A-24-120 (Stabilizer)

NCFI Polyurethanes

Revision date : 2022-09-11

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

15-40

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

10 - 30

EC/CAS

5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

10 - 30

EC/CAS

26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

1 - 5

EC/CAS

2536-05-2

Name of the chemical

2,2’-Methylenediphenyl diisocyanate

Concentration

<1

General Information

Version

1.0

Revision date

2022-09-11

Product name

A-24-120 (Stabilizer)

1.2.1 Relevant identified uses

Production of polyurethanes

1.2.2. Uses advised against

For industrial/occupational use only

supplier name

NCFI Polyurethanes

Emergency telephone

1-800-424-9300, 1-703-527-3887

Icons in SDS

GHS07 GHS08 M004 M009 M010 M011 M013 M017

Company Information

company name

NCFI Polyurethanes

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

Classification of the substance or mixture GHS US classification Acute toxicity (inhalation:dust,mist) Category 4 Skin corrosion/irritation Category 2 Eye irritation Category 2A Respiratory sensitization, Category 1 H332 Harmful if inhaled H315 Causes skin irritation H319 Causes serious eye irritation H334 May cause an allergy or asthma symptoms or breathing difficulties if inhaled Skin sensitization, Category 1 H317 May cause an allergic skin reaction Specific target organ toxicity – Single exposure, Category 3, H335 May cause respiratory irritation Respiratory tract irritation Specific target organ toxicity (repeated exposure) Category 2 H373 May cause damage to organs (lung/respiratory system) through prolonged or repeated exposure (Inhalation) Full text of H statements : see section 16

2.2 Label elements

GHS US labeling

Signal word

Danger

Hazard statements

H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H334 - May cause an allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation H373 - May cause damage to organs (lung/respiratory system) through prolonged or repeated exposure (Inhalation)

Precautionary statements

P260 - Do not breathe mist. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing must not be allowed out of the workplace. P280 - Wear eye protection, protective clothing, protective gloves. P284 - [In case of inadequate ventilation] wear respiratory protection. P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing. P312 - Call a POISON CENTER, a doctor if you feel unwell. P302+P352 - If on skin: Wash with plenty of soap and water. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P314 - Get medical advice/attention if you feel unwell. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to an approved waste disposal plant.

Other hazards which do not result in classification

None known.

Ingredient(s) with unknown acute toxicity

Not applicable

2.1 Classification of the substance or mixture

GHS US classification Acute toxicity (inhalation:dust,mist) Category 4 H332 Harmful if inhaled Skin corrosion/irritation Category 2 H315 Causes skin irritation Eye irritation Category 2A H319 Causes serious eye irritation Respiratory sensitization, Category 1 H334 May cause an allergy or asthma symptoms or breathing difficulties if inhaled Skin sensitization, Category 1 H317 May cause an allergic skin reaction Specific target organ toxicity – Single exposure, Category 3, H335 May cause respiratory irritation Respiratory tract irritation Specific target organ toxicity (repeated exposure) Category 2 H373 May cause damage to organs (lung/respiratory system) through prolonged or repeated exposure (Inhalation) Full text of H statements : see section 16

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