TAMPUR 116 PART A

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

Health hazards

Skin lrrlL 2- H315 Eye lrrll 2A- H319 Acute Tex. 4 • H332 Skin lrrll 2- H315 Eye lrrll 2A • H319 Resp. Sens. 1 - H334 Skin Sens • H317 Care. 2- H351 STOT SE 3 • H335 STOT RE 2 • H373

Environmental hazards

Not Classified Label efementa Envtronmentally hazardous eubatance/mar1ne pollutant No Special precautlonl for user Not applicable Transport In bulk according to Not applicable Annex II cf MARPOL 73/78 and the IBC Code 115. Ragulalory Information lnventorlea EU • EINECS/ELINCS All the Ingredients ere Hsted or exempt General lnfannatton Only trained peraonnel should use this material Revision data 11/01/2016 SOS number 5300 Hazard statements In fuO H315 causes skin Irritation H319 Causes serious eye Irritation, This Information relates only to the specific material designated and may not be valid for such material used In combination with any other materials or In any process. Such Information Is, to the best of the company's knowledge and belief, accurate and relfable as of the date Indicated. However, no warranty, guarantee or representation Is made to Its accuracy, rellablllty or completeness. It Is the user's responsibility to satisfy himself as to the suitability of such Information for his own particular use Revision date: 21/0712015 Revision; 1 1. ldentfflcation Product ldentlffer Product name TAMPUR 116 PARTB Product number 01• Recommended use of the chemtcal and rastrlctfons on use Restriction on use Seml--flexlble silicate polyurethane Injection Resin Delalla of the auppller of the safety data sheet Suppler Nonnet canada Ltd Columbus Cl Lively, Ontario P3Y 0B3 P.O. Box 4361 Lively, ONP3Y 1N3 Cenada Phone: +1 705 692 2800 Fax: +1 705 692 2805 SOS@NORMET.COM Emergency telephone number Emergency telephone 44 (0) 207 858 1228 • 24 hours Hazard ldentfflcaUon ClasalftcaUon of the aubatance or mbaure Phyak:al hazards Nol Classified Nol Classified

Hazard pictograms

Stgnalword Warning ~ ~

Hazard statements

H315 Causes skin lrrltallon. H319 Causes serious eye lrrltatlon. Ravillllndale: 111'0112018 Rrnlion: 1 Precautionary atatementa P264 Wash contaminated skln thoroughly after handHng. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351 +P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, If present and easy to do. Continue rinsing. P321 Specific treatment (see medical advice on this labeQ. P332+P313 If skin Irritation occurs: Get medical advice/ attention. P337+P313 If eye lnitatlon persists: Get medical advice/ attention. P362+P364 Take off contaminated clothing and wash It before reuse. H315 Causes skin Irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye krltatlon. H332 Harmful If Inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties If Inhaled. H335 May cause respiratory Irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure.

2.3 Other hazards

HSNO ctaaalffcatlon I a. Compoaltlonllnf an lngredlenta SODIUM SILICATE CAS number: 1344-09-8 Claaafflcatlon Skin lrril 2- H315 Eye lnil 2A- H319 The full text for all hazard statements Is displayed In Section 16. OeeaJpUon or 11rat aid meaau11111 General lnfonnallon Move affected person to fresh air and keep wann and at rest In a position comfortable for breathing. Get medk:al attenllon. Treat symptomatically. Inhalation IF INHALED Get medk al attention Immediately._ Move affected parson to fresh air and keep warm and at rest In a position comfortable for breathing. Do not induce vomiting. lngaatlon IF SWALLOWED: Get medical attention Immediately. If throat Irritation or coughing persists, proceed as follows. Rinse mouth thoroughly with water. Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Stop If the affected person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Skin contact IF ON SKIN (or hair): Rinse immediately with plenty of water. Continue to rinse for at least 10 minutes. Get medical attenllon If Irritation persists after washing. Remove contaminated clothing. Eye contact IF IN EYES: Remove any contact lenses end open eyelids wide apart Continue to rinse for at least 15 minutes end get medical attention. Get medical attention If lnitation persists after washing. Protacllon of first alders Arst aid personnel should wear appropriate protective equipment during any rescue. Moat important aymptoma and affeds, both acute and delayed General lnfcrmatlon Treat symptomatlcaUy. See Section 11 for additional Information on health hazards. Inhalation Irritating. Ingestion May cause stomach pain or vomiting. May cause Irritation. Gastrointestinal symptoms, Including upset stomach. Re¥lllon dale: 11/01/2018 Revlllcn: 1 Skin contact May cause skin Irritation. Eye contact Causes skin and eye lnitatlon. Indication of any Immediate medlcal attention and lpeclal treatment needed Not88 for lhe doctor Treat symptomallcally, Specific treatmenta Treat symptomallcaHy. 15, Fire-fighting rnwuree Extinguishing media Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire. Extinguish with alcohol-resistant foam, carbon dioxide or dry powder. Speclflc hazards arising fi"Crn the hazardous prodUct Specfflc hazards None known. Hazardous combustion None known. products Advice for ftraftghtera Protectlva actions during No action shall be taken without appropriate training or Involving any personal risk. Stop leak flreflghtlng If safe to do 110. If leakage cannot be stopped, evacuate area. Move containers from fire area If It can be done without risk. Spadal protective equipment Use air-supplied rasplrator, gloves and protective goggles. for flreflghtera Personal precautions, protective equipment and emergency proceduru Personal precautions No action shaH be taken without appropriate training or Involving any persQnal risk. Keep unnecessary and unprotected personnel away from the spillage. Avoid contact with skin, eyes and clothing. Avoid Inhalation of vapours. Follow precautions for safe handling described In this safety data sheel Environmental precautions SplHages or uncontrolled discharges Into watercourses must be reported Immediately to the Environmental Agency or other appropriate regulatory body. Do not discharge Into drains or watercourses or onto the ground. Avoid the splKage or runoff entering drains, sewers or watercourses. Methods an_d material for containment and deanli, ue Methods for deaning up If leakage cannot be stopped, evacuate area. Move containers from spHlage area. Large Spillages; Absorb spHlage with sand or other Inert absorbenl Collect and place In suitable waste disposal containers and seal securely. Small Spillages: Absorb small quantities with paper towels and evaporate In a safe place. Residues and empty containers should be taken care of as hazardous waste according to local and national provisions. Dispose of waste to Hcensed waste disposal site In accordance with the requirements of the local Waste Disposal Authority. Reference to other seclfons Reference to other sections For personal protection, &ee Section 8. For waste disposal, see Section 13. See Section 11 for additional Information on health hazards. See Section 12 for additional information on ecological hazards. Revision ct.le: 11/01/20111 Precautions for safe handling Usage precautions For professional users only. Do not handle until all safety precautions have been read and understood. Use only In wen-ventilated areas. Keep container dry. Container must be kept tightly closed when not In use. Oo not eat. drink or smoke when U$lng this product. Advice on general Do not eat, drink or smoke when using this product. Provide eyewash station. Wash promptly occupational hygiene with soap and water If skin becomes contaminated. PrompUy remove any clothing that becomes contaminated. Conditions for safe storage, Including any lnoompatlbllltles Storage precautions Store at temperatures between 4•c and 30"C. Store In tlghUy-closed, orlglnal container In a dry, cool and well-ventilated place. Do not store near heat sources or upose to high temperatures. Store away from the foHowlng materials: Acids. Alkalis.

Storage

d888 Chemical storage. Spedllc end use(a) Specfflc end use{•) The Identified uses for thl.s product are detaRed In Section 1.2. Control parameters i8 Approprtale engineering This product Is not to be used under conditions of poor ventilation. In case of Insufficient Exposww controls controls ventilation, wear suitable respiratory equlpmanl Eye/face protection Personal protective equipment for eye and face protection should comply with the Csnadlan regulation on health and safety at work, SOR/86-304, Part XII (12.6). and any relevant provlnclal regulation relating to health and safety at work. Hand protection To protect hands from chemicals, gloves should comply with the Canadian regulation on health and safety at work, SOR/86-304, Part XII (12.9), and any relevant provlnclal regulation relaUng to health and safety al work. Nltrlle rubber. Butyl rubber. other akin and body Wear appropriate clothing to prevent skin contamlnallon. protac:llon Hygiene measures Wash hands thoroughly after handling. PrompUy remove any clothing that becomes contaminated. Do not eat, drink or smoke when using this product Respiratory protection No specific requirements are anticipated under normal conditions of use. Environmental exposure Keep container tightly sealed when not In use. Residues and empty containers should be conlrota taken care of as hazardous waste according to local and national provisions. 19. pt,yalcal and Chemical Propertlea Information on baalc phyalcal and chemical prope11191 Appearance Clear liquid. CoJour Colourless. '1/8 ReYlllan date: 11/01/2018 Odour Characteristic. Odour threshold Not detennlned. pH Not available. Melting point Not applicable. Initial bolNng point and range Not determined. Flash point >200"C Evaporation rate Not detennlned. Evaporation factor Not detennlned. FlanvnablHty (aolld, gas) Not appllcable. Upper/lower 1'lammabfflty or Not appltcable. explolfve Omits Other ftammablllty Not applicable. Vapour pressure Not detennlned. Vapourdenalty Not determined. Relative density Not applk:able. Bulk density Not applk:able. Solublllty(la) Not detennlned. Par1ftlon coeftk:lerlt Not determined. Aldo-Ignition temperature Not determined. Decomposition Temperature Not determined. Vlscoefty 120 • 350 mPa s@ 25"C Exploelve properties Not applicable. Exploalve under the Influence Not conslderad to be explosive. of aflame O>ddlalng properties Not applicable. Density 1.30 • 1.57 g/cm3 110. stability and readlvlty Readlvlty Polymerises exolhermk:ally with dilsocyanates et ambient temperatures. The reaction becomes progressively more vigorous and can be violent at higher temperatures If the miscibility of reaction partners Is good or ls supported by stirring or by the presence of solvents. S1abntty Stable at normal ambient temperatures and wnen used as recommended. PosalbHlly of hazardous Under normal condltloo.s of storage and use, no hazardous reactions will occur. ructions CondltJona to avoid Avoid exposure to high temperatures or direct sunlight. SIS Revltlandalll: 11,'01/2018 Materials to avoid No spec:lric material or group of materials Is Hkely to react with the product to produce a hazardous sltoation. Hazardous decompoelllon None known. producbl j 11. Taxlcofoglcal ~ lnbmatlon on toxlcologlcal effects Toxlcologlcal effects This Information has been determined by consideration of Iha toxlcologlcal data for the components and for analogous products. Acute tmdclty - oral Notes (oral Lt>.) Method(&) - Metodo OCOE 401 Condlclones • rat male/female Results/Conclusions• LOSO = 3400 mg/Kg bw. Acute taxlcHy - dennal Notes (dannal LO.) Melhods(s) • EPA OPPTS 870.1200 Condlclones - rat (Sprague-Cawley) male/female Material: CAS 1312-76-1 Results/Conclusions -LOSO> 5000 mg/kg bw. Acute tmdclty - Inhalation Notes (Inhalation LC.) Method(s) - EPA OPPTS 870.1300 Condlclones - rat (Sprague-Dawley) male/female Material: CAS 1312•76-1 Results/Conclusions - LC50 {4hr) > 2.06 mg/Lair. Skin corroslonllnflaon Animal data Primary dermal Irritation Index: 0.4 Serious eye damage/Inflation Serious eye damag&nrrltatlon SllghUy Irritating. RNplratoryl8nsltlzatlon ~lratory sensitization Based on available data the classification criteria are not meL Skin aensltfzatlon Skin aensNfzation Based on available data the classification criteria are not meL Gann call mutaganldty Genotoxlcfty- In vitro Conclusive data but not sufficient for classification. Genotoxlclly - In vtvo Conclusive data but not sufficient for classification. Carolnog'"lclty Carcinogenicity Based on available data the classlficaUon criteria are not meL Conclusive data but not sufficient for classification. Reproductive toxicity Reproductive toxicity· fertHlty Based on available data the classlfteatlon crllarla are not meL Reproductive toxicity- This substance has no evidence of toxicity to reproduction. development $pecfflc target organ tmdclty- alngle exposure STOT • alngle exposure Not determined. Specillc target organ toxicity· repeated axpoaure STOT - n,peatad exposure NOAEL =159 mg/kg bw/day, Oral, {rat Sprague-Cawley male/female). NOAEL =2400 mg/kg bw/day, Oral, (rat Charles River Cesarean-derived male/female). 6/8 RaYllion date: 111'01/2016

Aspiration hazard

Aapfratlon hazard Not anticipated to present an aspiration hazard, based on chemical structure Ecotoxlclty Ecotoxlcologlcal data have not been detennlnad specifically for this product. Information given Is based on a knowledge or the components and the ecotoxlc:ology of slmllar products Toxicity No lnformallon avallable Acute toxicity - fish NOEC, 98 hours~ 1108 mg/I, Brachydanlo rerto (Zebra Fish) NOEC, (96 hours: Mortallty)=348 mg/1, Brachydanlo rerio (Zebra Fish) Acute toxldty - aquatic OECD Guldellne 202, part 1 ), 48 hours: 1700 mg/1, Oaphnla magna Invertebrates Acute toxicity-aquatic plants DIN 38412, Tell 9 according to OECD 201 72 hours: 207 mg/I, Scenedesmus aubsplcatus 72 hours: >345.4 mg/1, Scenedesmus subsplcatus Acute toxicity - Sclentlfically unjustified microorganisms Perslstance and degradablftty Pel'lllatence and degradab81ty The product Is degraded completely by ablotlc reduction Phototransfonnatlon Sclentlfically unjustified Blodegradatlon Sclenllflcally unjustified Bloaccumulatfve potential Bloaccumulallon Is unlikely Partition coeffldent Not determined MobHlty In 8011 Mobmty The product Is ·soluble In water. The product Is non-volatlle Results or PBT and vPvB auesament Results of PBT and vPvB This product does not contain any substances classified as PST or vPvB aaseument Other adverse effecla Other adverse effects None known l1a Dllpoeaf consldendlona Wasta treatment methods General Information Dispose of waste to Hcensed waste disposal site In accordance with the requirements of the local Waste Disposal Authority. Waste should be treated as controlled wasts Disposal methods Dispose or contents/container In accordance with national ragulatlons. Waste should be treated as controlled waste j 14, Transport lnfannatlon General The product Is not covored by lntemallonal regulallons on the transport of dangerous goods IMDG; IATA, TOG) 118 dete: 1111)1/2018

UN Number

UN No. (lntematlonal) Not applicable UN properlhlpplng name Proper shipping name Not applicable lntematlonal) Transport hazard clau(a) Transport Labell No transport wamlng sign required International) Pac:klng group Packing group (lntematlonal) Not appUcable

Signal word

Danger 1111 RevlslDn dale: 21/07/2015 Revisla!I: 1

Precautionary statements

P201 Obtain special Instructions before usa. P202 Do not handle until all safety precautions have been read and understood. P260 Do not braathe vapour/ spray. P261 Avoid breathing vapour/ spray. P264 Wash contaminated skin thoroughly after handling. P271 Use only outdoors or In a well-ventilated area. P272 Co.ntamloated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 [In case of Inadequate ventilation) wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty ofwatar. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351 +P336 IF IN EYES: Rlnse cautiously with water for several minutes. Remove contact lenses, If present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P312 Call a POISON CENTER/ doctor If you feel unwell. P314 Get medical advice/ attention If you feel unwell. P321 Specific treatment (see medical advice on this label). P332+P313 If skin Irritation occurs: Get medical advice/ attention. P333+P313 If skin Irritation or rash occurs: Get medical advice/ attention. P337+P313 If eye Irritation persists: Get medical advice/ attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor. P362+P364 Take off contaminated clothing and wash It before reuse. P403+P233 Stora In a well-ventilated place. Keep container tightly closed. P405 Store iocked up. P501 Dispose of contents/ container In accordance wHh national regulations.

Contains

lsocyanlc Acid, polymethylenepolyphenylene ester, Dlphenylmethane 4,4' • dilsocyanate

Other hazards

HSNO Claulflcatlon Mbduras 2111 Revtllion dale: 21/07/2015 Revision: 1 lsocyanfc Add, polymelhylenepolyphen eater 60-100% CAS number: 9016-87-9 Classlflcatlon Acute Tox. 4 • H332 Skin lrrll 2- H315 , Eye lrriL 2A • H319 Resp. Sens. 1 - H334 Skin Sens. 1- H317 Care. 2- H351 STOT SE 3 • H335 STOT RE 2 - H373 Dlphenylmethane 4,4' - dlisoc:yanat8 CAS number: 101-68-8 Claafflcatlon Acute Tox. 4 - H332 Skin lrrlt. 2 • H315 Eye lrrll 2A • H319 Resp. Sens. 1 • H334 Skin Sens. 1- H317 Care. 2 - H351 ' STOT SE 3 • H335 STOT RE 2 - H373 The full text for all hazard statements Is displayed In Section 16. Desctjpllon of fir8t aid meaauraa General lnfonnatlon Move affected person to fresh air and keep warm and at rest In a position comfortable for breathing. Get medical attention. Treat symptomatically. Inhalation IF INHALED: Get medical attention Immediately. Move affected person to fresh air and keep warm and at rest In a position comfortable for breathing. Do not Induce vomiting. Ingestion IF SWALLOWED: Get medical attention Immediately. If throat Irritation or coughing persists, proceed as follows. Rinse mouth thoroughly with water. Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Stop If the affected person feels sick as vomiting may be dangerous. If vomiting occura, the head should ba kept low so that vomit does not enter tha lungs. Skin contact IF ON SKIN (or hair): Rinse Immediately with plenty of water. Continue to rinse for at least 10 minutes. Get medical attention If Irritation persists after washing. Remove contaminated clothing. Eye contact IF IN EYES: Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention. Get medical attention If Irritation persists after washing. Protection of first aldera First aid personnel should wear appropriate protective equipment during any rescue. Most lmpor1ant symptoms and effects, both acute and delayed General Information Treat symptomatically. See Section 11 for additional lnformaUon on health hazards. S/11 Revltlon dale: 21/07/2015 Inhalation May cause sensitization by lnhalallon. The liquid may be lrrltatlng to eyes, respiratory system and skin. May cause allergy or asthma symptoms or breathing difficulties If Inhaled. Development of symptoms may be delayed for 24 to 48 hours. lngeatlon Gastrolntestlnal symptoms, Including upset stomach. Skin contact May cause skin Irritation. May cause sensitization or allergic reactions In sensitive Individuals. Eye contact Causes skin and eye Irritation. Indication of any lmmecllate medical attention and special Cnlatment needed Notes for the doctor Treat symptomatlcally. Spedflc trealmentl Treat symptomallcally. 1 s. Flnt-tlghUng ~ures Extinguishing media SUltabla exflngufshlng medla Use fire-extinguishing media suitable for the surrounding fire. Extinguish with alcohol-resistant foam, carbon dioxide or dry powder. Unsuitable extinguishing Do not use water, If avoidable. media Specific hazatdl arising from the hazardous product Specfflc hazards The product Is not flammable. Irritating gases or vapours. Hazardous combustion Harmful gases or vapours. productl Advice for ftreflghters Protective adlons during Stop leak If safe to do so. If leakage cannot be stopped, evacuate area. Move containers from firefighting fire area If It can be done without risk.

2.1 Classification of the substance or mixture

Not anticipated to present an aspiration hazard, based on chemical structure. Ecotoxlclty Ecotoxlcologlcal data have not been detennlnad specifically for this product. Information given Is based on a knowledge or the components and the ecotoxlc:ology of slmllar products. Toxicity No lnformallon avallable. Acute toxicity - fish NOEC, 98 hours~ 1108 mg/I, Brachydanlo rerto (Zebra Fish) NOEC, (96 hours: Mortallty)=348 mg/1, Brachydanlo rerio (Zebra Fish) Acute toxldty - aquatic (OECD Guldellne 202, part 1 ), 48 hours: 1700 mg/1, Oaphnla magna Invertebrates Acute toxicity-aquatic plants DIN 38412, Tell 9 according to OECD 201 , 72 hours: 207 mg/I, Scenedesmus aubsplcatus , 72 hours: >345.4 mg/1, Scenedesmus subsplcatus Acute toxicity - Sclentlfically unjustified. microorganisms Perslstance and degradablftty Pel'lllatence and degradab81ty The product Is degraded completely by ablotlc reduction. Phototransfonnatlon Sclentlfically unjustified. Blodegradatlon Sclenllflcally unjustified. Bloaccumulatfve potential Bloaccumulallon Is unlikely. Partition coeffldent Not determined. MobHlty In 8011 Mobmty The product Is ·soluble In water. The product Is non-volatlle. Results or PBT and vPvB auesament Results of PBT and vPvB This product does not contain any substances classified as PST or vPvB. aaseument Other adverse effecla Other adverse effects None known. l1a. Dllpoeaf consldendlona Wasta treatment methods General Information Dispose of waste to Hcensed waste disposal site In accordance with the requirements of the local Waste Disposal Authority. Waste should be treated as controlled wasts. Disposal methods Dispose or contents/container In accordance with national ragulatlons. Waste should be treated as controlled waste. j 14, Transport lnfannatlon General The product Is not covored by lntemallonal regulallons on the transport of dangerous goods (IMDG; IATA, TOG). 118 ~ dete: 1111)1/2018 UN number UN No. (lntematlonal) Not applicable. UN properlhlpplng name Proper shipping name Not applicable. (lntematlonal) Transport hazard clau(a) Transport Labell No transport wamlng sign required. (International) Pac:klng group Packing group (lntematlonal) Not appUcable. Environmental hazards Envtronmentally hazardous eubatance/mar1ne pollutant No. Special precautlonl for user Not applicable. Transport In bulk according to Not applicable. Annex II cf MARPOL 73/78 and the IBC Code 115. Ragulalory Information lnventorlea EU • EINECS/ELINCS All the Ingredients ere Hsted or exempt General lnfannatton Only trained peraonnel should use this material. Revision data 11/01/2016 1 SOS number 5300 Hazard statements In fuO H315 causes skin Irritation. H319 Causes serious eye Irritation, This Information relates only to the specific material designated and may not be valid for such material used In combination with any other materials or In any process. Such Information Is, to the best of the company's knowledge and belief, accurate and relfable as of the date Indicated. However, no warranty, guarantee or representation Is made to Its accuracy, rellablllty or completeness. It Is the user's responsibility to satisfy himself as to the suitability of such Information for his own particular use. Revision date: 21/0712015 Revision; 1 1 1. ldentfflcation Product ldentlffer Product name TAMPUR 116 PARTB Product number 01• Recommended use of the chemtcal and rastrlctfons on use Restriction on use Seml--flexlble silicate polyurethane Injection Resin Delalla of the auppller of the safety data sheet Suppler Nonnet canada Ltd. 1 Columbus Cl Lively, Ontario P3Y 0B3 P.O. Box 4361 Lively, ONP3Y 1N3 Cenada Phone: +1 705 692 2800 Fax: +1 705 692 2805 SOS@NORMET.COM Emergency telephone number Emergency telephone +44 (0) 207 858 1228 • 24 hours 12. Hazard ldentfflcaUon ClasalftcaUon of the aubatance or mbaure Phyak:al hazards Nol Classified Health hazards Acute Tex. 4 • H332 Skin lrrll 2- H315 Eye lrrll 2A • H319 Resp. Sens. 1 - H334 Skin Sens. 1 • H317 Care. 2- H351 STOT SE 3 • H335 STOT RE 2 • H373 Environmental hazards Nol Classified Label elements Pictogram ~ ~ Signal word Danger 1111 RevlslDn dale: 21/07/2015 Revisla!I: 1 Hazard statements H315 Causes skin Irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye krltatlon. H332 Harmful If Inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties If Inhaled. H335 May cause respiratory Irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. Precautionary statements P201 Obtain special Instructions before usa. P202 Do not handle until all safety precautions have been read and understood. P260 Do not braathe vapour/ spray. P261 Avoid breathing vapour/ spray. P264 Wash contaminated skin thoroughly after handling. P271 Use only outdoors or In a well-ventilated area. P272 Co.ntamloated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 [In case of Inadequate ventilation) wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty ofwatar. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351 +P336 IF IN EYES: Rlnse cautiously with water for several minutes. Remove contact lenses, If present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P312 Call a POISON CENTER/ doctor If you feel unwell. P314 Get medical advice/ attention If you feel unwell. P321 Specific treatment (see medical advice on this label). P332+P313 If skin Irritation occurs: Get medical advice/ attention. P333+P313 If skin Irritation or rash occurs: Get medical advice/ attention. P337+P313 If eye Irritation persists: Get medical advice/ attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor. P362+P364 Take off contaminated clothing and wash It before reuse. P403+P233 Stora In a well-ventilated place. Keep container tightly closed. P405 Store iocked up. P501 Dispose of contents/ container In accordance wHh national regulations. Contains lsocyanlc Acid, polymethylenepolyphenylene ester, Dlphenylmethane 4,4' • dilsocyanate other hazards HSNO Claulflcatlon Mbduras 2111 Revtllion dale: 21/07/2015 Revision: 1 lsocyanfc Add, polymelhylenepolyphen eater 60-100% CAS number: 9016-87-9 Classlflcatlon Acute Tox. 4 • H332 Skin lrrll 2- H315 , Eye lrriL 2A • H319 Resp. Sens. 1 - H334 Skin Sens. 1- H317 Care. 2- H351 STOT SE 3 • H335 STOT RE 2 - H373 Dlphenylmethane 4,4' - dlisoc:yanat8 CAS number: 101-68-8 Claafflcatlon Acute Tox. 4 - H332 Skin lrrlt. 2 • H315 Eye lrrll 2A • H319 Resp. Sens. 1 • H334 Skin Sens. 1- H317 Care. 2 - H351 ' STOT SE 3 • H335 STOT RE 2 - H373 The full text for all hazard statements Is displayed In Section 16. Desctjpllon of fir8t aid meaauraa General lnfonnatlon Move affected person to fresh air and keep warm and at rest In a position comfortable for breathing. Get medical attention. Treat symptomatically. Inhalation IF INHALED: Get medical attention Immediately. Move affected person to fresh air and keep warm and at rest In a position comfortable for breathing. Do not Induce vomiting. Ingestion IF SWALLOWED: Get medical attention Immediately. If throat Irritation or coughing persists, proceed as follows. Rinse mouth thoroughly with water. Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Stop If the affected person feels sick as vomiting may be dangerous. If vomiting occura, the head should ba kept low so that vomit does not enter tha lungs. Skin contact IF ON SKIN (or hair): Rinse Immediately with plenty of water. Continue to rinse for at least 10 minutes. Get medical attention If Irritation persists after washing. Remove contaminated clothing. Eye contact IF IN EYES: Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention. Get medical attention If Irritation persists after washing. Protection of first aldera First aid personnel should wear appropriate protective equipment during any rescue. Most lmpor1ant symptoms and effects, both acute and delayed General Information Treat symptomatically. See Section 11 for additional lnformaUon on health hazards. S/11 Revltlon dale: 21/07/2015 Inhalation May cause sensitization by lnhalallon. The liquid may be lrrltatlng to eyes, respiratory system and skin. May cause allergy or asthma symptoms or breathing difficulties If Inhaled. Development of symptoms may be delayed for 24 to 48 hours. lngeatlon Gastrolntestlnal symptoms, Including upset stomach. Skin contact May cause skin Irritation. May cause sensitization or allergic reactions In sensitive Individuals. Eye contact Causes skin and eye Irritation. Indication of any lmmecllate medical attention and special Cnlatment needed Notes for the doctor Treat symptomatlcally. Spedflc trealmentl Treat symptomallcally. 1 s. Flnt-tlghUng ~ures Extinguishing media SUltabla exflngufshlng medla Use fire-extinguishing media suitable for the surrounding fire. Extinguish with alcohol-resistant foam, carbon dioxide or dry powder. Unsuitable extinguishing Do not use water, If avoidable. media Specific hazatdl arising from the hazardous product Specfflc hazards The product Is not flammable. Irritating gases or vapours. Hazardous combustion Harmful gases or vapours. productl Advice for ftreflghters Protective adlons during Stop leak If safe to do so. If leakage cannot be stopped, evacuate area. Move containers from firefighting fire area If It can be done without risk. Special protactive equipment Use air-supplied respirator, gloves and protactlva goggles. fer firefighters Personal precautions, protactive equipment and emergency procedul'IIS Pel"IIOflal p18C8utlona No action shall be taken without appropriate training or Involving any personal risk. Keep unnecessary and unprotected personnel away from the aplNage. Avoid contact with skin, eyes and clothing. Avoid Inhalation of vapours. Follow precaullons for safe handHng described In this safety data sheet Environmental precautions Environmental pracautlona Spillages or uncontrolled discharges Into watercourses must be reported Immediately to the Environmental Agency or other appropriate regulatory body. Methods and material for containment and deaning up Methods for cleanlng up If leakage cannot be stopped, evacoate area. Mova containers from spillage area. Large Spillages: Absorb spillage with sand or other Inert absorbent Collect and place In suitable waste disposal containers and seal securely. Small Spillages: Absorb small quantities with paper towels and evaporate In a safe place. Residues and empty containers should be taken care of as hazardous waste according to local and national provisions. Dispose of waste to ncensed waste d}sposal site In accordance with the requirements of the local Waste Disposal Authority. Reference to other aecllons 11/11 ReYlslon data; 21/0Tli015 Referance to other sections For personal protection, see Section B. For waste dlsposal, see Section 13. See Section 11 for additional lnfonnatlon on health hazards. See Section 12 for addlllonal lnfonnatlon on ecological hazards. 11, Handling and_~ Precautions for aafe handUng Usage precautions For professional users only. Do not handle until all safety precautions have been read and understood. Use only In well-ventilated areas. Protect from moisture. Keep container dry. Container must be kept tightly dosed when not In use. Do not eat, drink or smoke when using this product. Advice on general Do not eat, drink or smoke when using this product. Provide eyewash station. Wash promptly occupational hygiene with soap and water If skin becomes contaminated. Promptly remove any clothing that becomes contaminated. Conditions foraafe lttnge, Including any lncompatlbllltfell Storage precautions Store at temperatures between 4•c and 30"C. Store In tightly-closed, original container In a dry, cool and well-ventilated place. Do not store near heat sources or expose to high temperatures. Store away from the following materials: Acids. Protect from moisture. Staagecfua Chemlcsl storage. Specfflc end use{•) Specific end UH{a) The Identified uses for this product ara detailed In Section 1.2. Appropriate engineering This product Is not to be used under conditions of poor ventllallon. In case of Insufficient controls ventllatlon, wear suitable respiratory equipment Eye/face protection