storage and shipment of original product. Remove all product residue from container and puncture or otherwise destroy empty container before disposal. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Use MSHA-NIOSH approved respirator for organic vapors, dusts and mists whose TLV is greater than 0.05 mg/m3. Eye Protection Chemical tight goggles. Gloves Impervious gloves Other Clothing and Equipment: Eyewash station and safety shower in work area. Ventilation: Use ventilation adequate to maintain safe levels. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Prevent skin contact. Avoid breathing vapors or aerosols. 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: Reactivity..................... : Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 108 A EMKARATE RL 220H I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 220H Product Number: 4318 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester >99 N/A Antioxidant <1 N/A Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 110 A EMKARATE RL 22H I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 22H Product Number: 4313-46 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester >99 N/A Antioxidant <1 N/A Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 112 A EMKARATE RL 22N I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 22N Product Number: 4313-66 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester (New Jersey TSR: >99 N/A 08306620-5816P,5845P) <1 N/A Antioxidants Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 115 116 A EMKARATE RL 32CF I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 32CF Product Number: 4314-34 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester >99 N/A Additives <1 N/A Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure (mm Hg at 20°C) <10 Vapor Density (Air=1) 60-90° F: No data Evaporation Rate: VOC Content (% by wt.): No data Solubility in H₂O: <1% pH @ Solution: No data Freezing Point °F: pH as Distributed: No data Boiling Point °F: 572 Appearance: Liquid, pale yellow Specific Gravity H₂O=1 @25° C: 0.972 Odor: Mild Odor IV - FIRE AND EXPLOSION Flash Point F 490°F, 254°C (COC) Flammable Limits (STP) No data Extinguishing Media: Water fog, foam, carbon dioxide, dry chemical, halogenated agents Special Fire Fighting Procedures: Self-contained breathing apparatus with full face piece and protective clothing. Unusual Fire and Explosion Hazards: None known V - REACTIVITY DATA Stability - Conditions to avoid: Stable under normal conditions. Incompatibility: Oxidizing agents Hazardous Decomposition Products Combustion products Carbon dioxide, carbon monoxide Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) Inhalation No toxic effects are known to be associated with inhalation of vapors from this material. High concentrations of mist may be slightly irritating to the upper respiratory tract. Thermal decomposition will evolve irritant vapors. Ingestion: The acute oral LD50 in rat is probably above 2,000 mg/kg. Relative to other materials, this material is classified as "slightly toxic" by ingestion. Eyes: No irritation is likely to develop following contact with human eyes. Skin: Short contact periods with human skin are not usually associated with skin irritation; repeated and/or prolonged contact may result in mild skin irritation. This product will probably not be absorbed through human skin. B. SUBCHRONIC, CHRONIC, OTHER: No other adverse clinical effects have been associated with exposures to this material. Short term tests and a consideration of the structure indicate that this substance is unlikely to be a carcinogenic hazard to humans C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 117 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove victim to fresh air. If a cough or other respiratory symptoms develop, consult medical attention. EYES: Immediately flush with plenty of water for at least 15 minutes. If redness, itching, or a burning sensation develops, have eyes examined and treated by medical personnel. SKIN: Wash material off of the skin with plenty of soap and water. If redness, itching, or a burning sensation develops, get medical attention. Wash contaminated and decontaminate footwear before reuse. INGESTION: Do not induce vomiting. Give 1 or 2 glasses of water to drink and refer person to medical personnel. (Never give anything by mouth to an unconscious person.) VIII - SPILL OR LEAK PROCEDURE Spill Management: Wear skin protection during cleanup. Contain spill. Keep out of sewers and drains. Soak up material with absorbent and shovel into a chemical waste container. Waste Disposal Methods: Discarded product is not a hazardous waste under RCRA, 40 CFR 261. Empty container retains product residue. Observe all hazard precautions. Do not distribute, make available, furnish, or reuse empty container except for storage and shipment of original product. Remove all product residue from container and puncture or otherwise destroy empty container before disposal.Ecological Information: Persistency and degradation: The product is substantially biodegradable in water IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not normally needed, if controls are adequate. If needed, use MSHA-NIOSH approved respirator for organic vapors Eye Protection Chemical tight goggles Gloves Impervious gloves and apron Other Clothing and Equipment: Eyewash station and safety shower in work area. Ventilation: Use ventilation adequate to maintain safe levels. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Prevent skin contact. Avoid inhalation of high concentrations of mists. 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 118 A EMKARATE RL 32H I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 32H Product Number: 4314-46 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester >99 N/A Additives <1 N/A Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 120 A EMKARATE RL 32HB I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 32HB Product Number: 4314-HB Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 97 N/A Antioxidant < 1 N/A Tricresyl Phosphate (TCP cont. 1330-78-5 < 2 N/A <1.0% ortho isomer) Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 123 124 A EMKARATE RL 32S I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 32S Product Number: 4314-56 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 08306620-5803P >99 N/A Additives <1 N/A Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 126 A EMKARATE RL 46H I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 46H Product Number: 4315-H Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester (New Jersey 99% N/A TSR#:08306620-5845P,5846P) N/A Additives 1% N/A Antioxidant Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 128 A EMKARATE RL 68H I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 68H Product Number: 4316-41 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol ester 08306620-5845P, >99 Not listed Additives 5846P <1 Not listed Ingredients not precisely identified are proprietary or non hazardous. Values are not product specifications. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 130 A EMKARATE RL 68HP I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 68HP Product Number: 4316-76 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 08306620-5845P, >98 N/A Additives 5846P <2 N/A Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 132 A EMKARATE RL 68S I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: EMKARATE RL 68S Product Number: 4316-S Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 08306620-5843P, >99 N/A Antioxidant 5844P <1 N/A Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. None of the ingredients are subject to the reporting requirements of 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 134 A Evap Pow'r - C I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Evap Pow'r - C Product Number: 4168 Synonyms: Evaporator coil cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # 2-butoxyethanol (111-76-2) <10 25ppm (skin) 25ppm ne sodium xylene sulfonate (1300-72-7) <15 ne # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. This product contains no chemicals rated as carcinogens or suspect carcinogens by N.T.P., I.A.R.C., or O.S.H.A.VOC Content: 5.3% (by wt) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate: (ether=1) Unknown VOC Content (% by wt.): 80 Solubility in H₂O: Complete pH @ 25% Solution: 7.5 Freezing Point °F: Unknown pH as Distributed: 8.0 Boiling Point °F: ~210 Appearance: Clear, green liquid Specific Gravity H₂O=1 @25° C: 1.04 Odor: Chemical odor IV - FIRE AND EXPLOSION Flash Point F Not flammable Flammable Limits N/A Extinguishing Media: Product is not flammable or combustible. Special Fire Fighting Procedures: None known. Unusual Fire and Explosion Hazards: None known. V - REACTIVITY DATA Stability - Conditions to avoid: None known. Incompatibility: None known. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Causes eye and skin irritation. Readily absorbed through skin. INHALATION Mists may be irritating. INGESTION May cause upset stomach if swallowed B. SUBCHRONIC, CHRONIC, OTHER: None known. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 135 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. EYES: Flush with plenty of water for 15 minutes. If irritation develops, call a physician. SKIN: Wash with soap and plenty of water for 15 minutes. If irritation develops, call a physician. INGESTION: N/A VIII - SPILL OR LEAK PROCEDURE Spill Management: Take up on absorbant material. Flush residue to sewer with plenty of water. Waste Disposal Methods: May be sewered in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not normally required Eye Protection Safety glasses Gloves Rubber Other Clothing and Equipment: None required. Ventilation: Good general room ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes and skin. Avoid breathing mists. Wear safety glasses and gloves when handling. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 136 A Evap Pow'r - RTU I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Evap Pow'r - RTU Product Number: 4169 Synonyms: Evaporator coil cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # 2-butoxyethanol 111-76-2 <2 25ppm (skin) 25ppm sodium xylene sulfonate 1300-72-7 ne # Ingredient subject to reporting <2 ne under Section 313 of Title III (SARA) and 40 CFR 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate: (ether=1) Unknown VOC Content (% by wt.): 95 Solubility in H₂O: Complete pH @ 25% Solution: N/A Freezing Point °F: Unknown pH as Distributed: 8.0 Boiling Point °F: ~210° Appearance: Clear, pale green liquid Specific Gravity H₂O=1 @25° C: 1.01 Odor: Faint chemical odor IV - FIRE AND EXPLOSION Flash Point F Non flammable Flammable Limits N/A Extinguishing Media: Product is non flammable or combustible. Special Fire Fighting Procedures: None known. Unusual Fire and Explosion Hazards: None known. V - REACTIVITY DATA Stability - Conditions to avoid: None known. Incompatibility: Strong acids/oxidizers; do not mix with chlorinated detergents (bleach). Hazardous Decomposition Products: Burning may produce oxides of carbon. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN May cause irritation. INHALATION Mists may be slightly irritating to upper respiratory tract. INGESTION: Not expected to be harmful if swallowed. B. SUBCHRONIC, CHRONIC, OTHER: None known. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with plenty of water. If irritation persists, get medical attention. SKIN: Wash well with soap and plenty of water for 15 minutes. Call physician. INGESTION: N/A 137 VIII - SPILL OR LEAK PROCEDURE Spill Management: Take up on absorbent material. Flush residue to sewer with plenty of water. Waste Disposal Methods: May be sewered in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Safety glasses Gloves Rubber gloves Other Clothing and Equipment: None required. Ventilation: Good general room ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes and skin. Avoid breathing mists. Wear safety glasses and rubber gloves when handling. Keep out of the reach of children. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 138 A Fluorescent Gas Leak Detector I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Fluorescent Gas Leak Detector Product Number: 4184 Synonyms: Bubble-Forming Liquid II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # Ethylene glycol (ORAL LD50 107-21-1 <40 50ppm ceiling NE 8.5mg/kg rat) (vapor) # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate (ether=1) Unknown VOC Content (% by wt.): @85 Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: 7.3 - 7.6 Boiling Point °F: Unknown Appearance: Fluorescent green liquid Specific Gravity H₂O=1 @25° C: 1.085 Odor: Mild chemical odor IV - FIRE AND EXPLOSION Flash Point F >200°F Flammable Limits Unknown Extinguishing Media: In case of fire, use CO₂ foam or dry chemical. Special Fire Fighting Procedures: Exercise caution when fighting any chemical fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: None known. V - REACTIVITY DATA Stability - Conditions to avoid: Heat and open flame. Incompatibility: Can react violently with strong oxidizers, dehydrating agents such as sulfuric acid, acetic anhydride. Hazardous Decomposition Products: Carbon monoxide. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES May cause eye irritation. SKIN Essentially non - irritating INGESTION: Harmful if swallowed. May cause nausea, dizziness, central nervous system damage, kidney disorders. INHALATION: Prolonged or repeated breathing of vapors may cause headache, nausea, dizziness. B. SUBCHRONIC, CHRONIC, OTHER: Repeated or prolonged inhalation of vapors may cause central nervous system damage. Repeated contact with skin may cause sensitization in some individuals. Ethylene glycol has cause birth defects in laboratory animals. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 139 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. EYES: Flush with plenty of water for at least 15 minutes. If irritation persists, call a physician. SKIN: Wash area with soap and plenty of water. INGESTION: If swallowed, call physician immediately. Give one or two glasses of water and induce vomiting by sticking finger down throat. Never give anything by mouth or attempt to induce vomiting in an unconscious person. VIII - SPILL OR LEAK PROCEDURE Spill Management: Flush spill with water or wipe up and incinerate. Waste Disposal Methods: Incinerate or flush to drain served by sanitary sewer in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not normally required Eye Protection Avoid eye contact Gloves None required Other Clothing and Equipment: None required. Ventilation: Vapors are minimal at room temperatures. Normal room ventilation should be sufficient. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. Avoid breathing mists or vapors. Wash thoroughly after handling. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 140 A Foam Insulation Tape I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Foam Insulation Tape Product Number: 4219 Synonyms: Same II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL None All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: N/A VOC Content (% by wt.): N/A Solubility in H₂O: NO pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: N/A Appearance: Soft, pliable, pressure sensitive Specific Gravity H₂O=1 @25° C: Odor: IV - FIRE AND EXPLOSION Flash Point F 350°F Flammable Limits N/A Extinguishing Media: Water Fog, Foam, Carbon dioxide, Dry chemical Special Fire Fighting Procedures: Water unsuited for rubber fires Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: This product is stable and hazardous decomposition will not occur. Incompatibility: Strong oxidizing agents, Lewis acids Hazardous Decomposition Products: Carbon monoxide, hydrocarbons, HCI, smoke, fumes Conditions Contributing to Hazardous Polymerizations: VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION N/A; EYES & SKIN N/A B. SUBCHRONIC, CHRONIC, OTHER: None known C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Not applicable EYES: Treat as any foreign particle. Flush eyes with running water for several minutes until all of the material is removed. Seek medical attention if irritation persists. SKIN: Wash thoroughly with soap and water if any signs of irritation appear. Individuals who show symptoms of an allergic reaction or sensitization should sheek medical attention and should avoid further contact with this product. INGESTION: Not applicable 141 VIII - SPILL OR LEAK PROCEDURE Spill Management: Repackage uncontaminated tape. Waste Disposal Methods: Recover material and place into suitable container. Dispose of in accordance with federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: N/A Eye Protection N/A Gloves N/A Other Clothing and Equipment: N/A Ventilation: N/A X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Prevent high temperature exposure. 0 0 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 1 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 142 A Foam-Brite I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Foam-Brite Product Number: 4178 Synonyms: Alkaline Coil Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Hydroxide (Caustic Soda) 1310-73-2 >20 2mg/M3 Ceiling VOC Content: 2.8% All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Not Determined Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate: (ether=1) Same as H₂O VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ 10% Solution: 12.9 Freezing Point °F: N/A pH as Distributed: 14.0 Boiling Point °F: 212°F Appearance: Clear, reddish-orange liquid Specific Gravity H₂O=1 @25° C: 1.252 +/- 0.005 Odor: No Distinct Odor IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits N/A Extinguishing Media Water spray (Fog) Dry chemical; CO₂; Foam Special Fire Fighting Procedures: Do not enter confined fire-spaces without protective clothing and self- contained air supply. Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: Stable Incompatibility: Strong acids/oxidizers. Do not mix with chlorinated detergents (bleach) Hazardous Decomposition Products: Burning may produce carbon monoxide and/or carbon dioxide. Conditions Contributing to Hazardous Polymerizations: N/A VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYE, SKIN, ORAL Corrosive material. Will cause burns of skin and eyes with prolonged contact. Eye damage likely if contact is prolonged. Generated mists may be seriously irritating and cause damage to respiratory tract if swallowed. Harmful or fatal if swallowed. May cause severe burns of mucous membranes, stomach, nausea, vomiting - possible internal damage. B. SUBCHRONIC, CHRONIC, OTHER: Chronic local effect may consist of multiple areas of superficial destruction of the skin or of primary irritant dermatitis. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 143 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Start artificial respiration if necessary. Oxygen may be administered. Call a physician. EYES: & SKIN Flush eyes with water for at least 15 minutes and call a physician immediately. Skin Wash affected area with large amounts of soap and water. If irritation persists call physician. INGESTION: Do not induce vomiting. Dilute by drinking water. Call a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Safely stop spill at source. Contain spill by diking with soil or other inert material and CAREFULLY neutralize with dilute acid. Mop, pump or absorb with inert material and reclaim into sound containers for proper disposal. Waste Disposal Methods: Dispose of in an approved waste facility according to Federal, State and local regulations. Keep non-neutralized material out of sewers, storm drains, surface water and soil. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH approved respirator where mists or sprays may be generated. (Caustic mist cartridge type) Eye Protection Chemical goggles, face shield Gloves Rubber gloves Other Clothing and Equipment: Protective clothing to minimize contact (boots, apron, faceshield) Ventilation: Product is intended for outdoor use. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Corrosive Material - Handle All Containers Carefully. Wash thoroughly after handling. Keep containers closed when not in use. Avoid contact with leather or wool. 3 3 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 144 A Freez-Kontr'l I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Freez-Kontr'l Product Number: 4188 Synonyms: Monopropylene Glycol II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Propylene Glycol 57-55-6 70 - 80% All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg 0.1 Vapor Density (Air=1) 60-90° F: 2.6 Evaporation Rate (ether=1) N/A VOC Content (% by wt.): slightly volatile Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: -76° F pH as Distributed: Boiling Point °F: 360°F Appearance: Light blue liquid slightly vis. Specific Gravity H₂O=1 @25° C: 1.04 Odor: Near odorless IV - FIRE AND EXPLOSION Flash Point F 211°F Flammable Limits (% vol. in air) -17.4 Extinguishing Media: CO₂ Dry chemical, Alcohol type foam Special Fire Fighting Procedures: Do not enter fire area without proper protection. See "decomposition products possible." Fight fire from safe distance/protected location. Heat may build pressure/rupture closed containers. Spreading fire. Increasing risk of burns/injuries. Use water spray/fog for cooling. Avoid frothing/steam explosion. Burning liquid may float on water. Although soluble, may not be practical to extinguish fire by water dilution. Notify authorities if liquid enters sewer/public water. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: Stable; avoid high temperatures and severe oxidizing conditions. Incompatibility: Strong oxidizing agents. Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide and other harmful gases/vapors. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), A. ACUTE (Primary Route of Exposure): Slight eye irritant, No inhalation hazard identified from data. No skin absorption hazard identified from data. No skin irritation identified from data. No ingestion hazard identified from data. B. SUBCHRONIC, CHRONIC, OTHER: No chronic health effects are expected from normal use. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 145 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: Flush with water for 20-30 minutes retract eyelids often. Obtain medical attention if pain, blinking, tears or redness persist. SKIN: Not expected to present a significant skin hazard under anticipated conditions of normal use. INGESTION: Not expected to present a significant ingestion hazard under anticipated conditons of normal use. VIII - SPILL OR LEAK PROCEDURE Spill Management: Evacuate/limit access. Prevent flow to sewers/public water. Stop release. Notify fire/environmental authorities. Restrict water use for cleanup. Slippery walking. Spread granular cover. Soak up small spill with inert solids. Use suitable disposal containers on water soluble material may float or sink. May biodegrade. Contain/minimize dispersion. Disperse residue to reduce aquatic harm. Report per regulatory requirements. Waste Disposal Methods: Landfill solids at permitted sites. Use registered transporters. Burn concentrated liquids. Diluting with clean, low viscosity fuel. Avoid flameouts. Assure emissions comply with applicable regulations. Avoid overloading/poisoning plant biomass. Assure effluent complies with applicable regulations. Contaminated product, soil or water should not be designated RCRA Hazardous waste. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: None when used with adequate ventilation. Eye Protection Safety glasses Gloves Recommended Other Clothing and Equipment: None required. Ventilation: Use with adequate ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Hygroscopic, use dry nitrogen or low dew point air for tank padding. Keep drums tightly closed to prevent contamination. Store at 65 - 90°F. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 146 A Freez-Therm I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Freez-Therm Product Number: 4189 Synonyms: Inhibited Ethylene Glycol II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Ethylene glycol** 107-21-1 >95 100 ppm 50 ppm Dipotassium phosphate 7758-11-4 >2 Water 7732-18-5 >2 **Subject to reporting requirements under 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 149 150 A Freez-Therm UH I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Freez-Therm UH Product Number: 4189-02 Synonyms: Uninhibited Ethylene Glycol II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Ethylene glycol** 107-21-1 >96 100 ppm 50 pppm Water 7732-18-5 <4 **Subject to reporting requirements under 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 152 A Gas Leak Detector I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Gas Leak Detector Product Number: 4180 Synonyms: Chemical Leak Detector II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Isopropanol* (ORAL LD50 67-63-0 5 400ppm 5840mg/kg Rat) *STEL=500ppm All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate (ether=1) Unknown VOC Content (% by wt.): 5 Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: Unknown Appearance: Clear solution Specific Gravity H₂O=1 @25° C: 1.10 - 1.15 Odor: Isopropanol odor IV - FIRE AND EXPLOSION Flash Point F 102°F Flammable Limits Unknown Extinguishing Media: In case of fire use CO₂ , foam or dry chemical. Special Fire Fighting Procedures: Exercise caution when fighting any chemical fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: None known. V - REACTIVITY DATA Stability - Conditions to avoid: Heat and open flame. Incompatibility: Can react violently with strong oxidizers. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN May cause irritation to both eyes and skin. INGESTION Large quantities may cause upset to stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush with plenty of water for at least 15 minutes. If irritation develops, contact a physician. INGESTION: If swallowed, call a physician immediately. 153 VIII - SPILL OR LEAK PROCEDURE Spill Management: Flush spill with water or wipe up and incinerate. Waste Disposal Methods: Flush product waste down drain with plenty of water, rinse container and discard. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: None required Eye Protection Avoid eye contact Gloves None required Other Clothing and Equipment: None required. Ventilation: Normal room ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. Keep away from heat and open flame. Wash thoroughly after handling. 0 0 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 154 A Gas Leak Detector - Canada I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Gas Leak Detector - Canada Product Number: 4832 Synonyms: Chemical Leak Detector II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Isopropanol* (ORAL LD50 67-63-0 5 400ppm 5840mg/kg Rat) *STEL=500ppm All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate (ether=1) Unknown VOC Content (% by wt.): 5 Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: Unknown Appearance: Clear solution Specific Gravity H₂O=1 @25° C: 1.10 - 1.15 Odor: Isopropanol odor IV - FIRE AND EXPLOSION Flash Point F 102°F Flammable Limits Unknown Extinguishing Media: In case of fire use CO₂ , foam or dry chemical. Special Fire Fighting Procedures: Exercise caution when fighting any chemical fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: None known. V - REACTIVITY DATA Stability - Conditions to avoid: Heat and open flame. Incompatibility: Can react violently with strong oxidizers. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN May cause irritation to both eyes and skin. INGESTION Large quantities may cause upset to stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush with plenty of water for at least 15 minutes. If irritation develops, contact a physician. INGESTION: If swallowed, call a physician immediately. 155 VIII - SPILL OR LEAK PROCEDURE Spill Management: Flush spill with water or wipe up and incinerate. Waste Disposal Methods: Flush product waste down drain with plenty of water, rinse container and discard. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: None required Eye Protection Avoid eye contact Gloves None required Other Clothing and Equipment: None required. Ventilation: Normal room ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. Keep away from heat and open flame. Wash thoroughly after handling. 0 0 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 156 A Green Clean I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Green Clean Product Number: 4186 Synonyms: General purpose cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Dipropylene Glycol Methyl Ether 34590-94-8 < 6 100 ppm 150 ppm Sodium Carbonate 497-19-8 < 6 N/A All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Not determined Vapor Density (Air=1) 60-90° F: Not Deter. Evaporation Rate (ether=1) ~same VOC Content (% by wt.): Not Determined Solubility in H₂O: Complete pH @ 25% Solution: 8.0 Freezing Point °F: Unknown pH as Distributed: 11.7 Boiling Point °F: 212° Appearance: Clear, green liquid Specific Gravity H₂O=1 @25° C: 1.04 Odor: Chemical IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits N/A Extinguishing Media: Product is not flammable or combustible. Special Fire Fighting Procedures: None known. Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: None known; product is stable Incompatibility: Strong acids/oxidizers. Do not mix with chlorinated detergents Hazardous Decomposition Products: Burning may produce oxides of carbon Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), A. ACUTE (Primary Route of Exposure): Direct contact with eyes may cause mild to moderate irritation with local redness and swelling of conjunctiva. Prolonged or repeated skin contact may cause irritation. Ingestion may cause irritation of mouth, throat and stomach with possible nausea and vomiting. Excessive inhalation of vapors may cause respiratory tract irritation and central nervous system effects including headache and nausea. B. SUBCHRONIC, CHRONIC, OTHER: C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Start artificial respiration if necessary. Oxygen may be administered. Call A physician. EYES: Flush with water for at least 15 minutes and call a physician immediately SKIN: Wash with large amounts of soap and water. If irritation persists, consult a physician INGESTION: Do NOT induce vomiting. Dilute by drinking water. Call a physician immediately. 157 VIII - SPILL OR LEAK PROCEDURE Spill Management: Do not touch or walk through spilled material. Stop leak if you can without risk. Dike ahead of large spills to prevent run-off. Mop, pump or take up with sand or other inert absorbent and reclaim into containers for reuse, recycle, or proper disposal. Waste Disposal Methods: Dispose of in an approved waste facility according to Federal, State and Local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not normally required Eye Protection Safety glasses Gloves Rubber gloves ,PVC Other Clothing and Equipment: None required. Ventilation: Good general room ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: No special requirements if product is handled according to good manufacturing practices. Keep container closed when not in use. Wash thoroughly after handling. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 158 A Ice Guard I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Ice Guard Product Number: 4209 Synonyms: Heterogeneous Catalyst II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Aluminum Oxide 1344-28-1 >96 10 15 Copper 7440-50-8 <3 1 Silver 7440-22-4 <1 0.1 All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: Solid Vapor Density (Air=1) 60-90° F: Solid Evaporation Rate: N/A VOC Content (% by wt.): less than 5% Solubility in H₂O: Insoluble pH @ Solution: Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: Appearance: Black-Green Spherical Particles Specific Gravity H₂O=1 @25° C: Solid Odor: None IV - FIRE AND EXPLOSION Flash Point F: Flammable Limits: Extinguishing Media: Use extinguishing agent applicable to surrounding fire. Special Fire Fighting Procedures: As in any fire, wear self-contained breathing apparatus operated in pressure- demand mode, (MSHA/NIOSH approved or equivalent) and full protective gear. Unusual Fire and Explosion Hazards: May emit toxic fumes when heated to decomposition. Dusts at sufficient concentrations can form explosive mixtures with air. V - REACTIVITY DATA Stability - Conditions to avoid: Wet storage Incompatibility: N/A Hazardous Decomposition Products: N/A Conditions Contributing to Hazardous Polymerizations: No VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), A. ACUTE (Primary Route of Exposure): Inhalation may cause irritation of eyes and nose. Inhalation of fumes may cause metal fume fever (flu-like symptoms: fever, cough, chest pains, muscle weakness, nausea, vomiting, and a high white blood cell count). B. SUBCHRONIC, CHRONIC, OTHER: Inhalation of high dust concentration may damage the respiratory tract. Aluminum oxide has been linked to emphysema and other respiratory diseases. Chronic ingestion of aluminum has been linked to central nervous system disorders including Alzheimer's Disease. Workers with kidney disease are at an increased risk. Individuals with lung diseases and/or kidney diseases should be protected from exposure. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE EYES Scratch or abrasion, damage to cornea (necrosis). SKIN Irritation, rash, itching, discoloration of the skin. INGESTION May cause vomiting, upset stomach. INHALATION: Coughing, wheezing, shortness of breath, difficult breathing, chest pain. 159 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen by trained personnel. Seek immediate medical attention. EYES: Immediately flush eyes with plenty of water (15 minute minimum). Get medical attention if irritation persists. SKIN: Wash with soap and water. Get medical attention if irritation develops or persists. INGESTION: If swallowed, induce vomiting only as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Sweep up spilled material and repackage. Minimize airborne particulates. Protect against inhalation of dusts. Avoid contact with skin. Use eye protection. Waste Disposal Methods: Dispose of in a landfill in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required for normal use. Eye Protection Not required for normal use. Gloves Not required for normal use Other Clothing and Equipment: N/A Ventilation: Normal X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Wash thoroughly after handling. Keep product sealed when not in use. Store in a dry place. Exercise caution in the storage and handling of all chemical substances. 0 0 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 160 A Icematic E100 I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Icematic E100 Product Number: 4317-05 Synonyms: Polyol Ester Lubricant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 131459-39-7 99% not list'd Antioxidant Additive Package n/a without non- <1% not list'd disclosure agreement Contains no SARA 313 compounds All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: (mmHg) negligible Vapor Density (Air=1) 60-90° F: 5 Evaporation Rate: Negligible VOC Content (% by wt.): negligible Solubility in H₂O: Insoluble pH @ not applicable Solution: - Freezing Point °F: Not determined pH as Distributed: N/A Boiling Point °F: >500°F Appearance: Clear colorless liquid Specific Gravity H₂O=1 @25° C: 0.98 Odor: Slight petroleum odor IV - FIRE AND EXPLOSION Flash Point F 450°F min (method PMCC) Flammable Limits N/D Extinguishing Media: Carbon dioxide, foam, dry chemical. Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: V - REACTIVITY DATA Stability - Conditions to avoid: Stable under normal conditions - none known. Incompatibility: Strong oxidizers, heat and sources of ignition. Hazardous Decomposition Products: Smoke, fumes, CO, CO₂ Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Can cause gastro-intestinal irritation, nausea, vomiting, abdominal pain & diarrhea. EYES & SKIN: May cause mild irritation. Prolonged or repeated skin contact may cause skin irritation, defatting. INHALATION: May cause nasal/respiratory irritation, dizziness. B. SUBCHRONIC, CHRONIC, OTHER: No obvious long-term hazards C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 161 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from exposure area to fresh air immediately. If breathing has stopped, perform CPR. Keep person warm and at rest. Treat symptomatically and supportively. Get medical attention immediately . EYES: Flush eyes with large amounts of clean water for at least 15 minutes. Contact a physician if irritation persists SKIN: Remove contaminated clothing. Wipe material from skin. Wash thoroughly with soap and water.If irritation develops, get medical attention. Wash contaminated clothing. Use skin cream for defatted areas INGESTION: Do not induce vomiting; aspiration hazard. Do not give anything by mouth. Do not leave victim unattended. If vomiting occurs, or if comatose or lethargic, place on the left side with the head down. Seek medical attention immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management Large spills wear appropriate protective clothing. Do not permit product to enter streams, sewers or other waterways. Dike spill and eliminate leak. Absorb with inert material and store in closed containers until disposal. Flush area with water. Where feasible, remove contaminated soil. Small spills: Neutralize and/or soak up spill with inert absorbent; store in closed containers until disposal. Waste Disposal Methods: All recovered material should be packaged, labelled, transported, and disposed of or reclaimed in conformance with good engineering practices. Dispose of by method in compliance with local, state and federal regulations regarding health, air and water pollution. May be destroyed by controlled incineration. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH/MSHA Approved organic vapor respirator or supplied air respiratory equipment as required. Eye Protection Safety glasses with side-shields Gloves Neoprene gloves Other Clothing and Equipment: Impervious protective clothing and chemical-resistant safety shoes should be worn to minimize contact. Emergency shower and eyewash facility should be provided in all areas in which this product is handled. Ventilation: Provide sufficient mechanical, general and/or local exhaust to maintain exposure below TLV. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Maintain ambient temperatures. Avoid prolonged/repeated breathing of vapors, mists, fumes. Keep container tightly closed. Do not store near heat, flame, strong oxidants. Maintain adequate ventilation. 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 162 A Icematic E68 I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Icematic E68 Product Number: 4316-16 Synonyms: Polyol Ester Lubricant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 131459-39-7 99% Not listed Antioxidant Additive Package n/a without non- <1% Not listed disclosure agreement VOC Content: 0.01lbs./gallon (1.0 %) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Negligible Vapor Density (Air=1) 60-90° F: >5 Evaporation Rate (ether=1) Negligible VOC Content (% by wt.): Negligible Solubility in H₂O: Not Soluble in Water pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: >500°F Appearance: Clear, colorless liquid Specific Gravity H₂O=1 @25° C: 0.98 Odor: Slight petroleum odor IV - FIRE AND EXPLOSION Flash Point F >400°F (COC) Flammable Limits ND Extinguishing Media: Dry chemical, CO₂, Foam Special Fire Fighting Procedures: Use water as fog or spray to cool containers exposed to fire. Wear self- contained breathing apparatus. Unusual Fire and Explosion Hazards: Empty containers may contain product residue or vapors which can ignite explosively; do not cut, weld or drill on or near empty or full containers. V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable - avoid oxidizing agents, heat, open flame. Incompatibility: None Hazardous Decomposition Products: Smoke, fumes, CO₂, CO . Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Can cause gastro-intestinal irritation, nausea, vomiting & diarrhea. EYES & SKIN: May cause mild irritation. Prolonged or repeated skin contact may cause skin irritation, defatting. INHALATION: May cause nasal/respiratory irritation, dizziness. B. SUBCHRONIC, CHRONIC, OTHER: N/A C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 163 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from area of exposure. Administer oxygen if deemed necessary. If breathing has stopped, administer CPR; contact physician. EYES: Flush eyes with large amounts of clean water for at least 15 minutes. Contact a physician if irritation persists. SKIN: Remove contaminated clothing. Wipe material from skin. Wash thoroughly with soap and water. INGESTION: Do not induce vomiting; aspiration hazard. Consult a physician immediately. If vomiting occurs, or if comtose or lethargic, place on the left side with the head down . Consult a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Do not permit product to enter streams, sewers or other waterways. Dike spill and eliminate leak. Absorb with inert material and store in closed containers until disposal. Waste Disposal Methods: All recovered material should be packaged, labelled, transported, and disposed of or reclaimed in conformance with good engineering practices. Dispose of by method in compliance with local, state and federal regulations regarding health, air and water pollution. May be destroyed by controlled incineration. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH/MSHA Approved organic vapor respirator or supplied air respiratory equipment as required. Eye Protection Safety glasses Gloves Resistant type gloves Other Clothing and Equipment: N/A Ventilation: Provide sufficient mechanical, general and/or local exhaust to maintain exposure below TLV. Greater than 60 +3/Min. recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Maintain ambient temperatures. Avoid prolonged/repeated breathing of vapors, mists, fumes. Keep container tightly closed. Do not store near heat, flame, strong oxidants. Maintain adequate ventilation. 0 0 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 164 A Icematic SW 100 I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Icematic SW 100 Product Number: 4317 Synonyms: Polyol Ester Lubricant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 131459-39-7 99% Not listed Antioxidant Additive Package n/a without non- <1% Not listed disclosure agreement VOC Content: 0.01lbs./gallon (1.0 %) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: Negligible Vapor Density (Air=1) 60-90° F: >5 Evaporation Rate: Negligible VOC Content (% by wt.): Negligible Solubility in H₂O: Not soluble in Water pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: >500°F Appearance: Clear, colorless liquid Specific Gravity H₂O=1 @25° C: 0.98 Odor: Slight petroleum odor IV - FIRE AND EXPLOSION Flash Point F >450°F (COC) Flammable Limits ND Extinguishing Media: Dry chemical, CO₂, Foam Special Fire Fighting Procedures: Use water as fog or spray to cool containers exposed to fire. Wear self- contained breathing apparatus. Unusual Fire and Explosion Hazards: Empty containers may contain product residue or vapors which can ignite explosively; do not cut, weld or drill on or near empty or full containers. V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable - avoid oxidizing agents, heat, open flame Incompatibility: Strong oxidizers, heat and sources of ignition. Hazardous Decomposition Products: Smoke, fumes, CO, CO₂. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Can cause gastro-intestinal irritation, nausea, vomiting & diarrhea. EYES & SKIN: May cause mild irritation. Prolonged or repeated skin contact may cause skin irritation, defatting. INHALATION: May cause nasal/respiratory irritation, dizziness. B. SUBCHRONIC, CHRONIC, OTHER: N/A C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 165 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from area of exposure. Administer oxygen if deemed necessary. If breathing has stopped, administer CPR; contact physician. Keep person warm and at rest. Treat symptomatically and supportively. EYES: Flush eyes with large amounts of clean water for at least 15 minutes. Contact a physician if irritation persists. SKIN: Remove contaminated clothing. Wash thoroughly with soap and water. Contact a physician if irritation persists. Use skin cream for defatted areas. INGESTION: Do not induce vomiting; aspiration hazard. If vomiting occurs, or if comatosa or lethargic, place on the left side with the head down. Consult a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Do not permit product to enter streams, sewers or other waterways. Dike spills and eliminate leak. Absorb with inert material and store in closed containers until disposal. Waste Disposal Methods: All recovered material should be packaged, labeled, transported, and disposed of or reclaimed in conformance with good engineering practices. Dispose of by method in compliance with local, state and federal regulations regarding health, air and water pollution. May be destroyed by controlled incineration. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH/MSHA Approved organic vapor respirator or supplied air respiratory equipment as required. Eye Protection Safety goggles Gloves Resistant type gloves Other Clothing and Equipment: N/A Ventilation: Provide sufficient mechanical, general and/or local exhaust to maintain exposure below TLV. Greater than 60+ 3/Min. recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Maintain ambient temperatures. Avoid prolonged/repeated breathing of vapors, mists, fumes. Keep container tightly closed. Do not store near heat, flame, strong oxidants. Maintain adequate ventilation. 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 166 A Icematic SW 220 I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Icematic SW 220 Product Number: 4318-05 Synonyms: Polyol Ester Lubricant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 131459-39-7 99% Not listed Antioxidant Additive Package n/a without non- <1% Not listed disclosure agreement VOC Content: 0.01lbs./gallon (1.0 %) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: Negligible Vapor Density (Air=1) 60-90° F: >5 Evaporation Rate: Negligible VOC Content (% by wt.): Negligible Solubility in H₂O: Insoluble pH @ Solution: N/A Freezing Point °F: Not determined pH as Distributed: N/A Boiling Point °F: >500° Appearance: Clear colorless Specific Gravity H₂O=1 @25° C: 0.9800 Odor: Slight petroleum odor IV - FIRE AND EXPLOSION Flash Point F >464°F 240°C Flammable Limits N/D N/D Extinguishing Media: Dry chemical, foam, carbon dioxide Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire-exposed container cool. Water spray may be used to flush spills away from exposure. Firefighters must use self-contained breathing apparatus. Prevent run-off from fire control from entering streams or drinking water supply. Unusual Fire and Explosion Hazards: V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable under normal conditions - avoid oxidizing agents, heat, open flame. Incompatibility: None Hazardous Decomposition Products: Smoke, fumes, CO, CO₂ Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Can cause gastro-intestinal irritation, nausea, vomiting & diarrhea. EYES & SKIN: May cause mild irritation. Prolonged or repeated skin contact may cause skin irritation, defatting. INHALATION: May cause nasal/respiratory irritation, dizziness. B. SUBCHRONIC, CHRONIC, OTHER: None C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: See acute effects above. 167 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from area of exposure to fresh air immediately. Administer oxygen if deemed necessary. If breathing has stopped, administer CPR; keep person warm and at rest. Contact physician immediately. EYES: Flush eyes with large amounts of clean water for at least 15 minutes. Contact a physician if irritation persists. SKIN: Remove contaminated clothing. Wipe material from skin. Wash thoroughly with soap and water. If irritation persists, get medical attention. Wash clothing before reuse. Use skin cream for defatted areas. INGESTION: Aspiration hazard. Do not induce vomiting or give anything by mouth. Do not leave victim unattended. If vomiting occurs or if comatosa or lethargic, place on the left side with head down Consult a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Do not permit product to enter streams, sewers or other waterways. Dike spill and eliminate leak. Absorb with inert material and store in closed containers until disposal. Waste Disposal Methods: All recovered material should be packaged, labelled, transported, and disposed of or reclaimed in conformance with good engineering practices. Dispose of by method in compliance with local, state and federal regulations regarding health, air and water pollution. May be destroyed by controlled incineration. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH/MSHA Approved organic vapor respirator or supplied air respiratory equipment as required. Eye Protection Safety glasses Gloves Neoprene-type gloves Other Clothing and Equipment: Impervious protective clothing and chemical-resistant safety shoes to minimize contact. Emergency shower and eye wash facility should be provided. Ventilation: X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Maintain ambient temperatures. Avoid prolonged/repeated breathing of vapors, mists, fumes. Keep container tightly closed. Do not store near heat, flame, strong oxidants. Maintain adequate ventilation. 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 168 A Icematic SW 32 I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Icematic SW 32 Product Number: 4314 Synonyms: Polyol Ester Lubricant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 131459-39-7 99% Not listed Antioxidant Additive Package n/a without non- <1% Not listed disclosure agreement VOC Content: 0.01lbs./gallon (1.0 %) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Negligible Vapor Density (Air=1) 60-90° F: >5 Evaporation Rate (ether=1) Negligible VOC Content (% by wt.): Negligible Solubility in H₂O: Not Soluble in Water pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: >500°F Appearance: Clear, colorless liquid Specific Gravity H₂O=1 @25° C: 0.98 Odor: Slight petroleum odor IV - FIRE AND EXPLOSION Flash Point F >400°F (COC) Flammable Limits ND Extinguishing Media: Dry chemical,CO₂ Foam Special Fire Fighting Procedures: Water or foam may cause frothing. Use water as fog or spray to cool containers exposed to fire. Water spray may be used to flush spills away from exposure. For fires in enclosed areas, wear self-contained breathing apparatus. Prevent runoff from fire control or dilution from entering streams or drinking water supply. Unusual Fire and Explosion Hazards: Empty containers may contain product residue or vapors which can ignite explosively; do not cut, weld or drill on or near empty or full containers. V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable - avoid oxidizing agents, heat, open flame. Incompatibility: None Hazardous Decomposition Products: Smoke, fumes, CO, CO₂ Conditions Contributing to Hazardous Polymerizations: Will not occur VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Can cause gastro-intestinal irritation, nausea, vomiting, diarrhea and abdominal pain. EYES & SKIN: May cause mild irritation. Prolonged or repeated skin contact may cause skin irritation, defatting. INHALATION: May cause nasal/respiratory irritation, dizziness. B. SUBCHRONIC, CHRONIC, OTHER: N/A C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 169 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from area of exposure to fresh air immediately. Administer oxygen if deemed necessary. If breathing has stopped, administer CPR. Keep person warm and at rest. Treat symptomatically and supportively. Get medical attention immediately. EYES: Flush eyes with large amounts of clean water for at least 15 minutes. Contact a physician if irritation persists. SKIN: Remove contaminated clothing and wash before reuse. Wash thoroughly with soap and water. Get medical attention if irritation persists. Use skin cream for defatted areas. INGESTION: Aspiration hazard. Do not induce vomiting or give anything mouth because this material can enter the lungs and cause severe damage. Do not leave victim unattended. If vomiting occurs, or if comatose or lethargic, place on the left side with the head down. Seek immediate medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management Large Spills wear appropriate protective clothing. Stop source of leak if possible. Dike, contain spill and recover free liquid. Prevent entry into waterways. Soak up residue with an inert material such as clay, sand or other suitable materials; store and dispose of properly. Flush area with water. Where feasible and appropriate, remove contaminated soil. Small Spills: Neutralize and/or soak up spill with inert absorbent. Store in a closed container and dispose of properly. Waste Disposal Methods: All recovered material should be packaged, labelled, transported, and disposed of or reclaimed in conformance with good engineering practices. Dispose of by method in compliance with local, state and federal regulations regarding health, air and water pollution. May be destroyed by controlled incineration. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH/MSHA Approved organic vapor respirator or supplied air respiratory equipment as required. Eye Protection Safety glasses Gloves Resistant type gloves Other Clothing and Equipment: N/A Ventilation: Provide sufficient mechanical, general and/or local exhaust to maintain exposure below TLV. Greater than 60 cu.ft. per minute is recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Maintain ambient temperatures. Avoid prolonged/repeated breathing of vapors, mists, fumes. Keep container tightly closed. Do not store near heat, flame, strong oxidants. Maintain adequate ventilation. 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 170 A Icematic SW 32C I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Icematic SW 32C Product Number: 4314-C Synonyms: Polyol Ester Lubricant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Contains no other ingredients now known to be hazardous as defined by 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 172 A Icematic SW 68 I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Icematic SW 68 Product Number: 4316 Synonyms: Polyol Ester Lubricant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 131459-39-7 99% Not listed Antioxidant Additive Package n/a without non- <1% Not listed disclosure agreement VOC Content: 0.01lbs./gallon (1.0 %) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Negligible Vapor Density (Air=1) 60-90° F: >5 Evaporation Rate (ether=1) Negligible VOC Content (% by wt.): Negligible Solubility in H₂O: <0.1% pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: N/A Appearance: Clear, colorless liquid Specific Gravity H₂O=1 @25° C: 0.97 Odor: Slight petroleum odor IV - FIRE AND EXPLOSION Flash Point F >464°F (COC) Flammable Limits ND Extinguishing Media: Dry chemical, CO₂Foam Special Fire Fighting Procedures: Water or foam may cause frothing. Use water as fog or spray to cool containers exposed to fire. Water spray may be used to flush spills away from exposure. For fires in enclosed areas, wear self-contained breathing apparatus. Prevent runoff from fire control or dilution from entering streams or drinking water supply. Unusual Fire and Explosion Hazards: Empty containers may contain product residue or vapors which can ignite explosively; do not cut, weld or drill on or near empty or full containers. V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable under normal conditions - avoid oxidizing agents, heat, open flame. Incompatibility: Strong oxidizers, heat and sources of ignition. Hazardous Decomposition Products: Smoke, fumes, CO, CO₂ Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Can cause gastro-intestinal irritation, nausea, vomiting & diarrhea. EYES & SKIN: May cause mild irritation. Prolonged or repeated skin contact may cause skin irritation, defatting. INHALATION: May cause nasal/respiratory irritation, dizziness. B. SUBCHRONIC, CHRONIC, OTHER: N/A C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 173 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from area of exposure to fresh air immediately. Administer oxygen if deemed necessary. If breathing has stopped, administer CPR. Keep person warm and at rest. Treat symptomatically and supportively. Get medical attention immediately. EYES: Flush eyes with large amounts of clean water for at least 15 minutes. Contact a physician if irritation persists. SKIN: Remove contaminated clothing and wash before reuse. Wash thoroughly with soap and water. Get medical attention if irritation persists. Use skin cream for defatted areas. INGESTION: Aspiration hazard. Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe damage. Do not leave victim unattended. If vomiting occurs, or if comatose or lethargic, place on the left side with the head down. Seek immediate medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management Large Spills wear appropriate protective clothing. Stop source of leak if possible. Dike, contain spill and recover free liquid. Prevent entry into waterways. Soak up residue with an inert material such as clay, sand or other suitable materials; store and dispose of properly. Flush area with water. Where feasible and appropriate, remove contaminated soil. Small Spills: Neutralize and/or soak up spill with inert absorbent. Store in a closed container and dispose of properly. Waste Disposal Methods: All recovered material should be packaged, labelled, transported, and disposed of or reclaimed in conformance with good engineering practices. Dispose of by method in compliance with local, state and federal regulations regarding health, air and water pollution. May be destroyed by controlled incineration. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH/MSHA Approved organic vapor respirator or supplied air respiratory equipment as required. Eye Protection Safety glasses Gloves Neoprene type gloves Other Clothing and Equipment: N/A Ventilation: Provide sufficient mechanical, general and/or local exhaust to maintain exposure below TLV. Greater than 60 cu ft/min. recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Maintain ambient temperatures. Avoid prolonged/repeated breathing of vapors, mists, fumes. Keep container tightly closed. Do not store near heat, flame, strong oxidants. Maintain adequate ventilation. 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 174 A Icematic SW 68C I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Icematic SW 68C Product Number: 4316-04 Synonyms: Refrigeration Oil II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Polyol Ester 131459-39-7 99% Not listed 99% Antioxidant Additive Package n/a without non- <1% Not listed <1% disclosure agreement Contains no SARA 313 listed chemicals VOC Content: 0.01lbs./gallon (1.0 %) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: Negligible Vapor Density (Air=1) 60-90° F: >5 Evaporation Rate: Negligible VOC Content (% by wt.): Negligible Solubility in H₂O: Not soluble pH @ Solution: N/A Freezing Point °F: Not determined pH as Distributed: N/A Boiling Point °F: > 500°F Appearance: Clear colorless liquid Specific Gravity H₂O=1 @25° C: 0.9800 Odor: Slight petroleum IV - FIRE AND EXPLOSION Flash Point F >400°F (COC) Flammable Limits N/D N/D Extinguishing Media: Dry chemical, CO₂ Foam Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire-exposed container cool. Water spray may be used to flush spills away from exposure. Firefighters must use self-contained breathing apparatus. Prevent run-off from fire control from entering streams or drinking water supply. Unusual Fire and Explosion Hazards: Empty containers may contain product residue or vapors which can ignite explosively; do not cut, weld or drill on or near empty or full containers. V - REACTIVITY DATA Stability - Conditions to avoid: Product is stable under normal conditions - avoid oxidizing agents, heat, open flame. Incompatibility: None Hazardous Decomposition Products: Smoke, fumes, CO, CO₂ Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Can cause gastrointestinal irritation, nausea, vomiting & diarrhea. EYES & SKIN: May cause mild irritation. Prolonged or repeated skin contact may cause skin irritation, defatting. INHALATION: May cause nasal/respiratory irritation, dizziness. B. SUBCHRONIC, CHRONIC, OTHER: None C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: See acute effects above. 175 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from area of exposure to fresh air immediately. Administer oxygen if deemed necessary. If breathing has stopped, administer CPR; keep person warm and at rest. Contact physician immediately. EYES: Flush eyes with large amounts of clean water for at least 15 minutes. Contact a physician if irritation persists. SKIN: Remove contaminated clothing. Wipe material from skin. Wash thoroughly with soap and water. If irritation persists, get medical attention. Wash clothing before reuse. Use skin cream for defatted areas. INGESTION: Aspiration hazard. Do not induce vomiting or give anything by mouth. Do not leave victim unattended. If vomiting occurs or if comatose or lethargic, place on the left side with head down Consult a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Do not permit product to enter streams, sewers or other waterways. Dike spill and eliminate leak. Absorb with inert material and store in closed containers until disposal. Waste Disposal Methods: All recovered material should be packaged, labelled, transported, and disposed of or reclaimed in conformance with good engineering practices. Dispose of by method in compliance with local, state and federal regulations regarding health, air and water pollution. May be destroyed by controlled incineration. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH/MSHA Approved organic vapor respirator or supplied air respiratory equipment as required. Eye Protection Safety glasses Gloves Neoprene type gloves Other Clothing and Equipment: Impervious protective clothing and chemical-resistant safety shoes to minimize contact. Emergency shower and eye wash facility should be provided. Ventilation: Provide sufficient mechanical, general and/or local exhaust to maintain exposure below TLV. Greater than 60 cu ft/min. recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Maintain ambient temperatures. Avoid prolonged/repeated breathing of vapors, mists, fumes. Keep container tightly closed. Do not store near heat, flame, strong oxidants. Maintain adequate ventilation. 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 176 A Imperial Scale Remover I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Imperial Scale Remover Product Number: 4360-84 Synonyms: Sulfamic Acid II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sulfamic Acid (ORAL LD50 - Rat 5329-14-6 97 N/A 1600mg/kg) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate (ether=1) N/A VOC Content (% by wt.): Solubility in H₂O: Appreciable pH @ 1% Solution: 1.25 Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: N/AV Appearance: Purple flowing granules Specific Gravity H₂O=1 @25° C: N/A Odor: Pungent odor IV - FIRE AND EXPLOSION Flash Point F N/A Flammable Limits N/A Extinguishing Media: Product is non flammable. In the event of fire, use water, chemical foam, dry chemical, CO₂. Special Fire Fighting Procedures: Water solutions of this compound result in strong acids. Unusual Fire and Explosion Hazards: May release SO2, SO3 or NH3 gases if involved in a fire. V - REACTIVITY DATA Stability - Conditions to avoid: If heated releases SO2, SO3 or NH3 gases. Incompatibility: Alkali, chlorine sources (bleaches). Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Causes burns to both eyes and skin. INGESTION Harmful if swallowed. Will burn mouth, throat and stomach. INHALATION: Irritates nose, throat and skin. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Call a physician. EYES: Flush eyes with plenty of water for at least 15 minutes. Call a physician. SKIN: Flush skin with plenty of water for at least 15 minutes. If irritation develops, call a physician. INGESTION: DO NOT induce vomiting. Give large quantities of water. Give at least 1 ounce of milk of magnesia or aluminum hydroxide gel in equal amounts of water. If not available, the whites of 2 - 3 eggs may be used. Never give anything by mouth to an unconscious person. Call a physician. 177 VIII - SPILL OR LEAK PROCEDURE Spill Management: Cautiously cover spill with bicarbonate of soda or soda ash - slaked lime mixture(50 - 50). Mix and flush to discharge using plenty of water in accordance with local, state and federal laws. Waste Disposal Methods: Cautiously stir product waste in large volume of soda ash - slaked lime solution. Flush neutralized solution and discharge in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH - approved filter respirator recommended in case of dust. Eye Protection Goggles or face shield Gloves Rubber gloves Other Clothing and Equipment: Wash protective clothing. Ventilation: Local and mechanical exhaust is recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not get in eyes, on skin or clothing. Keep from contact with chlorine bleaches. Wash thoroughly after handling. Keep container dry. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 1 Reactivity..................... : 1 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 178 A IMS-ll Ice Machine Sanitizer I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: IMS-ll Ice Machine Sanitizer Product Number: 4211 Synonyms: Industrial Sanitizer EPA Reg No.1839-50-65516 EPA Est. No. 72026-IL-01 II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Silicic Acid-Sodium Salt 1344-09-8 1.8 2.0mg/m3 N/A Alkyl Dimethyl Benzyl Ammonium 68391-01-5 0.8 N/A Chloride 68956-79-6 0.8 N/A Alkyl Dimethyl Ethyl Benzyl Ammonium Chloride All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: (ether=1) N/A VOC Content (% by wt.): <5% Solubility in H₂O: Complete pH @ 100% Solution: 13.0 Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: Like Water. Appearance: Clear colorless liquid Specific Gravity H₂O=1 @25° C: 1.08 Odor: Slight chemical odor. IV - FIRE AND EXPLOSION Flash Point F Non flammable Flammable Limits N/A Extinguishing Media: Product is non flammable or combustible. Use media appropriate for the primary source of fire. Special Fire Fighting Procedures: Use caution when fighting any fire involving chemicals. Wear self-contained breathing apparatus in the event of a fire. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: Stable. Incompatibility: Strong acids or oxidizers. Do not mix with chlorinated detergents or sanitizers. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES This product may result in transient irritation of reddening on contact with eye. SKIN: (Primary Route of Exposure) Product may result in irritation upon contact with skin. INHALATION: Inhalation of concentrated mist or vapor may result in irritation of the nose, throat and lungs. INGESTION: Ingestion may cause nausea, vomiting ,diarrhea and mucousal irritation. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 179 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Start artificial respiration if necessary. Oxygen may be administered. Call a physician. EYES: Flush eyes with water for at least 15 minutes and call a physician immediately. SKIN: Wash affected areas with large amounts of soap and water. If irritation persists call a physician. INGESTION: Do not induce vomiting. Dilute by drinking water. Call a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Safety stop spill at source. Contain spill by diking with soil or other inert material. Mop, pump or absorb with material and reclaim into sound containers for proper disposal. Waste Disposal Methods: Dispose of in an approved waste facility according to Federal, State and local regulations. See label for specifics. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required. Eye Protection Chemical splash goggles. Gloves Rubber gloves Other Clothing and Equipment: Rubber apron if splashing potential exists. Ventilation: Local and mechanical exhaust is recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: DANGER! Do not expose product to excessive heat or near freezing temperatures. Handle all containers carefully. Triple rinse all empty containers to remove all residual product. Wash thoroughly after handling. Follow label directions as to storage and disposal. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 180 A Insulation Cords & Slugs I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Insulation Cords & Slugs Product Number: 4216 Synonyms: Thumbing-Grade Insulation Material. II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL None All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate (ether=1) N/A VOC Content (% by wt.): N/A Solubility in H₂O: N/A pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: N/A Appearance: Soft, pliable, pressure sensitive material. Specific Gravity H₂O=1 @25° C: 1.30 +/- .05 g/cc Odor: IV - FIRE AND EXPLOSION Flash Point F >450°F Flammable Limits N/A Extinguishing Media: Foam, CO₂, Dry Chemicals. Special Fire Fighting Procedures: Water unsuited for rubber fires. Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: Stable; High temperature yields decomposition to isobutene. Incompatibility: Oxygen supplying chemicals and contact with acid clays at elevated temperatures. Hazardous Decomposition Products: CO, CO₂, H₂O, and isobutene. Conditions Contributing to Hazardous Polymerizations: May not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION N/A, EYES & SKIN N/A B. SUBCHRONIC, CHRONIC, OTHER: None known. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: Flush with plenty of water. SKIN: Flush with plenty of water. INGESTION: N/A VIII - SPILL OR LEAK PROCEDURE Spill Management: Repackage uncontaminated tape. Dispose of contaminated or unusable tape. Waste Disposal Methods: Bury tape in an approved land fill site. 181 IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: N/A Eye Protection N/A Gloves N/A Other Clothing and Equipment: N/A Ventilation: N/A X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Prevent high temperature exposure. 0 0 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 182 A Kleen-n-Toss I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Kleen-n-Toss Product Number: 4230 Synonyms: Waterless Hand Cleaner Towel II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Adepsine Oil 8052-41-3 N/A 100ppm This product is not known to contain any compound in concentrating requiring reporting under SARA Title III, Section 313 All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg N/A Vapor Density (Air=1) 60-90° F: >1 Evaporation Rate (ether=1) N/A VOC Content (% by wt.): Solubility in H₂O: Dispersible pH @ 100% Solution: 8.25 +/- 0.5 Freezing Point °F: N/A pH as Distributed: Boiling Point °F: 212° Appearance: Opaque white liquid saturated onto towels Specific Gravity H₂O=1 @25° C: 0.97 Odor: Citrus (orange) IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits No data Extinguishing Media: CO₂. dry chemical, foam, fog or water spray. Special Fire Fighting Procedures: Keep containers cool and vapors down with water spray. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: Stable Incompatibility: Strong oxidizers and acids Hazardous Decomposition Products: CO, CO₂, H2S, sulfur dioxide, smoke, soot Conditions Contributing to Hazardous Polymerizations: Will not occur VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION May cause irritation of throat or stomach, nausea, vomiting and diarrhea if swallowed. EYES: May cause irritation. B. SUBCHRONIC, CHRONIC, OTHER: Pre-existing skin conditions may be aggravated. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 183 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: & SKIN: Flush with water for 15 minutes, lifting eyelids. See a physician immediately. INGESTION: Not a likely exposure route. If a large quantity of liquid is swallowed, do not induce vomiting. Call a physician or poison center immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management Caution slip hazard. Wipe up small releases with a dry absorbent. For large releases, prevent material from entering sewers or drains. Waste Disposal Methods: Consult local, state or federal regulations. Discard empty container. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: None Eye Protection None Gloves None Other Clothing and Equipment: Not usually necessary. Ventilation: Nothing special usually needed. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: For external use only. Do not allow to contact eyes. Do not smoke while using - not for use around mouth or eyes. 1 1 Fire Hazard................: 1 Fire Hazard .................. : 1 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 184 A Liquid Ice Machine Cleaner I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Liquid Ice Machine Cleaner Product Number: 4207 Synonyms: Phosphoric Acid II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # Phosphoric Acid* (ORAL LD50 7664-38-2 75 1mg/m3 1530 mg/kg) (DERMAL LD50 2740mg/kg) *STEL=3mg/m3 # Ingredient subject to reporting under section 313 of Title III (SARA) and 40 CFR 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: 0.03 Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate: (ether=1) N/A VOC Content (% by wt.): 15 - 25 Solubility in H₂O: Complete pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: <1 Boiling Point °F: @500 Appearance: Clear liquid Specific Gravity H₂O=1 @25° C: 1.584 Odor: Odorless IV - FIRE AND EXPLOSION Flash Point F Non flammable Flammable Limits N/A Extinguishing Media: Product is not flammable or combustible. Special Fire Fighting Procedures: Exercise caution when fighting fires involving chemicals. Respiratory protection is essential--wear self-contained breathing apparatus. Unusual Fire and Explosion Hazards: Contact with some metals may form hydrogen gas. Avoid using in confined, unventilated spaces. V - REACTIVITY DATA Stability - Conditions to avoid: Unknown. Incompatibility: Strong caustics, metals and reducing agents. Hazardous Decomposition Products: Phosphoric acid fumes; phosphorus oxide fumes; hydrogen gas. Conditions Contributing to Hazardous Polymerizations: None known. 185 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES Corrosive. Concentrated solutions are extremely irritating to eyes and may produce burns on contact. SKIN: Corrosive to tissues. May result in skin burns. Severely irritating to skin; repeated contact with more dilute solutions may result in dermatitus. INHALATION: Mist, vapors or aerosols are irritating to respiratory tract and high concentrations may produce pulmonary edema and difficulty in breathing. INGESTION: If swallowed may result in abdominal hemorrhage, nausea, vomiting or loss of consciousness. Severe abdominal pain may result from severe burns of stomach and gastrointestinal tract. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical aid. EYES: Immediately flush with plenty of water for at least 15 minutes. Seek medical aid. SKIN: Immediately wash with soap and plenty of water for 15 minutes while removing contaminated clothing. Seek medical aid. INGESTION: DO NOT induce vomiting. Give large quantities of water. Seek medical aid. Never give anything by mouth to an unconscious person. VIII - SPILL OR LEAK PROCEDURE Spill Management: Absorb on vermiculite or other suitable material and place in a container for disposal. Waste Disposal Methods: Dispose of in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: For vapor or mist exposure, use NIOSH-approved respirator. Eye Protection Full face shield or goggles. Gloves Rubber gloves Other Clothing and Equipment: Rubber apron and boots. Ventilation: Local and mechanical exhaust recommended. Use only in well ventilated areas that will maintain air levels below limits established by federal, state and local regulations. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: DANGER! Do not get in eyes, on skin or clothing. Wear chemical splash goggles or face shield, rubber gloves, protective clothing when handling. Harmful if swallowed or inhaled. Avoid breathing vapor or mist. Wash thoroughly after handling. Keep container closed when not in use. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 186 A Liquid Ice Machine Cleaner - Canada I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Liquid Ice Machine Cleaner - Canada Product Number: 4834 Synonyms: Phosphoric Acid II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # Phosphoric Acid* (ORAL LD50 7664-38-2 75 1mg/m3 1530 mg/kg) (DERMAL LD50 2740mg/kg) *STEL=3mg/m3 # Ingredient subject to reporting under section 313 of Title III (SARA) and 40 CFR 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: 0.03 Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate: (ether=1) N/A VOC Content (% by wt.): 15 - 25 Solubility in H₂O: Complete pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: <1 Boiling Point °F: @500 Appearance: Clear liquid Specific Gravity H₂O=1 @25° C: 1.584 Odor: Odorless IV - FIRE AND EXPLOSION Flash Point F Non flammable Flammable Limits N/A Extinguishing Media: Product is not flammable or combustible. Special Fire Fighting Procedures: Exercise caution when fighting fires involving chemicals. Respiratory protection is essential--wear self-contained breathing apparatus. Unusual Fire and Explosion Hazards: Contact with some metals may form hydrogen gas. Avoid using in confined, unventilated spaces. V - REACTIVITY DATA Stability - Conditions to avoid: Unknown. Incompatibility: Strong caustics, metals and reducing agents. Hazardous Decomposition Products: Phosphoric acid fumes; phosphorus oxide fumes; hydrogen gas. Conditions Contributing to Hazardous Polymerizations: None known. 187 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES Corrosive. Concentrated solutions are extremely irritating to eyes and may produce burns on contact. SKIN: Corrosive to tissues. May result in skin burns. Severely irritating to skin; repeated contact with more dilute solutions may result in dermatitus. INHALATION: Mist, vapors or aerosols are irritating to respiratory tract and high concentrations may produce pulmonary edema and difficulty in breathing. INGESTION: If swallowed may result in abdominal hemorrhage, nausea, vomiting or loss of consciousness. Severe abdominal pain may result from severe burns of stomach and gastrointestinal tract. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical aid. EYES: Immediately flush with plenty of water for at least 15 minutes. Seek medical aid. SKIN: Immediately wash with soap and plenty of water for 15 minutes while removing contaminated clothing. Seek medical aid. INGESTION: DO NOT induce vomiting. Give large quantities of water. Seek medical aid. Never give anything by mouth to an unconscious person. VIII - SPILL OR LEAK PROCEDURE Spill Management: Absorb on vermiculite or other suitable material and place in a container for disposal. Waste Disposal Methods: Dispose of in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: For vapor or mist exposure, use NIOSH-approved respirator. Eye Protection Full face shield or goggles. Gloves Rubber gloves Other Clothing and Equipment: Rubber apron and boots. Ventilation: Local and mechanical exhaust recommended. Use only in well ventilated areas that will maintain air levels below limits established by federal, state and local regulations. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: DANGER! Do not get in eyes, on skin or clothing. Wear chemical splash goggles or face shield, rubber gloves, protective clothing when handling. Harmful if swallowed or inhaled. Avoid breathing vapor or mist. Wash thoroughly after handling. Keep container closed when not in use. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 188 A Liquid Scale Dissolver I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Liquid Scale Dissolver Product Number: 4330 Synonyms: Acidic Solution II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Hydrochloric Acid (ORAL LD50 - 7647-01-0 26 5ppm (ceiling) 5ppm Rabbit 900mg/kg) 7732-18-5 74 Water All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate (ether=1) Not Applicable VOC Content (% by wt.): 100 Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: <1 Boiling Point °F: >212° Appearance: Clear orange-color liquid. Specific Gravity H₂O=1 @25° C: 1.095 - 1.125 Odor: Sharp odor. IV - FIRE AND EXPLOSION Flash Point F Non flammable Flammable Limits N/A Extinguishing Media: Product is non flammable. Use water spray to cool fire. Special Fire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH - approved self- contained breathing apparatus. Unusual Fire and Explosion Hazards NOTE This product can react with metals to release hydrogen gas Firemen may need to protect against this. V - REACTIVITY DATA Stability - Conditions to avoid: None known. Incompatibility: Bases, strong oxidizers and metals. Hazardous Decomposition Products: Contact with metals may generate Hydrogen, which can be explosive. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Corrosive to tissues. Causes burns to eyes and skin INGESTION Harmful if swallowed. Burns to mouth, throat and stomach are likely. INHALATION Mists may cause coughing and irritation to respiratory tract. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 189 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air and contact a physician. EYES: & SKIN: In case of contact, immediately flush eyes and skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Wash clothing before reuse. INGESTION: If swallowed, DO NOT induce vomiting. Give large quantities of water. Call a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area, contain as much spilled material as possible. Cover with sodium bicarbonate or soda ash and flush with water. Waste Disposal Methods: Dispose of in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: A NIOSH - approved respirator for acids is recommended. Eye Protection Full face shield or goggles. Gloves Rubber gloves Other Clothing and Equipment: Protective clothing. Ventilation: Local and mechanical exhaust is recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not get in eyes, on skin or clothing. Avoid breathing vapor or mist. Keep container closed. Wash thoroughly after handling. Keep from contact with chlorine bleaches. 3 3 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 1 Reactivity..................... : 1 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 190 A Liquid Scale Dissolver - Canada I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Liquid Scale Dissolver - Canada Product Number: 4845 Synonyms: Acidic Solution II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Hydrochloric Acid (ORAL LD50 - 7647-01-0 26 5ppm (ceiling) 5ppm Rabbit 900mg/kg) 7732-18-5 74 Water All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate (ether=1) Not Applicable VOC Content (% by wt.): 100 Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: <1 Boiling Point °F: >212° Appearance: Clear orange-color liquid. Specific Gravity H₂O=1 @25° C: 1.095 - 1.125 Odor: Sharp odor. IV - FIRE AND EXPLOSION Flash Point F Non flammable Flammable Limits N/A Extinguishing Media: Product is non flammable. Use water spray to cool fire. Special Fire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH - approved self- contained breathing apparatus. Unusual Fire and Explosion Hazards NOTE This product can react with metals to release hydrogen gas Firemen may need to protect against this. V - REACTIVITY DATA Stability - Conditions to avoid: None known. Incompatibility: Bases, strong oxidizers and metals. Hazardous Decomposition Products: Contact with metals may generate Hydrogen, which can be explosive. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Corrosive to tissues. Causes burns to eyes and skin INGESTION Harmful if swallowed. Burns to mouth, throat and stomach are likely. INHALATION Mists may cause coughing and irritation to respiratory tract. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 191 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air and contact a physician. EYES: & SKIN: In case of contact, immediately flush eyes and skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Wash clothing before reuse. INGESTION: If swallowed, DO NOT induce vomiting. Give large quantities of water. Call a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area, contain as much spilled material as possible. Cover with sodium bicarbonate or soda ash and flush with water. Waste Disposal Methods: Dispose of in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: A NIOSH - approved respirator for acids is recommended. Eye Protection Full face shield or goggles. Gloves Rubber gloves Other Clothing and Equipment: Protective clothing. Ventilation: Local and mechanical exhaust is recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not get in eyes, on skin or clothing. Avoid breathing vapor or mist. Keep container closed. Wash thoroughly after handling. Keep from contact with chlorine bleaches. 3 3 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 1 Reactivity..................... : 1 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 192 A Micromet Crystals I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Micromet Crystals Product Number: 4243 Synonyms: Polyphosphate Glass II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL According to the 0 0 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 194 A Micromet Plates I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Micromet Plates Product Number: 4275 Synonyms: Polyphosphate Glass II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL According to the 0 0 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 196 A Nickel-Safe Ice Machine Cleaner I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Nickel-Safe Ice Machine Cleaner Product Number: 4287 Synonyms: Descaler for nickel-plated ice machines II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL phosphoric acid 7664-38-2 <30 1mg/m3 citric acid 77-92-9 <5 ne All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: (ether=1) N/A VOC Content (% by wt.): ~30 Solubility in H₂O: Complete pH @ 1% Solution: ~2.0 Freezing Point °F: 0 pH as Distributed: < 1 Boiling Point °F: >200°F Appearance: Green liquid Specific Gravity H₂O=1 @25° C: 1.188 Odor: Mild chemical odor IV - FIRE AND EXPLOSION Flash Point F None Flammable Limits N/A Extinguishing Media: Product is non flammable or combustible. Special Fire Fighting Procedures: None known. Unusual Fire and Explosion Hazards: N/A V - REACTIVITY DATA Stability - Conditions to avoid: Stable, none known. Incompatibility: Strong bases, ammonia, chlorine bleach. Hazardous Decomposition Products: Forced ignition of dried residues may produce oxides of phosphorus. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES Severely irritating to eyes on contact. May cause burns. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 198 A Nickel-Safe Ice Machine Cleaner - Canada I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Nickel-Safe Ice Machine Cleaner - Canada Product Number: 4841 Synonyms: Descaler for nickel-plated ice machines II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL phosphoric acid 7664-38-2 <30 1mg/m3 citric acid 77-92-9 <5 ne All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: (ether=1) N/A VOC Content (% by wt.): ~30 Solubility in H₂O: Complete pH @ 1% Solution: ~2.0 Freezing Point °F: 0 pH as Distributed: < 1 Boiling Point °F: >200°F Appearance: Green liquid Specific Gravity H₂O=1 @25° C: 1.188 Odor: Mild chemical odor IV - FIRE AND EXPLOSION Flash Point F None Flammable Limits N/A Extinguishing Media: Product is non flammable or combustible. Special Fire Fighting Procedures: None known. Unusual Fire and Explosion Hazards: N/A V - REACTIVITY DATA Stability - Conditions to avoid: Stable, none known. Incompatibility: Strong bases, ammonia, chlorine bleach. Hazardous Decomposition Products: Forced ignition of dried residues may produce oxides of phosphorus. Conditions Contributing to Hazardous Polymerizations: Will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES Severely irritating to eyes on contact. May cause burns. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 200 A No. 340 Liquid Scale Inhibitor I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: No. 340 Liquid Scale Inhibitor Product Number: 4340 Synonyms: Phosphonate Glycol Mixture II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL # Ethylene Glycol (ORAL LD50 - 107-21-1 13 50ppm (ceiling) Rat 8540mg/kg) # Ingredient subject to reporting under Section 313 of Title III (SARA) and 40 CFR 372. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Like water Vapor Density (Air=1) 60-90° F: Like H₂O Evaporation Rate (ether=1) N/A VOC Content (% by wt.): @70 Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: 8.5 Boiling Point °F: >212° Appearance: Clear, colorless liquid Specific Gravity H₂O=1 @25° C: 1.25 Odor: Chemical odor IV - FIRE AND EXPLOSION Flash Point F Non flammable Flammable Limits N/A Extinguishing Media: Product is non flammable. Special Fire Fighting Procedures: Always use suitable equipment for fighting chemical fires. A self-contained breathing apparatus and impervious clothing. Unusual Fire and Explosion Hazards: None known. V - REACTIVITY DATA Stability - Conditions to avoid: None known. Incompatibility: Strong oxidizers. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Causes irritation to both eyes and skin. INGESTION Harmful if swallowed. Large quantities will cause upset to stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 201 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: & SKIN: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Flush skin with water. INGESTION: If swallowed, induce vomiting immediately by giving two glasses of water and sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician. VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area, contain as much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable material and place in a sealed metal container for disposal. Waste Disposal Methods: Landfill or mix with a flammable solvent and incinerate in accordance with local, state and federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required unless the TLV for ethylene glycol is exceeded. Eye Protection Goggles or safety glasses. Gloves Rubber gloves Other Clothing and Equipment: Not required. Ventilation: Mechanical exhaust is recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. Keep container closed. Wash thoroughly after handling. Use with adequate ventilation. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 202 A No. 85 Algaecide I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: No. 85 Algaecide Product Number: 4108 Synonyms: Microbiocide EPA Regis. No. 1448-233-65516 EPA Est. No. 1459-IL-01 II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Poly{ oxyethylene (dimethylimino) 31075-24-8 30 N/A ethylene (dimethyliminio) ethylene dichloride} ORAL LD50 Rat 3690 mg/kg All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: like H₂O Evaporation Rate: (ether=1) N/AV VOC Content (% by wt.): 70 Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/AV pH as Distributed: 6.5 Boiling Point °F: above 212 Appearance: Clear, slightly viscous liquid Specific Gravity H₂O=1 @25° C: 1.075 Odor: Typical IV - FIRE AND EXPLOSION Flash Point F >275°F (TOC) Flammable Limits N/A Extinguishing Media: Foam, CO₂, dry chemical. Special Fire Fighting Procedures: Exercise caution when fighting any chemical fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: None. Incompatibility: Strong bases, strong acids. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYES & SKIN Testing of the active ingredient in rabbits produced only slight skin irritation and minimal trasient occular irritation. INGESTION: Harmful if swallowed. May cause upset to stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 203 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with cool water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush with cool water for at least 15 minutes. If irritation develops, call a physician. INGESTION: If swallowed, drink promptly a large quantity of milk, egg whites, gelatin solution, or if these are not available, drink large quantities of water. Avoid alcohol. Call a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Dike area to contain as much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable material and place in sealed container for disposal. Waste Disposal Methods: Keep container closed when not in use. Do not contaminate water, food or feed by storage, disposal or cleaning of equipment. This container must be triple rinsed (or equilvalent) and offered for recycling, reconditioning or disposal in an approved landfill. Rinsate that cannot be used or reprocessed should be disposed of in a landfill for pesticides. Open dumping is prohibited. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not required Eye Protection Eye goggles or safety glasses Gloves Rubber gloves Other Clothing and Equipment: None. Ventilation: Normal. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: This pesticide is toxic to fish. Keep out of lakes, streams or ponds. Permits may be required for discharges containing this pesticide into lakes, streams ponds or public water. For guidance, contact the regional office of the EPA. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 204 A No. 90 Algaecide I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: No. 90 Algaecide Product Number: 4109 Synonyms: Cooling Water Microbiocide EPA Regis. No. 5185-420-65516 EPA Est. No. 5185-MI-1 II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL 1-Bromo-3-Chloro-5, 5- 16079-88-2 96 N/A Dimethylhydantoin ORAL LD50 Rat>200 mg/kg All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Solid Vapor Density (Air=1) 60-90° F: Solid Evaporation Rate: (ether=1) N/A VOC Content (% by wt.): Solid Solubility in H₂O: 0.15g/100g in H2O pH @ Solution: Unknown Freezing Point °F: N/AV pH as Distributed: N/A Boiling Point °F: Solid Appearance: White compressed tablets Specific Gravity H₂O=1 @25° C: Solid Odor: Strong halogen odor IV - FIRE AND EXPLOSION Flash Point F Non flammable Flammable Limits N/A Extinguishing Media: Water. Special Fire Fighting Procedures: If involved in a fire, hydrogen bromide or bromine may be released. Exercise caution when fighting any chemical fire. Respiratory protection is essential. In large fires, product may smolder for prolonged periods emitting a dense black smoke. Unusual Fire and Explosion Hazards: Product is a strong oxidizing agent. Contamination with moisture, organic matter or other chemicals may start a chemical reaction with generation of heat, hazardous gases and possible fire and explosion. In case of contamination or decomposition do not reseal container. If possible, isolate container in open air or well ventilated area. If necessary, flood with large volume of water. V - REACTIVITY DATA Stability - Conditions to avoid: Do not mix with anything but water. Incompatibility: Organics and strong reducing agents. Hazardous Decomposition Products: Fires may release hydrogen bromide or bromine. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYE & SKIN Corrosive to tissues. Direct contact causes severe eye irritation. Can cause irreversible eye damage. Remove and wash all contaminated clothing before reuse. INHALATION Irritating to nose and throat. INGESTION Poisonous, may be fatal if swallowed B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 205 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Contact a physician, if irritation persists. EYES: In case of contact, flush eyes copiously with water for at least 15 minutes and get medical attention. SKIN: After handling, wash hands thoroughly. INGESTION: If swallowed, drink raw egg whites, milk or mucilage, follow with emetic (tablespoon of mustard in glass of warm water). VIII - SPILL OR LEAK PROCEDURE Spill Management: Dispose of in accordance with federal, state and local regulations. Sweep up spilled material and repackage. Wash area of spill with large amounts of water. Waste Disposal Methods PESTICIDE 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 2 Reactivity..................... : 2 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 206 A Nu-Blast I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Nu-Blast Product Number: 4290 Synonyms: Aerosol cleaner/degreaser II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Trichloroethylene* 79-01-6 >50 50 ppm Carbon Dioxide 124-38-9 > 5 5000 ppm *This is a SARA III listed ingredient. WARNING: This product contains a chemical or chemicals known to the State of Califonia to cause cancer. All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: 85-100psig @70°F Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate: (n-butyl acetate=1) = 2.6 VOC Content (% by wt.): 100 Solubility in H₂O: Insoluble pH @ N/A Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: N/A Appearance: Clear, colorless spray Specific Gravity H₂O=1 @25° C: 1.45 Odor: lemon-scented solvent IV - FIRE AND EXPLOSION Flash Point F None Flammable Limits None Extinguishing Media: Foam, dry chemical,carbon dioxide Special Fire Fighting Procedures: Self-contained breathing apparatus Unusual Fire and Explosion Hazards: Keep at room temperature. Do not expose to temperatures above 130°F V - REACTIVITY DATA Stability - Conditions to avoid: Stable; open flames, welding arcs, heat Incompatibility: Reactive metals, magnesium, strong oxidizing agents. Product may react with aluminum if immersed in liquid concentrate trichloroethylene for extended periods. Hazardous Decomposition Products: CO, CO₂, HCL, small amounts of phosgene and chlorine Conditions Contributing to Hazardous Polymerizations: Will not occur VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Possible chemical pneumonitis if aspirated into lungs, nausea. INHALATION: Excessive inhalation of vapor can be harmful and may cause headache, dizziness, asphyxia, anesthetic effects and possible unconsciousness. EYE CONTACT Irritation. SKIN CONTACT Irritation due to defatting of skin B. SUBCHRONIC, CHRONIC, OTHER: (Effects due to excessive exposure to the raw materials of this mixture) May cause liver abnormalities, kidney, spleen, lung, or brain damage, cardiac abnormalities. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 207 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove person to fresh air. Resuscitate if necessary. GET MEDICAL ATTENTION. EYES: Flush with water for at least 15 minutes. If irritated, seek medical attention. SKIN: Wash with soap and water. If irritated, seek medical attention. INGESTION: Call physician immediately. Do not induce vomiting. Drink two large glasses of water. VIII - SPILL OR LEAK PROCEDURE Spill Management: Absorb with suitable medium. incinerate or landfill according to local, state or Federal regulations. Allow to evaporate if small spill. DO NOT FLUSH TO SEWER. Waste Disposal Methods: Aerosols can when vented to atmospheric pressure through normal use, pose no disposal hazard. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: If vapor concentration exceeds TLV, use respirator approved by NIOSH/MSHA for organic matter Eye Protection Safety glasses Gloves Neoprene Other Clothing and Equipment: None Ventilation: Provide local exhaust ventilation in volume and pattern to keep TLV of all hazardous ingredients in section II below acceptance limit. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not store above 130°F. Do not puncture or incinerate. 2 2 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 208 A Nu-Brite I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Nu-Brite Product Number: 4291 Synonyms: Alkaline Coil Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Hydroxide (Caustic Soda) 1310-73-2 >20 2mg/M3 Ceiling VOC Content: 2.8% All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Not Determined Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate: (ether=1) Same as H₂O VOC Content (% by wt.): N/A Solubility in H₂O: Complete pH @ 10% Solution: 13.2 Freezing Point °F: N/A pH as Distributed: 14.0 Boiling Point °F: 212°F Appearance: Clear, colored Liquid Specific Gravity H₂O=1 @25° C: 1.252 +/- 0.005 Odor: No Distict Odor IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits N/A Extinguishing Media Water spray (Fog) Dry chemical; CO₂; Foam Special Fire Fighting Procedures: Do not enter confined fire-spaces without protective clothing and self- contained air supply. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: Stable Incompatibility: Strong acids/oxidizers. Do not mix with chlorinated detergents (bleach) Hazardous Decomposition Products: Burning may produce carbon monoxide and/or carbon dioxide. Conditions Contributing to Hazardous Polymerizations: N/A VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYE, SKIN, ORAL Corrosive material. Will cause burns of skin and eyes with prolonged contact. Eye damage likely if contact is prolonged. Generated mists may be seriously irritating and cause damage to respiratory tract if swallowed. Harmful or fatal if swallowed. May cause severe burns of mucous membranes, stomach, nausea, vomiting - possible internal damage. B. SUBCHRONIC, CHRONIC, OTHER: Chronic local effect may consist of multiple areas of superficial destruction of the skin or of primary irritant dermatitis. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 209 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Start artificial respiration if necessary. Oxygen may be administered. Call a physician. EYES: & SKIN Flush eyes with water for at least 15 minutes and call a physician immediately. Skin Wash affected area with large amounts of soap and water. If irritation persists call physician. INGESTION: Do not induce vomiting. Dilute by drinking water. Call a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Safely stop spill at source. Contain spill by diking with soil or other inert material and CAREFULLY neutralize with dilute acid. Mop, pump or absorb with inert material and reclaim into sound containers for proper disposal. Waste Disposal Methods: Dispose of in an approved waste facility according to Federal, State and local regulations. Keep non-neutralized material out of sewers, storm drains, surface water and soil. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: NIOSH approved respirator where mists or sprays may be generated. (Caustic mist cartridge type) Eye Protection Chemical goggles, face shield Gloves Rubber gloves Other Clothing and Equipment: Protective clothing to minimize contact (boots, apron, faceshield) Ventilation: Product is intended for outdoor use. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Corrosive Material - Handle All Containers Carefully. Wash thoroughly after handling. Keep containers closed when not in use. Avoid contact with leather or wool. 3 3 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 210 A Nu-Foam I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Nu-Foam Product Number: 4293 Synonyms: Insulating Sealant II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Methylene bisphenyl isocyanate** 101-68-8 3-6 .005ppm 0.02 ppm Polymethylene polyphenyl 9016-87-9 41-44 NE* isocyanate 13674-84-5 10-12 NE* Chlorinated Phosphate 115-10-6 1-3 NE* Dimethylether 74-98-6 3-6 1000 ppm Propane 75-28-5 7-6 NE* Isobutane Mixture 22-33 NE* Polyether Polyol * Not established ** This compound is a toxic chemical subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40 CFR 372) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: 82.0 psig @ 70°F Vapor Density (Air=1) 60-90° F: Heavier than air Evaporation Rate: NE* VOC Content (% by wt.): NE* Solubility in H₂O: N/A pH @ Solution: NE* Freezing Point °F: NE* pH as Distributed: NE* Boiling Point °F: -43.7°F (-42°C) Appearance: Gel under pressure. Specific Gravity H₂O=1 @25° C: 1.01 Odor: Hydrocarbon odor. IV - FIRE AND EXPLOSION Flash Point F Estimated -156°F Flammable Limits 1.8% Lower 10% Upper Extinguishing Media: Water fog; foam; CO₂; dry chemical. Special Fire Fighting Procedures: Wear full self-contained breathing apparatus and full protective clothing. Unusual Fire and Explosion Hazards: Avoid storage temperatures above 120°F to prevent can explosions. Avoid water contamination in closed container. V - REACTIVITY DATA Stability - Conditions to avoid: Stable under normal storage and handling conditions - Do not store above 100°F or in auto or direct sunlight; cured foam will deteriorate when exposed to UV light. Incompatibility: Water, alcohol, strong bases, finely powdered metal such as aluminum, magnesium or zinc, and strong oxidizers. Hazardous Decomposition Products: Contamination with water may form CO₂. Conditions Contributing to Hazardous Polymerizations: Contamination with water may form CO2. Avoid high heat (flames, extremely hot metal surfaces, heating elements, combustion engines, etc.). Do not store in auto or direct sunlight. 211 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), A. ACUTE (Primary Route of Exposure): EYE contact with MDI may result in conjunctival irritation and mild corneal opacity. SKIN contact may result in dermatitis, either irritative or allergic. INHALATION of MDI vapors may cause irritation of the mucous membranes of the nose, throat or trachea, breathlessness, chest discomfort, difficult breathing and reduced pulmonary function. Air-borne overexposure well above the PEL may result additionally in eye irritation, headache, chemical bronchitis, asthma-like findings or pulmonary edema. Isocyanates have also been reported to cause hypersensitivity pneumonitis, which is characterized by flu-like symptoms, the onset of which may be delayed. Gastrointestinal symptoms include nausea, vomiting and abdominal pain. Polyurethane resin forms a quick bond with skin. Cured foam is hard to remove from skin. May cause eye damage. B. SUBCHRONIC, CHRONIC, OTHER: Acute or chronic overexposure to isocyanates may cause sensitization in some individuals, resulting in allergic symptoms of the lower respiratory tract (asthma-like), including wheezing, shortness of breath and difficulty breathing. Subsequent reactions may occur at or substantially below the PEL and TLV. Asthma caused by isocyanates, including MDI, may persist in some individuals after removal from exposure and may be irreversible. Some isocyanate sensitized persons may experience asthma reactions upon exposure to non-isocyanate containing dusts or irritants. Cross sensitization to different isocyanates may occur. Long-term overexposure to isocyanates has also been reported to cause lung damage, including reduced lung function, which may be permanent. An animal study indicated that MDI may induce respiratory hypersensitivity following dermal exposure. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Breathing difficulties, chest discomfort, headache, eye and nose membrane irritation. VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Give oxygen. If not breathing, give artificial respiration. Keep victim quiet. Do not give stimulants. Get immediate medical attention. EYES: In case of eye contact, flush with water for 15 minutes. Get immediate medical attention. SKIN: If frostbitten, warm skin slowly with water; otherwise, wash affected areas with soap and water. Remove wet foam immediately from skin with acetone or nail polish remover. If foam dries on skin, apply generous amounts of petroleum jelly or lanolin, leave on for one hour, wash thoroughly, and repeat process until foam is removed. Do not attempt to remove dried foam with solvents. INGESTION: In case of ingestion, get immediate medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management: If can ruptures, protect area from heat, sparks, flames, or static electricity. Turn off sources of ignition. Vapors are heavier than air. Make sure area is adequately ventilated. Allow foaming process to complete; then dispose according to federal, state and local regulations. Waste Disposal Methods Waste Dispose of cured foam per federal, state and local regulations. Container Dispose according to federal, state and local regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not Applicable Eye Protection Safety glasses Gloves Rubber gloves Other Clothing and Equipment: Wear gloves and safety glasses. Use in well ventilated areas only. See section IV. Ventilation: Maintain local exhaust rate to keep below TLV. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Always store upright between 0 °F(min) and 100° F(max). Do not store in sunlight. 1 1 Fire Hazard................: 4 Fire Hazard .................. : 4 Reactivity ..................: 1 Reactivity..................... : 1 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 213 214 A Nu-Klean II I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Nu-Klean II Product Number: 4194 Synonyms: Waterless Hand Cleaner II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Adepsine Oil 8012-95-1 5 mg/m3 5mg/m3 mis d'Limonen 5988-27-5 NE 9-Octadecenoic Acid 112-80-1 NE Clay 1317-66-3 10mg/m3 15mg/m3 dust Pumice 60676-86-0 NE 15mg/m3 dust All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg N/A Vapor Density (Air=1) 60-90° F: >1 Evaporation Rate (ether=1) N/AV VOC Content (% by wt.): Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/AV pH as Distributed: 8.3 Boiling Point °F: 212° Appearance: Orange gel Specific Gravity H₂O=1 @25° C: 0.95 Odor: Citrus IV - FIRE AND EXPLOSION Flash Point F None to Boiling Flammable Limits No Data Extinguishing Media: Does not support combustion. Special Fire Fighting Procedures: Keep containers cool and vapors down with water spray. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: Stable Incompatibility: Strong acids, bases, oxidizers and selected amines. Hazardous Decomposition Products: CO₂, CO, hydrogen bromide, nitrous oxides and ammoniacal compounds. Conditions Contributing to Hazardous Polymerizations: None, will not occur. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Harmful if swallowed. May cause blindness. EYES May cause irritation. SUBCHRONIC, CHRONIC, OTHER Ingestion May irritate gastrointestinal tract. Pre-existing skin disorders C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 215 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Get to fresh air. EYES: Flush with plenty of water for 15 minutes, lifting eyelids to insure complete rinsing. Get medical attention. SKIN: N/A INGESTION: Rinse mouth, drink plenty of water. Call a physician immediately. VIII - SPILL OR LEAK PROCEDURE Spill Management: Caution - slip hazard. Wipe up or scoop product for reuse, or put in suitable container for disposal. Rinse residuals with water. Waste Disposal Methods: Consult local, state & federal regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: None required Eye Protection Safety glasses Gloves None required Other Clothing and Equipment: None required. Ventilation: Mechanical General. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Keep from freezing. Store in cool, dry location. Replace lid when not in use or use follow-plate. Wash or wipe skin after use. Avoid contact with eyes. Do not swallow. 0 0 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 216 A Odor-Free Deodorant Towels I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Odor-Free Deodorant Towels Product Number: 4294 Synonyms: II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL 1-Butoxyl-2-Propanol ab 10215-33-5 <4 N/E Synthetic isoparrafinic hydrocarbon 64742-47-8 <92 N/E a On 1 1 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 218 A Oxine I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Oxine Product Number: 4295-12 Synonyms: Sanitize and Deodorize II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Chlorite 3.35 N/A Chlorine Dioxide 0.1 All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: 23.7 mm Hg (25°C) Vapor Density (Air=1) 60-90° F: 0.02 kg/m Evaporation Rate: Comparable to water VOC Content (% by wt.): Solubility in H₂O: Complete pH @ Solution: Freezing Point °F: N/A pH as Distributed: Boiling Point °F: 213°F (100°C) Appearance: Clear liquid Specific Gravity H₂O=1 @25° C: 1.03 g/ml Odor: Very faint chlorinous odor IV - FIRE AND EXPLOSION Flash Point F None to boiling Flammable Limits N/A Extinguishing Media: Water unless contraindicated by other material involved in fire. Special Fire Fighting Procedures: Do not allow Oxine solutions to evaporate to dryness. If chlorine dioxide gas is produced, vent atmoshpere. Open or vent any large container of Oxine Unusual Fire and Explosion Hazards: The sodium chlorite in dried Oxine is a strong oxidizer, which supports combustion. Chlorine dioxide, which may evolve from Oxine solutions, is explosive in the gaseous phase at concentrations greater than 10% by volume. Do not allow chlorine dioxide gas to accumulate within a confined space V - REACTIVITY DATA Stability - Conditions to avoid: Product is Stable. Avoid storing product under conditions in which it could evaporate to crystalline salt. Incompatibility: Avoid accidental contact with acids, chlorine compounds, hypochlorites (bleach), sulfer and sulfite compounds, phosphorus, organic solvents, and combustible/flammable materials Hazardous Decomposition Products: Exposure to acids or chlorine compounds can produce uncontrolled generation of chlorine dioxide gas Conditions Contributing to Hazardous Polymerizations: Does not occur 219 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Rat Oral LD50 4.360 mg/Kg. Ingestion may produce gastric discomfort. nausea, vomiting and diarrhea. Intake of large quantities may produce methemoglobinemia. EYES: Based upon rabbit studies, product has been given an EPA Category III rating as a mild irritant. Exposure can produce slight irritation of conjunctiva, cornea and eyelid. SKIN: Based on rabbit studies, product is listed as "practically not an irritant". Prolonged exposure may produce localized irritation, contact dermatitis, mild erythema and odema. It is highly unlikely to be absorbed throught the skin in toxic amounts. Rabbit Acute Dermal LD50 > 2,020 mg/Kg. INHALATION Acute inhalation LC50 > 5.61 mg/L. Prolonged inhalation of fog or mist containg Oxine may be irritating to nose and throat. B. SUBCHRONIC, CHRONIC, OTHER: May cause localized irritation to areas exposed to product C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Skin disorder, such as dermal allergies and dermatitis. Exposure to chlorine dioxide produced by activation can aggravate pulmonary disorders, such as emphysema VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Unactivated Oxine normally has no respiratory effects. If exposure to chlorine dioxide produced from activation occurs, remove victim to fresh air. Contact a physician if respiratory distress continues EYES: Flush eyes thoroughly with water, making certain eyelids are held open. If irritation or burning persist, seek medical attention SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and rinse thoroughly with water before laundering or discard. If irritation occurs, seek medical attention. INGESTION: DO NOT INDUCE VOMITING. Contact a physician or Poison Control center immediately VIII - SPILL OR LEAK PROCEDURE Spill Management: Small spills, involving less than 10 gallons, may be flushed to a designated and permitted sewer system with copious amount of water. Larger spills should be contained and neutralized with sodium bisulfite or sodium thiosulfate (1.2 lbs neutralizer per each estimated lb. of spilled material) or disposed of as chemical waste in a manner indicated below. At no time should the spilled material be allowed to dry to a crystalline salt. Waste Disposal Methods: Small quantities, less that 10 gallons, may be flushed to an authorized and designated sewer with copious amount of water. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory Fogging or spraying applications may require worker respiratory protection such as NIOSH/MSHA approved air-purifying respirators or NIOSH/MSHA approved canister/cartridge facial respirators rated for chlorine/acid vapors or specified for chlorine dioxide. Eye Protection Use of chemical safety goggles for all applications involving chemical handling Gloves Rubber, neoprene or other chemically impervious gloves be worn for all applications Other Clothing and Equipment: Protective clothing to minimize contact (boots, apron, faceshield) Ventilation: Open air or good room ventilation is normally adequate for safe use of this product. Avoid breathing vapors or fumes X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: 1 Fire Hazard................: 0 Fire Hazard .................. : Reactivity ..................: 1 Reactivity..................... : Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 221 222 A Pan Pads Condensate Treatment I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Pan Pads Condensate Treatment Product Number: 4295, 4296 Synonyms: Condensate Drain Pan Treatment EPA Regis. No. 33427-4-65516 EPA Est. No. 33427-NY-1 II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Alkyl (60% C14, 30% C16, 5 98391-01-5 20 LD50: 500mg/kg not est. %C12, 5% C18) Dimethyl benzyl ammonium chloride Monohydrate LD50: 500mg/kg Alkyl (68% C12, 32% C14) 68956-79-6 20 not est. Dimethyl ethylbenzyl ammonium chloride Monohydrate not est.. 60 not est. Borax . All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate (ether=1) N/A VOC Content (% by wt.): Solubility in H₂O: 14% pH @ Solution: Freezing Point °F: N/A pH as Distributed: Boiling Point °F: N/A Appearance: White tablet Specific Gravity H₂O=1 @25° C: N/A Odor: odorless IV - FIRE AND EXPLOSION Flash Point F Non Flammable Flammable Limits N/A Extinguishing Media: Water, CO₂, foam, dry chemical. Special Fire Fighting Procedures: Use self-contained breathing apparatus and protective clothing. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: Stable. Incompatibility: Strong oxidizers. Hazardous Decomposition Products: Oxides of carbon, nitrogen, and other toxic decomposition products in case of incomplete combustion. Conditions Contributing to Hazardous Polymerizations: N/A 223 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Not known; expected to cause nausea and diarrhea EYES & SKIN: Severe irritation. B. SUBCHRONIC, CHRONIC, OTHER: Product is not meant to be inhaled, ingested, or touched as implied by its packaging, which doesn't permit skin contact. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Move person to fresh air. EYES: SKIN: Flush/wash thoroughly for at least 15 minutes, for eyes, seek immediate medical attention. INGESTION: Promptly drink large quantities of milk, egg whites, gelatin solution or water, avoid alcohol. Do not induce vomiting. Seek medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management: Pick up material with scoop, shovel or vacuum and place in closed container. Flush area with water. Waste Disposal Methods: Dispose of in accordance with federal, state and local regulations. Pesticides are acutely hazardous, and improper disposal of excess is a violation of Federal law. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: None Eye Protection Safety glasses Gloves Disposable Other Clothing and Equipment: N/A Ventilation: N/A X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Tablet should never be removed from its housing. It must not come in contact with food. Avoid contact with skin and eyes. Store in cool, dry place. 0 0 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 224 A Pan -Spray Aerosol I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Pan -Spray Aerosol Product Number: 4296 Synonyms: Rubberized Coating II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Xylene * 1330-20-7 100 ppm Aliphatic Hydrocarbon * 110-54-3 500 ppm Poly (Butadiene-co-styrene) 9003-55-8 not established N-tallowalkyl trimethylene 91791-53-5 not determined diamines ole. 68476-86-8 800 ppm Hydrocarbon propellant * Subject to reporting requirements of SARA TITLE III, Section 313 All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: <75 PSI Vapor Density (Air=1) 60-90° F: Heavier than Air Evaporation Rate: VOC Content (% by wt.): 68% Solubility in H₂O: Nil pH @ Solution: Freezing Point °F: pH as Distributed: Boiling Point °F: Not determined Appearance: White coating Specific Gravity H₂O=1 @25° C: 0.850 Odor: IV - FIRE AND EXPLOSION Flash Point F N/A Flammable Limits Level 3 Aerosol Extinguishing Media: Dry Chemical. CO₂. Halogenated Extinguishing Agent. Stop Gas Flow Special Fire Fighting Procedures: Gas fires should not be extinguished unless the gas flow can be stopped immediately. Allow the fire to burn itself out. If the source cannot be shut off immediately, all equipment and surfaces exposed to the fire should be cooled with water to prevent over-heating, flash-backs, or explosions. Control fire until gas supply can be shut off. Use proper protective equipment. Use fresh air respirator when exposure to hazardous concentrations of toxic gases is possible. Unusual Fire and Explosion Hazards: This product releases Flammable Vapors at well below ambient temperatures and readily forms flammable mixtures with air exposed to an ignition source. It will burn in the open or be explosive in confined spaces. Its vapors are heavier than air and may travel long distances to a point of ignition, and then flash back. Alkaline/chlorine gas mixtures have produced explosions. V - REACTIVITY DATA Stability - Conditions to avoid: Stable Incompatibility: Strong oxidizing agents Hazardous Decomposition Products: None Conditions Contributing to Hazardous Polymerizations: Not applicable 225 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), A. ACUTE (Primary Route of Exposure): Inhalation - High vapor/aerosol concentrations (greater than approximately 100 ppm) are irritating to the eyes and the respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness, and other central nervous system effects, including death. EYES - Slightly irritating but does not injure eye tissue. SKIN - Low order of toxicity. Frequent or prolonged contact may irritate and cause dermatitis. Skin contact may agreavate an existing dermatitis condition. INGESTION - Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe pulmonary injury, possibly minimal toxicity B. SUBCHRONIC, CHRONIC, OTHER: Health studies have shown that many hydrocarbons pose potential human helath risks which may vary from person to person As a precaution, exposure to liquids, vapors, mists or fumes should be minimized. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Using proper respiratiory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention. EYES: Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical attention. SKIN: Flush with large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes, and launder before reuse. INGESTION: If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management: Clean up area by mopping or with absorbant materials and place in closed container for disposal. Consult Federal, State, and local disposal authorities. Waste Disposal Methods: Consult local authorities for proper waste disposal procedures. Empty de-pressurized containers can not be reused. Cans which are pressurized or contain liquid must be disposed of in a permitted waste management facility. Consult Federal, State and local disposal authorities for approved procedures. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Based on contamination level and working limits of the respirator, use a respirator approved by NIOSH/MSHA. Eye Protection Face shield and goggles or chemical goggles should be worn. Gloves Impervious gloves should be worn. Gloves contaminated with the product should be discarded. Polyfluorinated polyethylene has been suggested. Other Clothing and Equipment: Standard work clothing. Ventilation Use adequate level exhaust ventilation. Note Where carbon monoxide may be generated, special ventilation may be required. Local exhaust recommended when appropriate to control employee exposure. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: When utilizing pressurized containers follow standard safety practices for handling aerosols. 2 2 Fire Hazard................: 4 Fire Hazard .................. : 4 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 227 228 A Pan-Treat I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Pan-Treat Product Number: 4296-60 Synonyms: Condensate Pan Treatment II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL n-Alkyl(60% C14, 30% C16, 5% 98391-01-5 C12, 5% C18 ) dimethyl benzyl ammonium chloride. No ingredients identified by 1 Fire Hazard................: Fire Hazard .................. : 0 Reactivity ..................: Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 230 A Phase III Refrigeration Oil Test Kit (L) I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Phase III Refrigeration Oil Test Kit (L) Product Number: 4320L Synonyms: Toluene / Alcohol Blend II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Toluene* (ORAL LD50 = 5000mg/kg) 108-88-3 <50 200ppm (DERMAL LD50 = 14g/kg) Methanol** (ORAL LD50 = 13g/kg) 67-56-1 <35 200ppm (DERMAL LD50 = 20g/kg) Isopropanol*** (ORAL LD50 = 67-63-0 <30 400ppm 5840mg/kg) (DERMAL LD50 = 13g/kg) *STEL=150ppm; **STEL=1250ppm; ***STEL=500ppm All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg Unknown Vapor Density (Air=1) 60-90° F: Unknown Evaporation Rate (ether=1) N/AV VOC Content (% by wt.): 100 Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: <212° Appearance: Clear, colorless solution Specific Gravity H₂O=1 @25° C: .827 Odor: Characteristic IV - FIRE AND EXPLOSION Flash Point F <55°F Flammable Limits Unknown Extinguishing Media: In case of fire use CO₂, foam or dry chemical. Special Fire Fighting Procedures: Exercise caution when fighting any chemical fire. Respiratory protection is essential. Unusual Fire and Explosion Hazards: None. V - REACTIVITY DATA Stability - Conditions to avoid: Heat and open flame. Incompatibility: Unknown. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYE & SKIN May cause irritation. Prolonged and repeated contact to skin may result in dermatitis. INGESTION & INHALATION: Harmful if swallowed or inhaled. May cause nausea, dizziness and upset stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 231 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: If inhaled, remove patient to fresh air. EYES: In case of contact, flush with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush with plenty of water. If irritation develops, call a physician. INGESTION: If swallowed, DO NOT induce vomiting. Call a physician. VIII - SPILL OR LEAK PROCEDURE Spill Management: Flush away spill with plenty of water. Waste Disposal Methods: Flush product waste down drain with plenty of water. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Avoid breathing vapors Eye Protection Safety glasses Gloves None required Other Clothing and Equipment: None required. Ventilation: None required. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. 1 1 Fire Hazard................: 2 Fire Hazard .................. : 2 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 232 A Phase III Refrigeration Oil Test Kit (S) I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Phase III Refrigeration Oil Test Kit (S) Product Number: 4320S Synonyms: Potassium Hydroxide Solution (trace amount KOH-is not a corrosive) II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Sodium Chloride (ORAL LD50 = 7647-14-5 <5 N/A N/AV) All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure mm Hg N/A Vapor Density (Air=1) 60-90° F: N/A Evaporation Rate (ether=1) N/AV VOC Content (% by wt.): Unknown Solubility in H₂O: Complete pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: 10.9 Boiling Point °F: Unknown Appearance: Clear, colorless solution Specific Gravity H₂O=1 @25° C: 1.106 Odor: Characteristic IV - FIRE AND EXPLOSION Flash Point F No flash to boiling Flammable Limits N/A Extinguishing Media: Product is non flammable Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None V - REACTIVITY DATA Stability - Conditions to avoid: None known. Incompatibility: Unknown. Hazardous Decomposition Products: Unknown. Conditions Contributing to Hazardous Polymerizations: None known. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) EYE & SKIN May cause irritation. Prolonged and repeated contact to skin may result in dermatitis. INGESTION: May upset stomach. B. SUBCHRONIC, CHRONIC, OTHER: No available information was found. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: N/A EYES: In case of contact, flush with plenty of water for at least 15 minutes. Call a physician. SKIN: In case of contact, flush with plenty of water. If irritation develops, call a physician. INGESTION: If swallowed, DO NOT induce vomiting. Give large quantities of water or milk to drink. Give at least one ounce of vinegar in an equal amount of water. Never give anything by mouth to an unconscious person. Call a physician. 233 VIII - SPILL OR LEAK PROCEDURE Spill Management: Flush away spill with plenty of water. Waste Disposal Methods: Flush product waste down drain with plenty of water. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: None required Eye Protection Safety glasses Gloves None required Other Clothing and Equipment: None required. Ventilation: None required. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid contact with eyes, skin and clothing. Wash hands after use. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 234 A Pipe-Dri I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Pipe-Dri Product Number: 4297 Synonyms: Insulation Spray II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Methylene Chloride* 75-09-2 60-75 50ppm 500ppm Propane 74-98-6 <5 1000ppm Isobutane 76-28-5 <5 800ppm not est. *SARA 313 Information: Subject to reporting and supplier notification of SARA 313 *RO #1000 lbs. VOC Content: 25.00% By Weight All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure psig @ 25°C 80 Vapor Density (Air=1) 60-90° F: >1 Evaporation Rate (ether=1) <1 VOC Content (% by wt.): N/A Solubility in H₂O: Insoluble pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: N/A Appearance: White coating Specific Gravity H₂O=1 @25° C: 1.25 Odor: Sweet Chlorinated Odor IV - FIRE AND EXPLOSION Flash Point F N/A Flammable Limits LEL Not Est. UEL Not Est Extinguishing Media: CO₂, Standard foam, Dry chemical, Halon Special Fire Fighting Procedures: Wear self-contained breathing apparatus. Unusual Fire and Explosion Hazards: Exposure to temp. over 120°F may cause bursting or venting. Heat or fire may cause hazardous fumes: CO, phosgene chlorine and HCL. V - REACTIVITY DATA Stability - Conditions to avoid: Stable; avoid sources of heat. Incompatibility: Oxidizing Materials. Hazardous Decomposition Products: Will not occur. Conditions Contributing to Hazardous Polymerizations: Open flames. VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INGESTION Nausea, headache, vomiting. EYES Moderate to severe irritation. SKIN May cause irritation, due to defatting of tissues. INHALATION Nausea, dizziness, coordination impairment on long exposure. B. SUBCHRONIC, CHRONIC, OTHER: C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 235 VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Give oxygen if breathing is difficult. Get medical attention. EYES: Flush with large amounts of water for 15 minutes and get medical attention. SKIN: Wash with soap and water. Remove contaminated clothing. INGESTION: Do not induce vomiting. Get medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management: Small spills - Mop up, soak up immediately. Remove to outdoors. Large spills - Evacuate area. Contain liquid; transfer to closed metal containers. Keep out of water supply. Waste Disposal Methods: Dispose of in accordance with federal, state and local regulations as well as EPA standards. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: None Eye Protection Safety glasses Gloves Disposable Other Clothing and Equipment: None Ventilation: General ventilation recommended to maintain the level of the hazardous ingredients to less than half of the TLV X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not store where temperatures will exceed 120°F. Keep out of reach of children. 1 1 Fire Hazard................: 0 Fire Hazard .................. : 0 Reactivity ..................: 0 Reactivity..................... : 0 Specific Hazard ........: Personal Protection.... : X (Sec. 9) Revision Date: 8/6/2004 Seller makes no warranty, expressed or implied, concerning the use of this product other than indicated on the label. Buyer assumes all risk of use and/or handling of this material when such use and/or handling is contrary to label instructions. While Seller believes that the information contained herein is accurate, such information is offered solely for its customers' consideration and verification under their specific use conditions. 236 A Pneu-flush I - PRODUCT IDENTIFICATION Company Name: Nu-Calgon Wholesaler, Inc. Tel No: (314) 469-7000, (800) 554-5499 Address: 2008 Altom Court, St. Louis, MO 63146-4151 CHEMTREC: (800) 424-9300 Product Name: Pneu-flush Product Number: 4298 Synonyms: Hydrofluorocarbon II - HAZARDOUS INGREDIENTS OF MIXTURES MATERIAL CAS# % By Wt TLV PEL Decafluoropentane 138495-42-8 60-85 200 Methanol 67-56-1 811- 3-4 200 Tetrafluoroethane (HFC-134a) 97-2 15-25 1000 All ingredients are TSCA listed. III - PHYSICAL DATA Vapor Pressure: 260 mm/Hg @ 77°F Vapor Density (Air=1) 60-90° F: Heavier than air Evaporation Rate: >>1 (ether=1) VOC Content (% by wt.): 100 Solubility in H₂O: Minimal pH @ Solution: N/A Freezing Point °F: N/A pH as Distributed: N/A Boiling Point °F: 118°F Appearance: Colorless liquid Specific Gravity H₂O=1 @25° C: 1.497 Odor: Ethereal odor IV - FIRE AND EXPLOSION Flash Point F Non Flammable Flammable Limits Air, LEL=9% & UEL=11% Extinguishing Media: CO₂, dry chemical or water Special Fire Fighting Procedures: Wear self-contained NIOSH approved breathing apparatus and proper eye and skin protection. Unusual Fire and Explosion Hazards: Containers generate pressure when heated, causing violent bursting and dangerous propelling of container. Cool containers with water spray or fog. V - REACTIVITY DATA Stability - Conditions to avoid: Material is stable - Avoid high temperatures or open flames which may cause decomposition. Incompatibility: Avoid strong bases, reactive materials (e.g. powdered aluminum, sodium, potassium, calcium, magnesium, zinc, molten aluminum, barium & lithium shavings). Hazardous Decomposition Products: Hydrochloric and hydrofluoric acids, and possibly carbonyl halides. Conditions Contributing to Hazardous Polymerizations: Will not occur. 237 VI - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE (Medical Conditions Aggravated/Target Organ Effects), ACUTE (Primary Route of Exposure) INHALATION Gross overexposure may cause suffocation if air is displaced by vapor, irregular heart beat with a strange sensation in the chest, lightheadedness, dizziness, fainting, drowsiness. It is unlikely that concentrations sufficient to produce these effects would be achieved without producing other signs of overexposure such as irritation of the nose and throat with sneezing, sore throat, or runny nose. ORAL: Short term exposure may cause irritation of digestive tract, stomach pain, nausea, vomiting or diarrhea. Liquid which may enter the lungs may result in "chemical pneumonia". SKIN: Slight irritation with redness, itching or swelling may occur. Defatting of the skin can occur with repeated overexposure. EYES: Liquid contact: Will irritate eyes and may cause redness, swelling, pain, tearing and hazy vision. SUBCHRONIC, CHRONIC, OTHER CARCINOGENICITY None of the components of Air Line Flushing Solvent are listed as carcinogens by NTP, IARC, or OSHA C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. Give artificial respiration if necessary. If breathing is difficult, give oxygen. Call physician.

Disposal

Consult Federal, State, and local disposal authorities for approved procedures Waste Disposal Methods: Consult local authorities for proper waste disposal procedures. Empty, de-pressurized containers cannot be reused. Cans which are pressurized or contain liquid must be disposed of in a permitted waste management facility. Consult Federal, State and local disposal authorities for approved procedures. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Based on contamination level and working limits of the respirator, use of respirator approved by NIOSH/MSHA. Eye Protection Face shield and goggles or chemical goggles should be worn. Gloves Impervious gloves should be worn. Gloves contaminated with product should be discarded. Polyfluorinated polyehtylene has been suggested. Other Clothing and Equipment: Standard work clothing. Standard work shoes; discard if shoes cannot be decontaminated. Store contaminated clothing in well ventilated cabinets or closed containers. Wash contaminated clothing and dry before reuse. Ventilation Use adequate level exhaust ventilation. Note Where carbon monoxide may be generated, special ventilation may be required. Local exhaust recommended when appropriate to control employee exposure. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: When utilizing pressurized containers follow standard safety practices for handling aerosols. Do not puncture or incinerate containers. Do not store at temperatures above 130 F. Odor is not an adequate warning of potentially hazardous concentrations in air. Releases of these gases may cuase a flammable atmosphere with explosion potential. Empty container retains product residue. Observe all hazard precautions. Do not distrubute, make available, furnish or reuse empty container except for storage and shipment of originial product. Remove all product residue from container and puncture or otherwise destroy empty container before disposal. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Use MSHA-NIOSH approved respirator for organic vapors, dusts and mists whose TLV is greater than 0.05 mg/m3. Eye Protection Chemical tight goggles Gloves Impervious Other Clothing and Equipment: Impervious gloves and apron. Eyewash station and safety shower in work area. Ventilation: Use ventilation adequate to maintain safe levels. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Prevent skin contact. Empty container retains product residue. Observe all hazard precautions. do not distribute, make available, furnish or reuse empty container except for storage and shipment of original product. Remove all product residue from container and puncture or otherwise destroy empty container before disposal. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not normally needed, if controls are adequate. If needed, use MSHA-NIOSH approved respirator for organic vapors Eye Protection Chemcial tight goggles Gloves Impervious Other Clothing and Equipment: Eyewash station and safety shower in work area. Ventilation: Use ventilation adequate to maintain safe levels. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Avoid prolonged or recurring skin contact. Avoid inhalation or high concentrations of mists or aerosols. Avoid ingress or moisture by keeping containers properly sealed when not in use. Product application requires that the product remain dry and free of excessive moisture pick-up. Keep away from strong oxidizing agents. Pesticide, spray mixture, or rinsate that cannot be used or chemically reprocessed should be disposed of in a landfill approved for pesticides. CONTAINER DISPOSAL: Dispose of in an incinerator or landfill approved for pesticide containers. Do not reuse empty container. GENERAL: Consult federal, state or local disosal authorities for approved alternative procedures. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Dust mask essential where dusting may occur. Eye Protection Eye goggles Gloves Rubber gloves Other Clothing and Equipment: Protective clothing. Ventilation: Local and mechanical exhaust is recommended. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Do not get in eyes, on skin or clothing. Keep container closed. Keep out of reach of children. After handling, wash hands throughly. Do not breath dusts. Store in a cool, dry area away from fire or flame.

Storage

Avoid ingress of moisture by keeping containers properly sealed when not in use. Product application requires that the product remain dry and free of excessive moisture pick-up. Keep away from strong oxidizing agents.

Aspiration hazard

DO NOT INDUCE VOMITING or give anything by mouth because this material can enter the lungs or cause severe damage. Do not leave victim unattended. If vomiting occurs, or if comatose or lethargic, place on the left side with the head down. Seek immediate medical attention. VIII - SPILL OR LEAK PROCEDURE Spill Management Large spills wear appropriate protective clothing. Stop source of leak if possible. Dike, contain spill and recover free liquid. Prevent entry into waterways. Soak up residue with an inert absorbent such as clay, sand or other suitable materials. Store and dispose of properly. Flush area with water. Where feasible and appropriate, remove contaminated soil. Small spills: Neutralize and/or soak up spill with inert absorbent. Store in a closed container and dispose of properly. Waste Disposal Methods: Dispose of in accordance with local, state and federal regulations. Disposal of this material to the land may be banned by federal law (40 CFR 268). IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Good industrial hygiene practices recommend that engineering controls be used to reduce environmental concentrations to the threshold limit value (TLV), if applicable. If an applicable TLV is exceeded provide NIOSH approved respiratory protection. Provide sufficient mechanical, general, and/or local exhaust to maintain exposure below any applicable TLV or PEL. Eye Protection Safety glasses w/side shield or Chemical goggles Gloves Use neoprene type gloves when handling this product. Other Clothing and Equipment: Impervious protective clothing and chemical resistant safety shoes should be worn to minimize contact. Wash contaminated clothing with soap and water and dry before reuse. Emergency shower and eyewash facility should be provided in all areas in which this product is handled. Ventilation: Maintain adequate ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Maintain ambient temperatures. Avoid prolonged/repeated breathing of vapors, mists, fumes. Keep container tightly closed. Do not store near heat, flame, strong oxidants.

Principle Routes of Exposure

SKIN Causes severe irritation. May cause burns on prolonged contact. INHALATION Mists irritating to upper respiratory tract. INGESTION: Severely irritating to mouth, throat and stomach. B. SUBCHRONIC, CHRONIC, OTHER: None known. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. SKIN: Flush skin with plenty of water for at least 15 minutes. If irritation persists, get medical attention. INGESTION: Do NOT induce vomiting. Give 1 or 2 glasses of water to dilute. Get immediate medical attention. 197 VIII - SPILL OR LEAK PROCEDURE Spill Management: Small spills may be mopped up and residues flushed to drain with water. Rinse mop before storing. Neutralize with dilute solution of soda ash. Waste Disposal Methods: Unused material is corrosive waste (D002). Used material may be sewered in accordance with all applicable regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not normally required. Eye Protection Splash goggles. Gloves Rubber gloves Other Clothing and Equipment: None normally required. Ventilation: Good general ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: This product will withstand an occasional accidental freezing without loss of performance. Thaw and remix before use. SKIN Causes severe irritation. May cause burns on prolonged contact. INHALATION Mists irritating to upper respiratory tract. INGESTION: Severely irritating to mouth, throat and stomach. B. SUBCHRONIC, CHRONIC, OTHER: None known. C. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: VII - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. SKIN: Flush skin with plenty of water for at least 15 minutes. If irritation persists, get medical attention. INGESTION: Do NOT induce vomiting. Give 1 or 2 glasses of water to dilute. Get immediate medical attention. 199 VIII - SPILL OR LEAK PROCEDURE Spill Management: Small spills may be mopped up and residues flushed to drain with water. Rinse mop before storing. Neutralize with dilute solution of soda ash. Waste Disposal Methods: Unused material is corrosive waste (D002). Used material may be sewered in accordance with all applicable regulations. IX - PROTECTION INFORMATION/CONTROL MEASURES Respiratory: Not normally required. Eye Protection Splash goggles. Gloves Rubber gloves Other Clothing and Equipment: None normally required. Ventilation: Good general ventilation. X - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: This product will withstand an occasional accidental freezing without loss of performance. Thaw and remix before use.