POLYHARD 100 PART A

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

2.1 Classification of the substance or mixture

Regulation (EC) No 1272/2008 Acute toxicity, Inhalative, Category 4 (H332) Skin irritation, Category 2 (H315) Eye irritation, Category 2 (H319) Sensitization of the respiratory airways, Category 1 (H334) Sensitization of the skin, Category 1 (H317) Carcinogenicity, Category 2 (H351) Specific target organ toxicity (single exposure), Category 3 (H335) Specific target organ toxicity (repeated exposure), Category 2 (H373) Directive 67/548/EEC or 1999/45/EC Harmful by inhalation. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. Irritating to eyes, respiratory system and skin.

2.2 Label elements

Danger Regulation (EC) No 1272/2008

Hazardous Ingredients

Diphenylmethanediisocyanate-prepolymer CAS-No.39420-98-9 ___________________________ Revision Date 06.10.2014 ________________ Print Date 07.10.2014 Diphenylmethane-2,4'-diisocyanate Index-No.: 615-005-00-9 diphenylmethane-4,4'-diisocyanate Index-No.: 615-005-00-9

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear protective gloves/ eye protection/ face protection. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Directive 67/548/EEC or 1999/45/EC Labelling as required by the Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4), in accordance with EC Directives: Xn Harmful Diphenylmethanediisocyanate-prepolymer Diphenylmethane-2,4'-diisocyanate EC-Label EC-No.: 227-534-9 diphenylmethane-4,4'-diisocyanate EC-Label EC-No.: 202-966-0

R-phrase(s)

R20 Harmful by inhalation. R36/37/38 Irritating to eyes, respiratory system and skin. R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitization by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

S-phrase(s)

S23 Do not breathe vapour. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

2.3 Other hazards

No information available.