Premier Super Stick Canister

SECTION 2: Hazards identification

3.1 EMERGENCY OVERVIEW Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Intentional concentration and inhalation may be harmful or fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Sings/Symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed: Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURE 5.1 FLAMMABLE PROPERTIES Flammability: Flammable per industry standard flame projection test Auto ignition temp Not Established Flash Point -156 degrees F (-104 degrees C) Flammable Limits-LEL 1.8 Flammable Limits-UEL 18 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide) 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Evacuate unprotected and untrained personnel from hazard area. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Ventilate the area with fresh air. Contain spill. Mix in sufficient absorbent until it appears dry. Collect in approved container and dispose of according to local, state and federal laws and regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Avoid breathing of vapors, mists or spray. Keep out of reach of children. Use general ventilation and/or local exhaust ventilation. If ventilation is not adequate, use respiratory protection equipment.

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields. Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Goves made from the following material(s) are recommended: Polyvinyl Alcohol (PVA), Polyethylene/Ethylene Vinyl Alcohol. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information Dimethyl Ether AIHA TWA 1000 ppm Dimethyl Ether CMRG TWA 1000 ppm Heptane ACGIH TWA 400 ppm Heptane ACGIH STEL 500 ppm Heptane OSHA TWA, Vacated 400 ppm Heptane OSHA TWA 500 ppm Table Z-1 Heptane OSHA STEL, Vacated 500 ppm Propane ACGIH TWA 1000 ppm Propane OSHA TWA 1000 ppm Isobutane ACGIH TWA 1000 ppm Hexane ACGIH TWA 50 ppm Hexane OSHA TWA 500 ppm Table Z-1A Hexane OSHA TWA, Vacated 50 ppm Table Z-1A VAC Vacated PEL: Vacated Permissible Exposure Limits (PEL) are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCES OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists AIHA: American Industrial Hygience Association Workplace Environmental Exposure Level (WEEL) CMRG: Chemical Manufacturer Recommended Guideline EPA: