Note: Ingredients listed on restricted chemical lists
EC/CAS
6786-83-0
Name of the chemical
α,α-Bis[4-(dimethylamino)phenyl]-4 (phenylamino)naphthalene-1-methanol (C.I. Solvent Blue 4) [with ≥ 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)]
Concentration
N/A
EC/CAS
495-54-5
Name of the chemical
Chrysoidin; 4-(Phenylazo)benzol-1,3-diamin (790/2009)
Concentration
N/A
General Information
Revision date
2015-10-02
Product name
INK MA4512 BLACK
1.2.1 Relevant identified uses
Ink for BEROL Toughpoint marker, Permanent marker round & wedge nib
Emergency telephone
0845 4647
Icons in SDS
Company Information
company name
Newell Rubbermaid UK Limited
e-mail address of the competent person responsible for the Safety Data Sheet
Aftersales.SERVICE@newellco.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H302, H314, H336, H341, H411
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
2.1 Classification of the substance or mixture
In compliance with EC regulation No. 1272/2008 and its amendments. Flammable liquid, Category 2 (Flam. Liq. 2, H225). Acute oral toxicity, Category 4 (Acute Tox. 4, H302). Skin corrosion, Category 1B (Skin Corr. 1B, H314). Germ cell mutagenicity, Category 2 (Muta. 2, H341). Specific target organ toxicity (single exposure), Category 3 (STOT SE 3, H336). Hazardous to the aquatic environment - Chronic hazard, Category 2 (Aquatic Chronic 2, H411). In compliance with directives 67/548/EEC, 1999/45/EC and their amendments. Highly flammable (F, R 11). Acute oral toxicity: harmful (Xn, R 22). Serious eye damage (Xi, R 41). Vapours may cause drowsiness and dizziness (R 67). Category 3 mutagen (Xn, R 68 Muta. Cat. 3). Aquatic environmental hazard, chronic toxicity: toxic (N, R 51/53).
2.2 Label elements
In compliance with EC regulation No. 1272/2008 and its amendments.
Hazard pictograms
GHS07 GHS05 GHS09 GHS08 GHS02
Signal word
DANGER
Product definition
603-003-00-0 PROPAN-1-OL EC 291-933-4 ETHYLHEXYL PHOSPHORIC ACID ESTER CAS 8005-02-5 C.I. SOLVENT BLACK 7 CAS 52080-58-7 C.I. SOLVENT VIOLET 8 CAS 495-54-5 C.I. SOLVENT ORANGE 3 CAS 6786-83-0 C.I. SOLVENT BLUE 4
Hazard statements
H225 Highly flammable liquid and vapour. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H341 Suspected of causing genetic defects . H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. Disposal P501 Dispose of contents/container to ...
Prevention
P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240 Ground/bond container and receiving equipment. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER/doctor/... P321 Specific treatment (see ... on this label). P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use... to extinguish. P391 Collect spillage.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.
2.3 Other hazards
The mixture contains substances classified as ‘Substances of Very High Concern' (SVHC) >= 0.1% published by the European CHemicals Agency (ECHA) under article 57 of REACH: http://echa.europa.eu/fr/candidate-list-table The mixture satisfies neither the PBT nor the vPvB criteria for mixtures in accordance with annexe XIII of the REACH regulations EC 1907/2006.