Northland Techata 700

Hazard statements (CLP)

H312, H314, H318, H332

Code

Statements

H312

Harmful in contact with skin

Precautionary statements

P2614 - Avoid breathing dust, fume, mist, spray, vapours P271 - Use only outdoors or in a well-ventilated area P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P312 - Cail a a doctor, a POISON CENTER if you feel unwell This product contains a petroleum-based mineral Proionged or repeated skin contact can

2.1 Classification of the substance or mixture

cause mild irritation and inflammation characterized by drying, cracking, (dermatitis) or oil acne. Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. Spills of this product present a serious slipping hazard.

Ingredient(s) with unknown acute toxicity

No data available 3 Su Not applicable

Hazard statements

see section 16 | Name: ductidentifie lassificatior Distillates, petroleum, solvent-refined heavy paraffinic (CAS No) 64741-88-4 46-60 Acute Tox. 4 (Inhalation:dust mist), H332 Phosphoric acid, bis(2-ethylhexyl) ester {CAS No) 298-07-7 6.2-0.4 Acute Tox. 4 (Dermal), H312 Skin Cor, 1C, H314 Eye Dam. 1, H318 08/19/2014 EN (English) SDS 1D: S0M4 Page 1 according to the federal final rule of hazard communication revised on 2042 (HazCom 2042) escription of first: First-aid measures general Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible}. First-aid measures after inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing, Assure fresh air breathing. Maintain an open airways. In case of breathing difficulties administer oxygen, Cail a POISON CENTER or doctor/physician. First-aid measures after skin contact Wipe off as much as possible (using a clean, soft, absorbent material). Remove affected clothing and wash ail exposed skin area with mild soap and water, followed by warm water rinse. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. When using high-pressure equipment, injection of product can occur. Injection under the skin of pressurized hydrocarbons can cause severe, permanent tissue damage. injection of petroleum hydrocarbons requires immediate medical attention. Heated product causes burns. Do not put ice on the burn. Burns caused by heated material must be treated clinically. First-aid measures after eye contact in case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes hoiding eyelids apart. Subsequently consult an ophthaimologist. If redness, burning, blurred vision or swelling occur, transport to nearest medical facility for additional treatment. First-aid measures after ingestion If swallowed, rinse mouth with water (only if the person is conscious). Do NOT induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Immediately call a POISON CENTER or doctor/physician. 4 ays Symptoms/injuries This product contains a petroleum-based mineral oil. Prolonged or repeated skin contact can cause mild irritation and inflammation characterized by drying, cracking, (dermatitis) or oll acne, Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. Symptoms/injuries after inhalation Harmful if inhaled. At elevated temperatures or in enclosed spaces, product mist or vapors may irritate the mucous membranes of the nose, the throat, bronchi, and fungs. High concentration of vapours may induce: headache, dizziness, drowsiness, nausea and vomiting. Symptomssinjuries after skin contact Prolonged/repetitive skin contact may cause skin defattening or dermatitis. Injection under the skin of pressurized hydrocarbons can cause severe, permanent tissue damage. Injection of petroieum hydrocarbons requires immediate medical attention. Heated product causes burns. Symptoms/injuries after eye contact Oil Mist, May cause eye irritation. Symptomsj/injuries after ingestion Ingestion may cause nausea, vomiting and diarrhea. y iinmediate medical attentl No additional information available 5 guishing Suitable extinguishing media Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire. le vapours. Precautionary measures fire Approach from upwind. Vapours may travel long distances along ground before igniting/flashing back to vapour source. This material may burn but will not ignite readily. Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protective equipment for firefighters Do not enter fire area without proper protective equipment, including respiratory protection. Wear self-contained respiratory apparatus during longer or intensive exposition or spraying processing.

Further information

Special danger of slipping by leaking/spilling product. Material will float and can be re-ignited on surface of water, Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Toxic and irritating gases are released following therma! decomposition or combustion. General measures Use personal protective equipment as required. Special danger of slipping by leaking/spilling product. Stop leak if safe to do so. Relevant water authorities should be notified of any large spillage to water course or drain. GT For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. 08/19/2014 EN (English) ™ SOS 1D: 50M4 38 according to the federal final rule of hazard communication revised on 2012 (HazCom 2042) BAR, For amargency responders Protective equipment Equip cleanup crew with proper protection. Emergency procedures The low volatility of this product does not require ventilation. However depending on the condition an adequate ventalation might be required. snmental precautions Prevent entry to sewers and public waters. An environmental fate analysis is not available for this specific product. Plants and animals may experience harmful or fatal effects when coated with petroleum products. Petroleum-based (mineral) oils normally will float on water. {n stagnant or siow-flowing waterways, an oil layer can cover a large surface area. As a result, this oi! jayer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depietion in the waterway may be sufficient to cause a fish kill or create an anaerobic environment, Notify authorities if liquid enters sewers or public waters. Methods for cleaning up Approach from upwind. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Do not absorb with saw-dust or any other combustible absorbent material. Collect spillage, Store away from other materials. This material will float on water. In case of small spillages in closed waters, contain product with floating barriers or other equipment. Consult the appropriate authorities about waste disposal. Large spilis: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Consult the appropriate authorities about waste disposal. For large fiquid spills (> 4 drum), transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal. Collect spilis and put it into appropriated container. Ensure all nationai/ocal regulations are observed. The use of dispersants should be advised by an expert, and, if required, approved by local authorities. In case of soil contarnination, remove contaminated soil and treat in accordance with local regulations, This material is classified as an oi! under Section 311 of the Clean Water Act (CWA) and the Oi! Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits teading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. ‘Reference to other sections See Heading 8. Exposure controls and personal protection. qe , tions forsafe Additional hazards when pracessed Special danger of slipping by feaking/spilling product. Precautions for safe handling Obtain special instructions before use. Avoid contact with skin, eyes and clothes. Personal protective equipment should be selected based upon the conditions under which this product is handled or used. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing dust/fume/gas/mist/vapours/spray. Empty container retains product residue. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work, Proper grounding procedures to avoid static electricity should be followed. Avoid splash filling of bulk volumes when handling hot liquid product. Hygiene measures Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Separate working clothes from town clothes. Launder separately. Do not eat, drink or smoke when using this product. Discard contaminated leather articles. onditions for Safé Storage, including an i Technical measures Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists and/or vapors below the recommended exposure limits. Ground/bond container and receiving equipment. Use explosion-proof ventilating equipment. A washing facilityAwater for eye and skin cleaning purposes should be present. Ensure that all relevant regulations regarding handling and storage facilities of combustible products are followed, Storage conditions Keep container closed when not in use. Keep only in the original container in a cool, well- ventilated place away from highly flammable substances. Keep away from open flames, hot surfaces and sources of ignition. Keep container tightly closed. Store containers in an upright manner to prevent leakage. Keep locked up and out of reach of children. incompatible materials Strong reducing agents. Oxidizing agents. Heat and ignition sources Remove all sources of ignition. 7 Specific use(s)’ nal information available 08/49/2014 EN (Engtish) SDS 10: 50M4 3/8 according to the federal finat rule of hazard communication revised on 2012 (HazCom 2042) Appropriate engineering controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists and/or vapors below the recommended exposure limits. A washing facilityAwater for eye and skin cleaning purposes should be present. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Personal protective equipment Personal protective equipment should be selected based upon the conditions under which this product is handled or used. Avoid all unnecessary exposure. The following pictograms represent the minimum requirements for personal protective equipment. Gloves. Protective ciothing. Protective goggles. For certain operations, additional Personal Protection Equipment (PPE) may be required, Hand protection Wear protective gloves. Nitrile-rubber protective gloves. For special purposes, it is recommended to check the resistance to chemicals of the protective glaves mentioned above together with the supplier of these gloves. Eye protection Chemical goggles or safety glasses. with side-shields. Eye protection, including both chemical splash goggles and face shield, must be worn when possibility exists for eye contact due to spraying liquid or airborne particles. Skin and body protection Chemical resistant suit. Wear rubber boots. Respiratory protection Work in well-ventilated zones or use proper respiratory protection. if there is any possibility of uncontrolled emissions or entering in instances where the exposure levels are unknown use a full-facepiece positive-pressure, air-supplied respirator. Thermal hazard protection Incase of insufficient ventilation, wear suitable respiratory equipment. Wear a self-contained breathing apparatus and appropriate personal protective equipment (PPE}. Wear heat resistant boots and protective clothing when handling material at elevated temperatures. Environmental exposure controls Avoid discharge to the environment. Ensure waste is collected and contained. Notify authorities if product enters sewers or public waters. Do not eat, drink or smoke during use. oA Information Physical state Liquid Colour Clear to light amber. Odour Petroleum characteristic. Odour threshold No data available pH No data available Relative evaporation rate (buty! acetate=1)} No data available Meiting point No data available Freezing point No data available Boiling point No data available Flash point 246 °C (475 °F) Test method: COC Auto-ignition temperature No data available Decomposition temperature No data available Flarnmability (solid, gas) No data available Vapour pressure <0.01 mmHg @ 37.8 °C (100 °F) Relative vapour density at 20 °C 1 > Relative density > 0.885 g/em* at 15.6 °C /60 °F Solubility Water: insoluble Organic solvent:completely soluble Log Pow Base oil hydrocarbons: fog Kow > 4 (estimate) Log Kow Base oil hydrocarbons: log Kow > 4 (estimate) Viscosity, kinematic 184 eSt (40 °C/104 °F) Viscosity, dynamic ; No data available Explosive properties No data available Oxidising properties No data available Explosive iimits. No data available 9.2. ‘Ot ‘mati No additional information available SOS 1D: 50M4 8" 08/19/2014 EN (English) according {o the federal final rule of hazard communication revised on 2012 (HazCom 2012) patible: materials Strong reducing agents. Oxidizing agents. Acute toxicity > Harmful if inhaled. Distillate: raffinic. 4 LD50 oral rat > 5000 mg/kg LD50 dermai rabbit > 2000 mg/kg C50 inhalation rat (mg/l) 2.18 mgfi4h ATE CLP (dust,mist) 2.180 mg/V#4h Phosp LDSO oral rat 4940 pi/kg LDS50 dermal rabbit 1250 pkg ATE CLP (dermal) 1100,000 mg/kg bodyweight Skin corrosion/irritation Not classified (Based on available data, the classification criteria are not met) Serious eye damage/irritation Not classified (Based on available data, the classification criteria are not met) Respiratory or skin sensitisation Not classified (Based on available data, the classification criteria are not met) Germ cell mutagenicity Not classified (Based on available data, the classification criteria are not met) Carcinogenicity Not classified (Based on available data, the classification criteria are not met) Reproductive toxicity Not classified (Based on available data, the classification criteria are not met) Specific target organ toxicity (single exposure): Not classified (Based on available data, the classification criteria are not met} Specific target organ toxicity (repeated Not classified (Based on avaliable data, the classification criteria are not met) exposure)

Aspiration hazard

Not classified (Based on available data, the classification criteria are not met) Potential Adverse human health effects and Based on available data, the classification criteria are not met. symptoms Symptoms/injuries after inhalation Harmful if inhaled. At elevated temperatures or in enclosed spaces, product mist or vapors may irritate the mucous membranes of the nose, the throat, bronchi, and lungs. High concentration of vapours may induce; headache, dizziness, drowsiness, nausea and vomiting. Symptoms/injuries after skin contact Prolonged/repetitive skin contact may cause skin defattening or dermatitis. Injection under the skin of pressurized hydrocarbons can cause severe, permanent tissue damage. Injection of petroleum hydrocarbons requires immediate medical attention. Heated product causes burns. Symptoms/injuries after eye contact Oil Mist. May cause eye irritation. Symptomsj/injuries after ingestion Ingestion may cause nausea, vomiting and diarrhea. A oxic! Ecology - general An environmental fate analysis is not available for this specific product. Plants and animals may experience harmful or fatal effects when coated with petroleum products. Petroleum-based (mineral) ois normally will float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result, this ail layer might fimit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway may be sufficient to cause a fish kill or create an anaerobic environment. Distillates, pet f i LC50 fishes 4 | §000 mg/l (Exposure time 96 h - Species Oncorhynchus mykiss) 08/19/2014 EN (English) SDS ID: SOM4 5/8 according to the federal final rule of hazard communication revised on 2012 (HazCom 2012) 1000 mgd (Exposure time 48 h - Species Daphnia magna) 20 mg/t (Exposure tim ncorhynchus mykiss [static]) [ Not established, Base oil hydrocarbons: log Kow > 4 (estimate) Base oil hydrocarbons: log Kow > 4 (estimate) Not established. Avoid release to the environment. Waste disposal recommendations r Dispose in a safe manner in accordance with {ocai/national regulations. Liquid product may not be disposed of with household waste or landfilled, Do not allow to enter into drains/waters or in the soil. Additional information Used oif, may contain harmful impurities. It is the responsibility of the user to determine if disposal material is hazardous according to federal, state and local regulations. Ecology - waste materials Avoid release to the environment.