PERMETHRIN

SECTION 2: Hazards identification

Health and Environmental Harmful if swallowed or inhaled. Irritating to skin. Causes mild eye irritation. Vapors may cause drowsiness and dizziness. May be harmful if swallowed and inhaled. May cause temporary itching, tingling, burning or numbness of exposed skin, called paresthesia. Hazardous Decomposition Products Hazardous decomposition gases may develop in the headspace of containers at normal storage and handling temperatures. Physical Properties

Appearance/Odor

Light beige liquid Aromatic Unusual Fire, Explosion and Reactivity Hazards During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. 3. COMPOSITION/INFORMATION ON INGREDIENTS OSHA ACGIH NTP/IARC/OSHA Material PEL TLV Other Carcinogen Titanium Dioxide 15 mg/m³ TWA (total) 10 mg/m³ TWA Not Established IARC Group 2B Petroleum Solvent Not Established 100 mg/m³ (15-17 No ppm) TWA * Naphthalene (< 5%) 10 ppm TWA 10 ppm TWA (skin) 10 ppm TWA ** See "Toxicity", Sec. 11 Glycerin 15 mg/m³ TWA (total); 5 10 mg/m³ TWA (total) Not Established No mg/m³ TWA (respirable) Lambda-Cyhalothrin (9.48%) Not Established 0.04 mg/m³ TWA No (skin) *** Thiamethoxam (12.60%) Not Established 3 mg/m³ TWA *** No Product Name: ENDIGO ZC Page: 1 Appendix 1 - Page 128 MSDS ** recommended by NIOSH *** Syngenta Occupational Exposure Limit (OEL) Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. Syngenta Hazard Category: D, S 4. FIRST AID MEASURES Have the product container, label or Material Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment. Ingestion: If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so after calling 800-888- 8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Eye Contact: If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Skin Contact: If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Inhalation: If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment advice. Notes to Physician There is no specific antidote if this product is ingested. Treat symptomatically. Skin contact paresthesia effects (itching, tingling, burning or numbness) are transient, lasting up to 24 hours. Treat symptomatically. Contains petroleum distillate - vomiting may cause aspiration pneumonia. Medical Condition Likely to be Aggravated by Exposure None known. 5. FIRE FIGHTING MEASURES Fire and Explosion Flash Point (Test Method): > 216°F Flammable Limits (% in Air): Lower: Not Applicable Upper: Not Applicable Autoignition Temperature: Not Available Flammability: Not Applicable Unusual Fire, Explosion and Reactivity Hazards During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. In Case of Fire Use dry chemical, foam or CO2 extinguishing media. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. Prevent use of contaminated buildings, area, and equipment until decontaminated. Water runoff can cause environmental damage. If water is used to fight fire, dike and collect runoff. 6. ACCIDENTAL RELEASE MEASURES In Case of Spill or Leak Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Cover Product Name: ENDIGO ZC Page: 2 Appendix 1 - Page 129 MSDS commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. HANDLING AND STORAGE Because of its physical properties this material needs to be heated before dispensing. Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Eye Contact: Where eye contact is likely, use chemical splash goggles. Skin Contact: Where contact is likely, wear chemical-resistant gloves (such as barrier laminate or Viton), coveralls, socks and chemical-resistant footwear. Stringent housekeeping measures are necessary to prevent translocation of the material from contaminated work surfaces to uncontaminated surfaces (railings, doors, etc.). Unprotected contact with such translocated material can result in paresthesia effects and possible sensitization (see Section 11). Do not touch unprotected skin areas (face) with contaminated gloves or clothing. Wash thoroughly with soap and water immediately after handling. Inhalation: Avoid breathing air from drum headspace. Use local exhaust ventilation or air-supplied respiratory protection when dispensing heated material to control exposure to lambda-cyhalothrin vapor and hazardous headspace gases. A NIOSH-certified combination air-purifying respirator with an N, P or R 95 or HE class filter and an organic vapor cartridge may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a pressure demand atmosphere-supplying respirator if there is any potential for uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection (for example, during spill response activities). 9. PHYSICAL AND CHEMICAL PROPERTIES Light beige liquid Aromatic Melting Point: Not Applicable Boiling Point: Not Available Specific Gravity/Density: 1.12 g/ml @ 68°F (20°C) pH: 6 - 7 @ 1% w/v Solubility in H2O Lambda-Cyhalothrin : 0.004 mg/l Thiamethoxam: 4.1 g/l @ 77°F (25°C) Vapor Pressure Lambda-Cyhalothrin : 1.5 x 10(-9) mmHg @ 68°F (20°C) Thiamethoxam: 2 x 10(-11) mmHg @ 68°F (20°C) 10. STABILITY AND REACTIVITY Product Name: ENDIGO ZC Page: 3 Appendix 1 - Page 130 Stable under normal use and storage conditions. MSDS Hazardous Polymerization: Will not occur. Conditions to Avoid: None known. Materials to Avoid: None known. Hazardous Decomposition Products: Hazardous decomposition gases may develop in the headspace of containers at normal storage and handling temperatures. Light red to dark red granules Weak Unusual Fire, Explosion and Reactivity Hazards During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. 4. FIRST AID MEASURES Have the product container, label or Material Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment. Ingestion: If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Eye Contact: If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Skin Contact: If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Inhalation: If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment advice. Notes to Physician There is no specific antidote if this product is ingested. Treat symptomatically. Medical Condition Likely to be Aggravated by Exposure None known. 5. FIRE FIGHTING MEASURES Fire and Explosion Flash Point (Test Method): Not Applicable Flammable Limits (% in Air): Lower: % Not Applicable Upper: % Not Applicable Autoignition Temperature: Not Applicable Flammability: Not Applicable Unusual Fire, Explosion and Reactivity Hazards During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. In Case of Fire Use dry chemical, foam or CO2 extinguishing media. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. Prevent use of contaminated buildings, area, and equipment until decontaminated. Water runoff can cause environmental damage. If water is used to fight fire, dike and collect runoff. 6. ACCIDENTAL RELEASE MEASURES In Case of Spill or Leak Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions in Protective Equipment Section. Sweep up material and place in a compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. HANDLING AND STORAGE Product Name: WAKIL XL FUNGICIDE Appendix 1 - Page 136 Page: 2 MSDS or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION, PACKAGING AND USE OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Eye Contact: Where eye contact is likely, use chemical splash goggles. Skin Contact: Where contact is likely, wear chemical-resistant (such as nitrile or butyl) gloves, coveralls, socks and chemical-resistant footwear. For overhead exposure, wear chemical-resistant headgear. Inhalation: A respirator is not normally required when handling this substance. Use effective engineering controls to comply with occupational exposure limits. In case of emergency spills, use a NIOSH approved respirator with any N, R, or P or HE filter. 9. PHYSICAL AND CHEMICAL PROPERTIES Light red to dark red granules Weak Melting Point: Not Available Boiling Point: Not Applicable Specific Gravity/Density: 0.4 - 0.6 g/cm³ pH: 4 - 8 (1% suspension in water) Solubility in H2O Cymoxanil: (1% solution in H2O @ 77°F (25°C)) Fludioxonil: 1.8 mg/l @ 77°F (25°C) Mefenoxam: 26 g/l @ 77°F (25°C) Vapor Pressure Cymoxanil: 6.0 x 10(-7) mmHg @ 77°F (25°C) Fludioxonil: 2.9 x 10(-9) mmHg @ 77°F (25°C) Mefenoxam: 2.5 x 10(-5) mmHg @ 77°F (25°C) 10. STABILITY AND REACTIVITY Stability: Stable under normal use and storage conditions. Hazardous Polymerization: Will not occur. Conditions to Avoid: None known. Materials to Avoid: None known. Hazardous Decomposition Products: Can decompose at high temperatures forming toxic gases. Yellow to brown liquid Weak Unusual Fire, Explosion and Reactivity Hazards During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. 3. COMPOSITION/INFORMATION ON INGREDIENTS OSHA ACGIH NTP/IARC/OSHA Material PEL TLV Other Carcinogen n-Methylpyrrolidone (<= 10%) Not Established 10 ppm TWA **** No Cyproconazole (8.9%) Not Established 0.5 mg/m³ TWA *** No *** Syngenta Occupational Exposure Limit (OEL) **** Recommended by AIHA (American Industrial Hygiene Association) Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. Syngenta Hazard Category: D 4. FIRST AID MEASURES Have the product container, label or Material Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment. Ingestion: If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Product Name: ALTO 100 SL Page: 1 Appendix 1 - Page 141 MSDS present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Skin Contact: If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Inhalation: If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment advice. Notes to Physician There is no specific antidote if this product is ingested. Treat symptomatically. Medical Condition Likely to be Aggravated by Exposure None known. 5. FIRE FIGHTING MEASURES Fire and Explosion Flash Point (Test Method): 268°F Flammable Limits (% in Air): Lower: Not Applicable Upper: Not Applicable Autoignition Temperature: Not Available Flammability: Not Applicable Unusual Fire, Explosion and Reactivity Hazards During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. In Case of Fire Use dry chemical, foam or CO2 extinguishing media. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. Prevent use of contaminated buildings, area, and equipment until decontaminated. Water runoff can cause environmental damage. If water is used to fight fire, dike and collect runoff. 6. ACCIDENTAL RELEASE MEASURES In Case of Spill or Leak Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions in Protective Equipment Section. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. HANDLING AND STORAGE Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION, PACKAGING AND USE OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Eye Contact: Where eye contact is likely, use chemical splash goggles. Product Name: ALTO 100 SL Page: 2 Appendix 1 - Page 142 MSDS socks and chemical-resistant footwear. Inhalation: A combination particulate/ organic vapor respirator may be necessary until effective engineering controls are installed to comply with occupational exposure limits. Use a NIOSH approved respirator with an organic vapor (OV) cartridge or canister with an HE prefilter. Use a self-contained breathing apparatus in cases of emergency spills, when exposure levels are unknown, or under any circumstances where air-purifying respirators may not provide adequate protection. 9. PHYSICAL AND CHEMICAL PROPERTIES Yellow to brown liquid Weak Melting Point: Not Applicable Boiling Point: Not Available Specific Gravity/Density: 1.10 - 1.14 g/cm³ @ 68°F (20°C) pH: 2 - 6 (1% in deionized water) Solubility in H2O Cyproconazole: 360g/l @ 77°F (25°C) Vapor Pressure Cyproconazole: 2.25 x 10(-7) mmHg @ 77°F (25°C) 10. STABILITY AND REACTIVITY Stability: Stable under normal use and storage conditions. Hazardous Polymerization: Will not occur. Conditions to Avoid: None known. Materials to Avoid: None known. Hazardous Decomposition Products: May decompose at high temperatures forming toxic gases.

TOXICOLOGICAL INFORMATION

Acute Toxicity/Irritation Studies (Finished Product) Ingestion: Oral (LD50 Female Rat) : 310.2 mg/kg body weight Dermal: Dermal (LD50 Rat) : > 2000 mg/kg body weight Inhalation: Inhalation (LC50 Rat) : > 2.15 mg/l air - 4 hours Eye Contact: Mildly Irritating (Rabbit) Skin Contact: Moderately Irritating (Rabbit) Skin Sensitization: Not a Sensitizer (Guinea Pig) Reproductive/Developmental Effects Lambda-Cyhalothrin : Not a developmental or reproductive toxicant. Thiamethoxam Developmental Not teratogenic in rats or rabbits Reproductive: No effects on reproduction. Minor increase in a common testis effect in rats at high doses, which did not affect reproduction. When used in accordance with label directions and recommendations in this MSDS, no effects would be expected in humans. Chronic/Subchronic Toxicity Studies Lambda-Cyhalothrin : Reversible paresthesia (abnormal skin sensation). Reversible clinical signs of neurotoxicity in mammals. Thiamethoxam Subchronic Liver effects occurred in rodents only at high dose levels. Not neurotoxic after high acute and subchronic exposure in rats. Carcinogenicity Lambda-Cyhalothrin : No treatment-related tumors in rats or mice. Thiamethoxam: Classified as "not likely to be carcinogenic in humans" based on lifetime studies in mice and rats. Other Toxicity Information In humans, contact with exposed skin may result in temporary itching, tingling, burning or numbness, called paresthesia. The effect may result from splash, aerosol, or hot vapor contact, or transfer to the face from contaminated gloves and hands. The symptoms normally disappear within 24 hours. Face and genital areas are especially susceptible to this effect. Paresthesia involving the face is also known as "subjective facial sensation" or SFS. Toxicity of Other Components Glycerin Test results reported in Section 11 for the final product take into account any acute hazards related to the glycerin in the formulation. Naphthalene (< 5%) Test results reported in Section 11 for the final product take into account any acute hazards related to the naphthalene in the formulation. Chronic overexposure to naphthalene can affect the liver, kidney, respiratory tract and blood. Carcinogen Status: NTP: Anticipated Carcinogen IARC: Group 2B Possible Human Carcinogen Product Name: ENDIGO ZC Page: 4 Appendix 1 - Page 131 MSDS Inhalation of vapors at high concentrations can cause central nervous system effects (dizziness, headache), irritation to eyes or respiratory tract. Titanium Dioxide Titanium dioxide is listed as an IARC Group 2B (Possibly Carcinogenic to Humans). Prolonged exposure causes respiratory irritation and may lead to pulmonary fibrosis. Target Organs Active Ingredients Lambda-Cyhalothrin : Liver, nervous system Thiamethoxam: Liver Inert Ingredients Glycerin: Not Applicable Naphthalene: Liver, kidney, respiratory tract, blood Petroleum Solvent: Respiratory tract, stomach, liver, thyroid, urinary bladder, CNS, skin Titanium Dioxide: Lung Acute Toxicity/Irritation Studies (Finished Product) Ingestion: Slightly Toxic Oral (LD50 Rat) : > 2,000 mg/kg body weight Dermal: Slightly Toxic Dermal (LD50 Rat) : > 2,000 mg/kg body weight Inhalation: Practically Non-Toxic Inhalation (LC50 Rat) : > 2.56 mg/l air - 4 hours Eye Contact: All irritation cleared by day 7 (Rabbit). Product Name: WAKIL XL FUNGICIDE Appendix 1 - Page 137 Page: 3 Slightly Irritating (Rabbit) MSDS Skin Sensitization: Not a Sensitizer (Guinea Pig) Reproductive/Developmental Effects Cymoxanil: No evidence of reproductive or developmental toxicity below levels that produced other toxic effects in adult animals. Evidence of genetic damage in mammalian cell cultures but not in animal tests. Fludioxonil: Delayed development at doses causing maternal toxicity. Mefenoxam: None observed. Chronic/Subchronic Toxicity Studies Cymoxanil: Ingestion studies have shown decreased organ weights, degeneration of the nervous system, pathological changes in organs, altered hematology, weakness and increased mortality. Fludioxonil: Liver and kidney toxicity at high dose levels. Mefenoxam: Liver effects at high dose animal tests. Carcinogenicity Cymoxanil: No evidence of carcinogenicity. Fludioxonil: Marginal increase (7%) of liver tumors (female, rats: 3,000 ppm); Within historical control range (1 to 10%). Mefenoxam: None observed. Other Toxicity Information None Toxicity of Other Components Talc Limited potential for respiratory disease. Titanium Dioxide Titanium dioxide is listed as an IARC (Group 3) carcinogen not classifiable as human carcinogen (No Data Available) with limited animal evidence. Prolonged exposure causes respiratory irritation and may lead to pulmonary fibrosis. Target Organs Active Ingredients Cymoxanil: Eye, skin, nervous system, heart, liver, blood, reproductive system Fludioxonil: Liver, kidney Mefenoxam: Liver Inert Ingredients Talc: Respiratory tract Titanium Dioxide: Lung Acute Toxicity/Irritation Studies (Finished Product) Ingestion: Oral (LD50 Rat) : > 2000 mg/kg body weight Dermal: Dermal (LD50 Rat) : > 4000 mg/kg body weight Inhalation: Inhalation (LC50 Rat) : > 5.0 mg/l air - 4 hours Eye Contact: Non-Irritating (Rabbit) Skin Contact: Non-Irritating (Rabbit) Skin Sensitization: Not a Sensitizer (Guinea Pig) Reproductive/Developmental Effects Cyproconazole: Maternal and fetal toxicity were observed at high dose levels (rats). Chronic/Subchronic Toxicity Studies Cyproconazole: Liver enlargements and decreased body weight (mice). Liver damage in rats and dogs. Carcinogenicity Cyproconazole: Liver tumors (mice only). Other Toxicity Information There are indications of developmental toxic effects from reproduction studies with cyproconazole. Product Name: ALTO 100 SL Page: 3 Appendix 1 - Page 143 MSDS Toxicity of Other Components n-Methylpyrrolidone (<= 10%) May cause respiratory tract irritation. Repeated or prolonged exposure may cause drying and cracking of the skin. Target Organs Active Ingredients Cyproconazole: Liver Inert Ingredients n-Methylpyrrolidone: Eye, skin Acute Oral Toxicity. . . . . . . . . . . .: Male/Female Combined Rat: LD50: >5,050 mg/kg Acute Dermal Toxicity. . . . . . . . . .: Male/Female Combined Rat: LD50: > 2,000 mg/kg 3 Appendix 1 - Page 148 MSDS Acute Inhalation Toxicity. . . . . . . Male/Female Combined Rat LC50 4-hr exposure to dust: > 2.74 mg/1 (actual) Male/Female Combined Rat 1-hr exposure to dust (extrapolated from 4-hr LC50) > 10.96 mg/1 (actual). Skin Irritation. . . . . . . . . . . . . . . . Rabbit slight dermal irritant Eye Irritation. . . . . . . . . . . . . . . . . Rabbit Mild irritation to the cornea and conjunctiva was observed with all irritation clearing within 7 days post-treatment. Sensitization. . . . . . . . . . . . . . . . . Guinea pig Not a dermal sensitizer. Sub-Chronic Toxicity. . . . . . . . . .: In a 28-day dermal toxicity study in rats, trifloxystrobin was tolerated without local effects at doses up to and including the limit dose of 1000 mg/kg/day. Systemic effects were observed in males at the limit dose and included increased organ weights (liver and kidney). Chronic Toxicity. . . . . . . . . . . . . .: In chronic toxicity studies in mice and dogs, the major primary target organ appears to be the liver following dietary administration of trifloxystrobin. Liver effects were not seen in a chronic toxicity rat study with trifloxystrobin. Assessment Carcinogenicity. . .: Trifloxystrobin did not cause any treatment-related increase in general tumor incidence, any elevated incidence of rare tumors, or shortened time to the development of palpable or rapidly lethal tumors in an 18- month mouse and a 24-month rat study. ACGIH NTP IARC OSHA None None None None Reproductive & Developmental Toxicity. . . . . . . . REPRODUCTION In a two generation reproduction study using rats, trifloxystrobin was not a primary reproductive toxicant. DEVELOPMENTAL TOXCITY: In a developmental toxicity stud- ies using rats and rabbits, trifloxystrobin was not a primary developmental toxicant. Mutagenicity. . . . . . . . . . . . . . . . .: Trifloxystrobin has been tested for its potential to induce gene mutation and chromosomal changes in 5 different test systems. Taken collectively, these studies demonstrate trifloxystrobin is not genotoxic or mutagenic. 12. Ecological And Ecotoxicological Information Environmental Precautions. . . . .: This pesticide is toxic to fish and aquatic invertebrates. Do not apply directly to water, to areas where surface water is present or to intertidal area below the mean high water mark. Drift and runoff may be hazardous to aquatic organisms in neighboring areas. Do not contaminate water when disposing of equipment washwater or rinsate. Environmental Fate. . . . . . . . . . . : Ground Water Advisory: Several trifloxystrobin degradates have properties and char- acteristics associated with chemicals detected in ground water. The use of this chemical in areas where soils are 4 Appendix 1 - Page 149 MSDS permeable, particularly where the water table is shallow, may result in ground water contamination.

ECOLOGICAL INFORMATION

Ecotoxicity Effects Lambda-Cyhalothrin : Fish (Rainbow Trout) 96-hour LC50 0.19 ppb Bird (Mallard Duck) LD50 Oral > 3950 mg/kg Invertebrate (Water Flea) 48-hour EC50 0.04 ppb Thiamethoxam: Fish (Rainbow Trout) 96-hour LC50 > 100 ppm Bird (Mallard Duck) LD50 Oral 576 mg/kg Invertebrate (Daphnia Magna) 48-hour EC50 > 106 ppm Green Algae 4-day EC50 > 97 ppm Environmental Fate Lambda-Cyhalothrin : The information presented here is for the active ingredient, lambda-cyhalothrin. Not persistent in soil or water. Immobile in soil. Sinks in water (after 24 h). Thiamethoxam: The information presented here is for the active ingredient, thiamethoxam. Not persistent in soil. Stable in water. Moderate mobility in soil. Floats in water (after 24 h). 13. DISPOSAL CONSIDERATIONS Summary of Effects Cymoxanil: Very toxic to algae. Fludioxonil: Practically nontoxic to birds and bees, but highly toxic to aquatic invertebrates and fish. Mefenoxam: Practically non-toxic to aquatic organisms and wildlife. Eco-Acute Toxicity Mefenoxam: Bees LC50/EC50 > 25 ug/bee Invertebrates (Water Flea) LC50/EC50 > 113 ppm Product Name: WAKIL XL FUNGICIDE Appendix 1 - Page 138 Page: 4 MSDS Birds (8-day dietary - Bobwhite Quail) LC50/EC50 5,620 ppm Fludioxonil: Bees LC50/EC50 > 25 ug/bee Invertebrates (Water Flea) LC50/EC50 0.90 ppm Fish (Trout) LC50/EC50 0.47 ppm Fish (Bluegill) LC50/EC50 0.74 ppm Birds (8-day dietary - Bobwhite Quail) LC50/EC50 > 5,200 ppm Birds (8-day dietary - Mallard Duck) LC50/EC50 > 5,200 ppm Cymoxanil: Rainbow Trout 96-hour LC50 61 mg/l Bluegill Sunfish 96-hour LC50 29 mg/l Bobwhite Quail Oral LD50 >2,250 mg/kg Mallard Oral LD50 >2,250 mg/kg Bobwhite 8-day Dietary LC50 >5,620 ppm Mallard 8-day Dietary LC50 >5,620 ppm Eco-Chronic Toxicity Mefenoxam: Not Available Fludioxonil: Fish (Fathead minnow) Early Life Stage MATC 0.028 mg/l Invertebrate (Daphnia Magna) Life Cycle MATC 0.025 mg/l Mallard Reproduction NOEC 700 ppm Bobwhite Reproduction NOEC 125 ppm Cymoxanil: Not Available Environmental Fate Cymoxanil: The information presented here is for the active ingredient, cymoxanil. In lab soils, DT50 0.75 - 1.5 d (5 soils, pH range 5.7 - 7.8, o.m. 0.8 - 3.5%). In the field, DT50 (bare soil) 0.9 - 9 d. In aquatic studies, DT50 <1 d. Koc 39 - 250. Cymoxanil is mobile, adsorption Freundlich K 0.29 to 2.86 in four soil types. Fludioxonil: The information presented here is for the active ingredient, fludioxonil. Does not bioaccumulate. Persistent in soil. Stable in water. Low mobility in soil. Sinks in water (after 24 h). Mefenoxam: The information presented here is for the active ingredient, mefenoxam. Does not bioaccumulate. Not persistent in soil or water. Moderate mobility in soil. Mixes/sinks (after 24 h). 13. DISPOSAL CONSIDERATIONS Summary of Effects Cyproconazole: Very toxic to aquatic life. Ecotoxicity Effects Cyproconazole: Fish (Rainbow Trout) 96-hour LC50 19 ppm Green Algae 5-day EC50 0.026 ppm Invertebrate (Water Flea) Daphnia magna 48-hour EC50 26 ppm Bird (Bobwhite Quail) 14-day LD50 150 mg/kg Environmental Fate Cyproconazole: The information presented here is for the active ingredient, cyproconazole. Low bioaccumulation potential. Stable in soil and water. Low to moderate mobility in soil. Floats in water (after 24 h). 13. DISPOSAL CONSIDERATIONS

Disposal

Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations. Characteristic Waste: Not Applicable Listed Waste: Not Applicable 14. TRANSPORT INFORMATION Product Name: ENDIGO ZC Page: 5 Appendix 1 - Page 132 DOT Classification MSDS Ground Transport - NAFTA Containers < 450 liters: Not regulated. Containers > 450 liters: Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Lambda-Cyhalothrin) Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations. Characteristic Waste: Not Applicable Listed Waste: Not Applicable 14. TRANSPORT INFORMATION DOT Classification Ground Transport - NAFTA Not regulated. Air Transportation - Domestic and International Not regulated. B/L Freight Classification Fungicides, NOI, O/T Poison Product Name: WAKIL XL FUNGICIDE Appendix 1 - Page 139 Page: 5 MSDS None 15. REGULATORY INFORMATION EPCRA SARA Title III Classification Section 311/312 Hazard Classes: Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations. Characteristic Waste: Not Applicable Listed Waste: Not Applicable 14. TRANSPORT INFORMATION DOT Classification Ground Transport - NAFTA Not regulated. Air Transport - NAFTA Not regulated. B/L Freight Classification Fungicides, NOIBN Comments Water Transport - International Not regulated. Air Transport - International Product Name: ALTO 100 SL Page: 4 Appendix 1 - Page 144 MSDS 15. REGULATORY INFORMATION EPCRA SARA Title III Classification Section 311/312 Hazard Classes: Considerations Additional inform. : Trifloxystrobin is rapidly adsorbed and de-activated in soil. Observe all federal state and local environmental regulations. Permitted for hazardous waste. 14. Transport Information Not applicable. 15. Regulatory Information Not applicable.

Hazard categories

Class 9 Identification Number: UN 3082 Packing Group: PG III Comments Water Transport - International Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Lambda-Cyhalothrin), Marine Pollutant Class 9 Identification Number: UN 3082 Packing Group: PG III Air Transport - International Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Lambda-Cyhalothrin) Class 9 Identification Number: UN 3082 Packing Group: PG III Note: This product is currently not regulated for airfreight within the NAFTA region. However, effective 01/01/2011 the above classification must be used. 15. REGULATORY INFORMATION EPCRA SARA Title III Classification Section 311/312 Hazard Classes:

Health hazards

Section 313 Toxic Chemicals: Naphthalene (< 5%) (CAS No. 91-20-3) California Proposition 65 Not Applicable CERCLA/SARA 302 Reportable Quantity (RQ) Report product spills > 1,250 gal. (based on naphthalene [RQ = 100 lbs.] content in the formulation) RCRA Hazardous Waste Classification (40 CFR 261) Not Applicable TSCA Status Exempt from TSCA, subject to FIFRA

Further information

NFPA Hazard Ratings HMIS Hazard Ratings 0 Minimal Health: 2 Health: 2 1 Slight Flammability: 1 Flammability: 1 2 Moderate Instability: 0 Reactivity: 0 3 Serious 4 Extreme For non-emergency questions about this product call: 1-800-334-9481 Original Issued Date: 3/16/2007 Revision Date: 12/9/2010 Replaces: 9/17/2010 Product Name: ENDIGO ZC Page: 6 Appendix 1 - Page 133 MSDS The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. End of MSDS Product Name: ENDIGO ZC Page: 7 Appendix 1 - Page 134 Syngenta Crop Protection, Inc. Post Office Box 18300 Greensboro, NC 27419 1. PRODUCT IDENTIFICATION Product Name: WAKIL XL FUNGICIDE Product No.: A9873C EPA Signal Word: Caution Active Ingredient(%): Cymoxanil (10.0%) CAS No.: 57966-95-7 Chemical Name: 2-Cyano-N-[(ethylamino)carbonyl]-2-(methyloxyimino)acetamide Chemical Class: Fungicide Active Ingredient(%): Fludioxonil (5.0%) CAS No.: 131341-86-1 Chemical Name: 4-(2,2-difluoro-1,3-benzodioxol-4-yl)-1H-pyrrole-3-carbonitrile Chemical Class: Substituted Benzodioxalcarbonitrile Fungicide Active Ingredient(%): Mefenoxam (17.5%) CAS No.: 70630-17-0 Chemical Name: (R,S)-2-[(2,6-dimethylphenyl)-methoxyacetylamino]-propionic acid methyl ester Chemical Class: Phenylamide Fungicide EPA Registration Number(s): Not Applicable Section(s) Revised: 2, 8, 15 In Case of Emergency, Call 1-800-888-8372 2. COMPOSITION/INFORMATION ON INGREDIENTS OSHA ACGIH NTP/IARC/OSHA Material PEL TLV Other Carcinogen Titanium Dioxide 15 mg/m³ TWA (total) 10 mg/m³ TWA Not Established IARC Group 3 Talc 20 mppcf (containing 2 mg/m³ (respirable; <1% 2 mg/m³ (respirable) IARC Group 3 <1% quartz) TWA crystalline silica) TWA TWA ** Mefenoxam (17.5%) Not Established 10 mg/m³ TWA*** No Fludioxonil (5.0%) Not Established 10 mg/m³ TWA*** No Cymoxanil (10.0%) Not Established 2mg/m³, 8 & 12 Hr. No TWA* * recommended by manufacturer ** recommended by NIOSH *** Syngenta Occupational Exposure Limit (OEL) Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. Syngenta Hazard Category: B Symptoms of Acute Exposure May cause eye and skin irritation. Hazardous Decomposition Products Can decompose at high temperatures forming toxic gases. Product Name: WAKIL XL FUNGICIDE Appendix 1 - Page 135 Page: 1 MSDS NFPA Hazard Ratings HMIS Hazard Ratings 0 Minimal Health: 1 Health: 1 1 Slight Flammability: 1 Flammability: 1 2 Moderate Instability: 0 Reactivity: 0 3 Serious 4 Extreme For non-emergency questions about this product call: 1-800-334-9481 Original Issued Date: 06/04/2003 Revision Date: 02/06/2006 Replaces: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. RSVP# : SCP-955-00394B End of MSDS Product Name: WAKIL XL FUNGICIDE Appendix 1 - Page 140 Page: 6 Syngenta Crop Protection, Inc. Post Office Box 18300 Greensboro, NC 27419 1. PRODUCT IDENTIFICATION Product Name: ALTO 100 SL Product No.: A9898A EPA Signal Word: Caution Active Ingredient(%): Cyproconazole (8.9%) CAS No.: 94361-06-5 & 94361-07-6 Chemical Name: [Alpha-(4-Chlorophenyl)-alpha-(1-cyclopropylethyl)-1H-1,2,4-triazole-1-ethanol Chemical Class: Triazol Derivative Fungicide EPA Registration Number(s): 100-1226 Section(s) Revised: 1, 2, 8 In Case of Emergency, Call 1-800-888-8372 Health and Environmental May be harmful if swallowed or in contact with skin. May cause respiratory tract irritation. Hazardous Decomposition Products May decompose at high temperatures forming toxic gases. Physical Properties NFPA Hazard Ratings HMIS Hazard Ratings 0 Minimal Health: 2 Health: 2 1 Slight Flammability: 1 Flammability: 1 2 Moderate Instability: 0 Reactivity: 0 3 Serious 4 Extreme For non-emergency questions about this product call: 1-800-334-9481 Original Issued Date: 4/7/2006 Revision Date: 5/30/2008 Replaces: 4/20/2006 The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. End of MSDS Product Name: ALTO 100 SL Page: 5 Appendix 1 - Page 145 Manufacturer/information service: ZHEJIANG RAYFULL CHEMICALS CO.,LTD ADD: NO.113 PUXING ROAD, PUZHOU INDUSTRIAL PARK, LONGWAN DISTRICT, WENZHOU ZHEJIANG P.R. CHINA Tel: +86-577-88905587 Fax: +86-577-88905567 Email: info@rayfull.com sales@rayfull.com 1. Chemical Product Identification Product Name: Trifloxystrobin Molecular Formula: C20H19F3N2O4 Molecular Weight: 408.37 Structural Formula: Chemical Name: Benzeneacetic acid, (E,E)- alpha-(methoxylmino)-2-((((1-(3-trifluoromethyl) phenyl)ethylidene)amino)oxy)methy)-,methyl ester Form: powder Color: white Odor: odourless CAS No.: 141517-21-7 2. Composition / Information On Ingredients Composition CAS No. All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is necessary to ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS. 5

Acute Health Hazards

Section 313 Toxic Chemicals: Not Applicable California Proposition 65 Not Applicable CERCLA/SARA 302 Reportable Quantity (RQ) None RCRA Hazardous Waste Classification (40 CFR 261) Not Applicable TSCA Status Exempt from TSCA, subject to FIFRA Section 313 Toxic Chemicals: n-Methylpyrrolidone (<= 10%) (CAS No. 872-50-4) California Proposition 65 WARNING This product contains a chemical (n-Methylpyrrolidone) known to the State of California to cause cancer and birth defects or other reproductive harm. CERCLA/SARA 302 Reportable Quantity (RQ) None RCRA Hazardous Waste Classification (40 CFR 261) Not Applicable TSCA Status Exempt from TSCA, subject to FIFRA

Contains

Trifloxystrobin 141517-21-7 50 Other ingredients 50 1 Appendix 1 - Page 146 MSDS Inhalation: Cough. Laboured breathing. Sore throat. Skin contact: It caused some sensitisation Eyes contact: It cause eye irritation if it is not rinsed out Ingestion: May be fatal if swallowed. 4. First Aid Measures Inhalation: Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Skin contact: Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison controlcenter immediately. Eyes contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye Call a physician or poison control center immediately. Ingestion: Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended 5. Fire-Fighting Measures Fire and explosion: Flash Point: 593.6F Extinguishing media: Dry chemical, Foam, Carbon dioxide (CO2), Water. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing Evacuate personnel to safe areas. Avoid contact with spilled product or contaminated surfaces. Contain the spread of the fire-fighting media. Keep out of smoke. Do not allow run-off from fire fighting to enter drains or water courses. After fire is extinguished, do not turn on any ignition source until the area is determined to be free from explosion or fire hazard. 6. Accidental Release Measures Consult an expert! Collect leaking and spilled liquid in sealed containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Sweep spilled substance into dry, sealed containers. Carefully collect remainder, then remove to safe place (extra personal protection: P3 filter respirator for toxic particles). 7. Handling And Storage 2 Appendix 1 - Page 147 MSDS Handling: Always practice good industrial hygiene;handle with care ,avoid personal contact.Do not get into eyes or skin,do not breathe mist or vaporof product.do not swallow.wash hands with soap and water and rinse after handling product.shower after each shift.wash all work clothing and completely clean all PPE after each shift.

Storage

Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Store in original container. Store in a place accessible by authorized persons only. 8. Exposure Controls/Personal Protection Repeated or prolonged contact with skin may cause dermatitis, abnormalities and loss of fingernails. Lungs may be affected by repeated or prolonged exposure to the aerosol. General Protection Keep and wash PPE separately from other laundry. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables use detergent and warm/tepid water. Eye/Face Protection Safety glasses with side-shields Hand protection Chemical resistant nitrile rubber gloves Body Protection Wear long-sleeved shirt and long pants and shoes plus socks. Coveralls Respiratory protection When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations 9. Physical and Chemical Properties Appearance: Grey to Beige Solid granules Melting / Freezing Point : 70.9° C Vapor pressure: 2.56E(-11) pH: 9-11 (1% suspension in water) 10. Stability and Reactivity stable to hydrolysis and is demonstrated to be thermally stable for 2 years The substance decomposes under influence of UV light producing toxic and corrosive fumes including nitrogen oxides, hydrogen chloride. Reacts with strong oxidants. Reacts with bases (hydrolysis). Unformulated products are corrosiveto common metals. Inactivated by inert clays and by anionic surfactants.