P280

Hazard statements (CLP)

H301, H302, H314, H315, H318, H335

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

3.2. Mixtures.

TOXICOLOGICAL INFORMATION

open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half appropriate protective gear. For information on risks for the environmental and health, respiratory tract protection, ventilation and personal Tunnel restriction code. Text of risk (R) phrases mentioned in section 2-3 of the sheet: (E) mask or mouthpiece (ref. standard EN 138). protection equipment, refer to the other sections of this sheet. These indications apply for both processing staff and those involved in Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (AMMONIUM BIFLUORIDE; PHOSPHORIC

Contains

An emergency eye washing and shower system must be provided.

2.1 Classification of the substance or mixture

11.1. Information on toxicological effects. ACID) emergency procedures. R22 HARMFUL IF SWALLOWED. In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent Acute effects: ingestion of this product is harmful. Even small amounts of product may cause serious health problems (stomach pain, nausea, R25 TOXIC IF SWALLOWED. Identification. accidental absorption. Conc. %. 1272/2008 (CLP) 6.2. Environmental precautions. sickness, diarrhoea). This product may slightly irritate mucosas, the upper respiratory tract, eyes, and skin. Exposure symptoms may include: Carriage by sea (shipping): R34 CAUSES BURNS. The product is classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or EC Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). The product thus requires a safety datasheet that complies with the The product must not penetrate the sewers, surface water, ground water and neighbouring areas. Dilute the product well with water after sting, cough, asthma, laryngitis, respiratory disorders, headache, nausea and sickness. 1272/2008 (CLP) (and subsequent amendments and supplements). The product thus requires a safety datasheet that complies with the R37/38 IRRITATING TO RESPIRATORY SYSTEM AND SKIN. PHOSPHORIC ACID R41 RISK OF SERIOUS DAMAGE TO EYES. 9. Physical and chemical properties. provisions of EC Regulationn 1907/2006 and subsequent amendments. collection. This product is corrosive and causes abrasions of skin surface, accompanied by rubefaction, warmth and sting. In the most serious cases, IMO Class: provisions of EC Regulationn 1907/2006 and subsequent amendments. CAS. 7664-38-2 35 - 37,5 C R34, Note B 8 UN: 3264 Skin Corr. 1B H314, Note B Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. small vesicles appear, which cause strong sting and pain. Upon contact with eyes, it may cause serious harm, such as cornea opacity, iris Packing Group: Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. EC. 231-633-2 II 6.3. Methods and material for containment and cleaning up. 9.1. Information on basic physical and chemical properties. lesions, irreversible eye coloration. Possible vapours are caustic for the respiratory system and may cause pulmonary edema, whose Label: INDEX. 015-011-00-6 8 For liquid products, suck into a suitable container (made of material not incompatible with the product) and soak up any leaked product with Appearance GENERAL BIBLIOGRAPHY symptoms sometimes arise only after some hours. Exposure symptoms may include: sting, cough, asthma, laryngitis, respiratory disorders, EMS: CITRIC ACID F-A, S-B liquid 1. Directive 1999/45/EC and following amendments headache, nausea and sickness. If swallowed, it may cause mouth, throat and oesophagus burns; sickness, diarrhoea, edema, larynx Marine Pollutant. NO 2.1.1. Regulation 1272/2008 (CLP) and following amendments and adjustments. absorbent inert material (sand, vermiculite, diatomeous earth, Kieselguhr, etc). Collect the majority of the remaining material and deposit in Colour CAS. 77-92-9 8 - 9 Xi R37/38, Xi R41 straw yellow Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335 containers for disposal. For solid products, use spark proof mechanical tools to collect the leaked product and place in plastic containers. If Odour 2. Directive 67/548/EEC and following amendments and adjustments swelling and, consequently, asphyxia. Perforation of the gastro-intestinal tract is also possible. Proper Shipping Name: EC. 201-069-1 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (AMMONIUM BIFLUORIDE; PHOSPHORIC characteristic 3. Regulation (EC) 1907/2006 (REACH) of the European Parliament ACID) Hazard classification and indication: there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Contaminated Odour threshold. Hazard classification and indication: INDEX. - Not available. 4. Regulation (EC) 1272/2008 (CLP) of the European Parliament AMMONIUM BIFLUORIDE material should be disposed of in compliance with the provisions set forth in point 13. pH. AMMONIUM BIFLUORIDE Acute Tox. 4 H302 1 Melting or freezing point. 5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament LD50 (Oral): Transport by air: Skin Corr. 1B H314 T R25, C R34 130 mg/kg Rat Not available. Acute Tox. 3 H301, Skin Corr. 1B H314 6. Regulation (EC) 453/2010 of the European Parliament CAS. 1341-49-7 8 - 9 6.4. Reference to other sections. Initial boiling point. PHOSPHORIC ACID EC. 215-676-4 Not available. 7. The Merck Index. - 10th Edition LD50 (Oral): IATA: 1530 mg/kg Rat 8 UN: 3264 2.1.2. Directive 67/548/EEC and following amendments and adjustments. Any information on personal protection and disposal is given in sections 8 and 13. Boiling range. 8. Handling Chemical Safety INDEX. 009-009-00-4 Not available. Flash point. LC50 (Inhalation): Packing Group: > 0,85 mg/l/1h Rat II > 60 °C. T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = 9. Niosh - Registry of Toxic Effects of Chemical Substances

Hazard pictograms

Evaporation Rate LD50 (Dermal): Label: C 2740 mg/kg Rabbit 8 Not available. 7. Handling and storage. Dangerous for the Environment(N) 10. INRS - Fiche Toxicologique (toxicological sheet) Flammability of solids and gases CITRIC ACID Cargo: Not flammable 7.1. Precautions for safe handling. Lower inflammability limit. 11. Patty - Industrial Hygiene and Toxicology

R-phrase(s)

LD50 (Oral): Packaging instructions: 22-34 3000 mg/kg Rat 855 Not available. Maximum quantity: 30 L The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. Upper inflammability limit. 12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition Pass.: Not available. Before handling the product, consult all the other sections of this material safety data sheet. Do not eat, drink or smoke during use.

ECOLOGICAL INFORMATION

Lower explosive limit. 13. ECHA website The classification of the compound, featuring an extreme pH value, is based on the results of an appropriate validated in-vitro test as set out Packaging instructions: The classification of the compound, featuring an extreme pH value, is based on the results of an appropriate validated in-vitro test as set out 851 Not available. Maximum quantity: 1 L