NITROESTER-CONTAINING EXPLOSIVES (DYNAMITES, BARBARYT)

Hazard statements (CLP)

H201, H300, H310, H330, H373, H412

Code

Statements

H201

Explosive; mass explosion hazard

2.1 Classification of the substance or mixture

2.1.1 Classification of the mixture according to Directive 67/548/EEC E; R 2 T+; R 26/27/28 R 33 R 52-53 2.1.2 Classification of the mixture according to Regulation (EC) No. 1272/2008 Expl. 1.1 H201 Acute Tox. 2 H330 Acute Tox. 1 H310 Acute Tox. 2 H300 STOT RE 2 H373 Aquatic Chronic 3 H412

2.2 Label elements

Below mentioned elements of marking are used only in transport of not elaborated explosive between operations. Note: In accordance with the Regulation of the Minister of Health of 5 March 2009 on the labelling of hazardous substances and hazardous preparations, packages with explosives are not labelled under that regulation but under the ADR regulations. This labelling is discussed in Section 14. - According to EEC Directive 67/548 E – explosive R 2 – Risk of explosion by shock, friction, fire and/or other sources of energy. T+ – very toxic R 26/27/28 – Very toxic by inhalation, in contact with skin and if swallowed. R 33 – Danger of cumulative effects. R 52-53 – Harmful to aquatic organisms; may cause long-term adverse effects in the aquatic environment. Safety advice concerning the mixture (S-phrases): S 1 – Keep locked up. S 20/21 – When using do not eat, drink or smoke. S 35 – This material and its container must be disposed of in a safe way. S 36 – Wear suitable protective clothing. S 41 – In case of fire and/or explosion do not breathe fumes. S 45 – In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). - According to Regulation (EC) No. 1272/2008 Expl. 1.1 - H201 – Explosive; risk of massive explosion. Explosive subcategory 1.1 Acute Tox. 1 - H310 – Fatal in contact with skin. Acute toxicity dermal, category 1 Acute Tox. 2 - H300 – Fatal if swallowed. Acute toxicity oral and H330 – Fatal if inhaled. inhalation, category 2 STOT RE 2 H373 –May cause damage to circulatory system in the Target organ toxicity - repeated consequence of long-term exposure ore repeated Danger exposure, category 2 exposure via inhalation or ingestion. Aquatic Chronic 3 - H412 – Harmful to aquatic organisms, causes long-lasting Poses hazard to aquatic life, effects. category 3

Precautionary statements

P-phrases) P210: – Keep away from heat/sparks/open flames/hot surfaces. No smoking. P270: – Do not eat, drink, or smoke when using this product. P302+P352 – IF ON SKIN Gently wash with plenty of soap and water P370: – In case of fire: Do not breathe fume. P372: – Explosion risk in case of fire. P373: – DO NOT fight fire when fire reaches explosives. P312: – Call a POISON CENTRE or doctor/physician if you feel unwell. P501: – Dispose of contents/container (to) in a safe manner. P101: – If medical advice is needed, have product container or label at hand.

2.3 Other hazards

The mixture is an explosive material decomposing at temperatures exceeding 165°C. Heating and combustion of the material yield highly toxic nitrogen oxides. The product burns gently if in small quantities and in the open air. Combustion of small quantities in enclosed space or combustion of large quantities turns into explosion. Fire may occur also as a secondary effect of detonation.