First-aid measures general

Precautionary statements

fire Approach from upwind. Vapaurs may travel long distances along ground before igniting/lashing back to vapour source. This material may burn but wil not ignite readily. Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protective equipment for firefighters Do not enter fire area without proper protective equipment, including respiratory protection. Wear self-contained respiratory apparatus during longer or intensive exposition or spraying processing.

Further information

Special danger of slipping by leaking/spilling product. Material will float and can be re-ignited on surface of water. Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Toxic and irritating gases are released following thermal decomposition or combustion. 6 Perse cautions, protec i General measures Use personal protective equipment as required. Special danger of slipping by leaking/spilling product. Stop leak if safe to do so. Relevant water authorities should be notified of any large spillage to water course or drain. B44. For non-eniergen vat Emergency procedures Evacuate unnecessary personnel. 08/19/2014 EN (English) . SDS 10: 60M4 218 according to the federal finat ruie of hazard communication revised on 2012 (HazCom 2012) For amergency responders Protective equipment > Equip cleanup crew with proper protection. Emergency procedures The low volatility of this product does not require ventilation, However depending on the condition an adequate ventalation might be required. ntal precaution Prevent entry to sewers and public waters. An environmental fate analysis is not available for this specific product. Plants and animals may experience harmful or fatal effects when coated with petroleum products. Petroleum-based (mineral) oils normally will float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway may be sufficient to cause a fish kill or create an anaerobic environment. Notify authorities if liquid enters sewers or public waters. 4 é gu Methods for cleaning up Approach from upwind. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible, Do not absorb with saw-dust or any other combustible absorbent material. Collect spillage. Store away from other materials. This material will float on water. In case of smail spillages in closed waters, contain product with floating barriers or other equipment. Consult the appropriate authorities about waste disposal. Large spills: Contain any spilis with dikes or absorbents to prevent migration and entry into sewers or streams. Consult the appropriate authorities about waste disposal, For large liquid spilis (> 4 drum), transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal. Collect spills and put it into appropriated container. Ensure all national/local regulations are observed. The use of dispersants should be advised by an expert, and, if required, approved by focal authorities. In case of soil contamination, remove contaminated soil and treat in accordance with focal regulations. This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. TA Yecautio: ate-handlin Additional hazards when processed Specia! danger of slipping by leaking/spilling product. Precautions for safe handling Obtain special instructions before use, Avoid contact with skin, eyes and clothes. Personal protective equipment should be selected based upon the conditions under which this product is handled or used. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing dust/fume/gas/mist/vapours/spray. Empty container retains product residue. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Proper grounding procedures to avoid static electricity should be followed. Avoid splash filling of bulk volumes when handling hot liquid product. Hygiene measures Contaminated work clothing should not be allowed out of the workplace, Wash contaminated clothing before reuse. Separate working clothes from town clothes. Launder separately. Do not eat, drink or smoke when using this product. Discard contaminated leather articles. 12. ond’ 3 for safe storage, including an \ Technical measures Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists and/or vapors below the recommended exposure limits. Ground/bond container and receiving equipment. Use explosion-proof ventilating equipment. A washing facilityAwater for eye and skin cleaning purposes should be present. Ensure that all relevant regulations regarding handling and storage facilities of combustible products are followed. Storage conditions Keep container closed when not in use. Keep only in the original container in a cool, well- ventilated place away from highly flammable substances. Keep away from open flames, hot surfaces and sources of ignition. Keep container tightly closed. Store containers in an upright manner to prevent leakage. Keep locked up and out of reach of children. Incompatible materials Strong reducing agents. Oxidizing agents. Heat and ignition sources Remove all sources of ignition. No additional information available 08/19/2014 EN (English) 3/8 SDS iD: 50M4 according to the federal final rile of hazard communication revised on 2012 (HazCom 2012) KPOSUT 0) Appropriate engineering controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists and/or vapors below the recommended exposure limits. A washing facilityAvater for eye and skin cleaning purposes should be present. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Personal protective equipment Personal protective equipment should be selected based upon the conditions under which this product is handied or used. Avoid all unnecessary exposure. The following pictograms represent the minimum requirements for personal protective equipment. Gloves. Protective clothing, Protective goggles. For certain operations, additional Personal Protection Equipment (PPE) may be required. Hand protection Wear protective gloves. Nitrile-rubber protective gloves. For special purposes, it is recommended to check the resistance to chemicais of the protective gloves mentioned above together with the supplier of these gloves. Eye protection Chemical goggles or safety glasses. with side-shields. Eye protection, including both chemical splash goggles and face shield, must be worn when possibility exists for eye contact due to spraying liquid or airborne partictes, Skin and body protection Chemical resistant suit. Wear rubber boots. Respiratory protection Work in well-ventilated zones or use proper respiratory protection. If there is any possibility of uncontrolled emissions or entering in instances where the exposure levels are unknown use a full-facepiece positive-pressure, air-supplied respirator. Thermal hazard protection In case of insufficient ventilation, wear suitable respiratory equipment. Wear a self-contained breathing apparatus and appropriate personal protective equipment (PPE). Wear heat resistant boots and protective clothing when handling material at elevated temperatures. Environmental exposure controis Avoid discharge to the environment. Ensure waste is collected and contained. Notify authorities if product enters sewers or public waters. Do not eat, drink or smoke during use. Physical state 2 Liquid Colour Clear to light amber, Odour Petroleum characteristic. Odour threshold No data available pH No data available Relative evaporation rate (butyl acetate=1) No data available Melting point No data available Freezing point No data available Boiling point No data available Fiash point 264 °C (807 °F) Test method: COC Auto-ignition temperature No data available Decomposition temperature No data available Flammability (solid, gas) No data available Vapour pressure <0.01mmHg @ 37.8 °C (100 °F) Relative vapour density at 20 °C 134 Relative density 0.888 g/cm? at 16.6 °C /60 °F Solubility Water: insoluble Organic solvent:completely soluble Log Pow Base oil hydrocarbons: log Kaw > 4 (estimate) Log Kow Base oil hydrocarbons: log Kow > 4 (estimate) Viscosity, kinematic 305 eSt (40 °C/104 °F) Viscosity, dynamic No data available Explosive properties No data available Oxidising properties No data available Explosive limits No data available 6 , 4 i No additional information available 08/19/2014 ee "EN (English) SDS 15: BOM4 418 according to the federal finat rule of hazard communication revised on 2012 (HazCom 2012) 10: s Conditior Vv Do not pressurize, cut, weld, braze, solder, drill, grind, or expose containers to flames, sparks, heat, or other potential ignition sources. Harmful if inhaled. LDS0 oral rat > 5000 mg/kg D850 dermal rabbit > 2000 mg/kg LCS50 inhalation rat (mg/l) 2.18 mgil/4h ATE GLP (dust,mist) 2.180 mall/4h OSP. ‘ | i LDS50 oral rat 4940 plhkg LOSO dermal rabbit 1250 pkg ATE CLP (dermal) 1100,000 mg/kg bodyweight Skin corrosion/irritation Not classified (Based on available data, the classification criteria are not met) Serious eye damage/irritation Not classified (Based on available data, the classification criteria are not met} Respiratory or skin sensitisation Not classified (Based on available data, the classification criteria are not met) Germ cell mutagenicity Not classified (Based on available data, the classification criteria are not met) Carcinogenicity Not classified (Based on available data, the classification criteria are not met) Reproductive toxicity Not classified (Based on available data, the classification criteria are not met) Specific target organ toxicity (single exposure): Not classified (Based on available data, the classification criteria are not met) Specific target organ toxicity (repeated Not classified (Based on available data, the classification criteria are not met) exposure)

Aspiration hazard

Not classified (Based on available data, the classification criteria are not met) Potential Adverse human health effects and Based on available data, the classification criteria are not met. symptoms Symptoms/injuries after inhalation Harmful if inhaled, At elevated temperatures or in enclosed spaces, product mist or vapors may irritate the mucous membranes of the nose, the throat, bronchi, and lungs. High concentration of vapours may induce: headache, dizziness, drowsiness, nausea and vomiting. Symptoms/injuries after skin contact Protonged/repetitive skin contact may cause skin defattening or dermatitis. Injection under the skin of pressurized hydrocarbons can cause severe, permanent tissue damage. Injection of petroleum hydrocarbons requires immediate medical attention. Heated product causes bums. Symptoms/injuries after eye contact Oil Mist, May cause eye irritation. Symptoms/injuries after ingestion Ingestion may cause nausea, vomiting and diarrhea. A xicity Ecology - general An environmental fate analysis is not available for this specific product. Plants and animais may experience harmful or fatal effects when coated with petroleum products. Petroleum-based (mineral) oils normally will float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area, As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway may be sufficient to cause a fish kill or create an anaerobic environment. LC50 fishes 1 > 5000 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss} 08/19/2014 EN (English) SDS 10: 50M4 618 according to the federal final nite of hazard communication revised on 2012 (HazCom 2012) Log Pow Base oil hydrocarbons: log Kow > 4 (estimate) Log Kow Base oil hydrocarbons: log Kow > 4 (estimate) Bioaccumulative potential Not established. 4 hin-soll No additional information avai table Avoid release to the environment. Waste disposal recommendations Dispose in a safe manner in accordance with local/national regutations. Liquid product may not be disposed of with household waste or landfilled, Do not allow to enter into drains/waters or in the soil. Additional information Used oil, may contain harmful impurities. It is the responsibility of the user to determine if disposal material is hazardous according to federal, state and local regulations. Ecology - waste materials Avoid release to the environment. Transport in tio) In accordance with ADR / RID /IMDG /[ATA/ ADN IN RUT Not applicable aE JN Not applicable No supplementary information available. Ove d franspart, No additional information available Transport by sae No additional information available Ads transport No additional information available This material is classified as an oi! under Section 341 of the Clean Water Act (CWA) an Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802 CAMA! 08/19/2014 EN (English) SOS 10: 5OM4 oe Safety Data Sheet according to the federal final rule of hazard communication revised on 2042 (HazCom 2012) isted on the Canadian DSL. (Domestic Sustances List) | Listed on the Canadian DSL (Domestic Sustances List) ] EU-Reguletions Listed on the EEC inventory EINECS (European inventory of Existing Commercial Chemical Substances) | isted on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) ] Classification according to Regulation (EC) No. 1272/2008 [CLP] No additional information available Classification according to Directive G7/S48/EEG or 1999/4H/EC No additional information available 15.2.2, National regulations Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China} Listed on the Japanese ENCS (Existing & New Chemicat Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZloC (New Zealand Inventory of Chemicats) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZloC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the Canadian IDL (ingredient Disclosure List) U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity U.S, - Massachusetts - Oif & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2 U.S. - New Jersey - Right to-Know Hazardous Substance List U.S. - New Jersey ~ Special Health Hazards Substances List U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Other information None. Full text of H-phrases: see section 16: Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4 Acute Tox. 4 (inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Corr. 1C Skin corrosion/irritation Category 1C 08/19/2014 EN (English) SDS 1D: 50M4 718 according to the federal final rute of hazard communication revised on 2012 (HazCGom 2042) H312 Harmfui in contact with skin H314 Causes severe skin burns and eye damage H318 Causes serious eye damage H332 Harmful if inhaled SDS US (GHS HazCom 2012) ‘The information presented herein has been compited from sources considered to be dependable and is accurate to the best of Northland Products Company's knowledge; however, Northland Products Company makes no waranty whatsoever, expressed or implied, of merchantability or fitness for the particular purpose, regarding the accuracy of such data or the results fo be obtained from the use thereof. Northland Products Company assumes no responsibility for the injury to the recipiont or to third party persons or for any damage to any property and recipient assumes aif such risks. EN (Engfish)