Aflatoxin Multi-Level Controls

Hazard statements (CLP)

H225, H301, H301+H311+H331, H311, H331, H370

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Highly flammable liquid and vapour. Causes damage to organs. Toxic in contact with skin. Toxic if inhaled. Toxic if swallowed

Hazard pictograms

GHS02 GHS06 GHS08

Signal word

Danger

Contains

Methanol

Hazard statements

H225 - Highly flammable liquid and vapour. H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled. H370 - Causes damage to organs.

Precautionary statements

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. P308+P311 - IF exposed or concerned: Call a POISON CENTER or doctor. P321 - Specific treatment (see supplemental first aid instruction on this label).

2.3 Other hazards

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII Component Substance(s) not meeting the PBT criteria of REACH Methanol (67-56-1) regulation, in accordance with Annex XIII Substance(s) not meeting the vPvB criteria of REACH Methanol (67-56-1) regulation, in accordance with Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Flammable liquids, Category 2 H225 Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhalation:dust,mist) Category 3 H331 Specific target organ toxicity – single exposure, Category 1 H370 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Highly flammable liquid and vapour. Causes damage to organs. Toxic in contact with skin. Toxic if inhaled. Toxic if swallowed. 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS02 GHS06 GHS08 Signal word (CLP) : Danger Contains : Methanol Hazard statements (CLP) : H225 - Highly flammable liquid and vapour. H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled. H370 - Causes damage to organs. Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. P308+P311 - IF exposed or concerned: Call a POISON CENTER or doctor. P321 - Specific treatment (see supplemental first aid instruction on this label). 2.3. Other hazards Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII Component Substance(s) not meeting the PBT criteria of REACH Methanol (67-56-1) regulation, in accordance with Annex XIII Substance(s) not meeting the vPvB criteria of REACH Methanol (67-56-1) regulation, in accordance with Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 % SECTION 3: Composition/information on ingredients 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Methanol CAS-No.: 67-56-1 ≥ 50 – < 75 Flam. Liq. 2, H225 substance with national workplace exposure limit(s) EC-No.: 200-659-6 Acute Tox. 3 (Oral), H301 (AT, BE, BG, CY, CZ, DE, DK, EE, ES, FI, FR, GB, EC Index-No.: 603-001-00-X Acute Tox. 3 (Dermal), H311 GI, GR, HR, HU, IE, IT, LT, LU, LV, MT, NL, PT, RO, Acute Tox. 3 (Inhalation), H331 SE, SI, SK, AL, IS, NO, MK, RS, CH, TR); substance STOT SE 1, H370 with a Community workplace exposure limit Specific concentration limits: Name Product identifier Specific concentration limits (%) Methanol CAS-No.: 67-56-1 (3 ≤ C < 10) STOT SE 2; H371 EC-No.: 200-659-6 (10 ≤ C < 100) STOT SE 1; H370 EC Index-No.: 603-001-00-X Full text of H- and EUH-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Call a physician immediately. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a doctor. First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. First-aid measures after eye contact : Rinse eyes with water as a precaution. First-aid measures after ingestion : Rinse mouth. Call a physician immediately. Self protection of the first-aider : First aid workers will be equipped with suitable personal protective equipment. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation : Toxic if inhaled. Symptoms/effects after skin contact : Toxic in contact with skin. Symptoms/effects after eye contact : None under normal conditions. Symptoms/effects after ingestion : Toxic if swallowed. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapour. Explosion hazard : No direct explosion hazard. Hazardous decomposition products in case of fire : Toxic fumes may be released. 5.3. Advice for firefighters Firefighting instructions : Fight fire from safe distance and protected location. Do not enter fire area without proper protective equipment, including respiratory protection. Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Stop leak if safe to do so. Notify authorities if product enters sewers or public waters. Absorb spillage to prevent material damage. For non-emergency personnel Protective equipment : Wear recommended personal protective equipment. Emergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact with skin, eyes and clothing. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures : Evacuate unnecessary personnel. Stop leak if safe to do so. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up For containment : Absorb spilled material with sand or earth. Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Stop leak without risks if possible. Methods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapours may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Use only outdoors or in a well-ventilated area. Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ground/bond container and receiving equipment. Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Storage temperature : 2 – 8 °C Packaging materials : Store always product in container of same material as original container. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters National occupational exposure and biological limit values Methanol (67-56-1) EU - Indicative Occupational Exposure Limit (IOEL) Local name Methanol IOEL TWA 260 mg/m³ 200 ppm Remark