BATHWORKS DIY Refinishing Kit - Part B Base Hardener

Hazard statements (CLP)

H226, H317, H334, H412

Code

Statements

H226

Flammable liquid and vapour

2.1 Classification of the substance or mixture

Flam. Liq. 3; H226 Flammable liquid and vapor. Skin Sens. 1; H317 May cause an allergic skin reaction. Resp. Sens. 1; H334 May cause allergy or asthma symptoms of breathing difficulties if inhaled. Aquatic Chronic 3; H412 Harmful to aquatic life with long lasting effects.

2.2 Label elements

Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows. Danger H226 Flammable liquid and vapor. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms of breathing difficulties if inhaled. H412 Harmful to aquatic life with long lasting effects. P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P260 Do not breathe mist / vapors / spray. P261 Avoid breathing dust / fume / gas / mist / vapors / spray. P262 Do not get in eyes, on skin, or on clothing. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. P285 In case of inadequate ventilation wear respiratory protection. P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+352 IF ON SKIN: Wash with soap and water. P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P331 Do NOT induce vomiting. P333+313 If skin irritation or a rash occurs: Get medical advice/attention. P342+311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor / physician. P363 Wash contaminated clothing before reuse. P370 In case of fire:. P403+233 Store in a well ventilated place. Keep container tightly closed.

HMIS® ratings

Health: 3 Flammability: 3 Reactivity: 0 3. Ingredient Composition This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Notes Hexamethylene diisocyanate homopolymer 75 - 100 Skin Sens. 1;H317 [1] CAS Number: 0028182-81-2 BUTYL ACETATE 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0000123-86-4 STOT SE 3;H336 Petroleum naphtha 1.0 - 10 Asp. Tox. 1;H304 [1] CAS Number: 0064742-95-6 Aquatic Chronic 2;H411 (Self Classification) Hexamethylene diisocyanate 0.10 - 1.0 Acute Tox. 3;H331 [1][2] CAS Number: 0000822-06-0 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Resp. Sens. 1;H334 Skin Sens. 1;H317 [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vPvB-substance. *The full texts of the phrases are shown in Section 16. 4. First Aid 4.1. Description of first aid measures General Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean or destroy contaminated shoes. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin In case of contact, immediately flush skin with soap and plenty of water. Get medical attention immediately. Ingestion If swallowed, immediately contact Poison Control Center at 1-800-854-6813. DO NOT induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to an unconscious person 4.2. Most important symptoms and effects, both acute and delayed Overview NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Avoid contact with eyes, skin and clothing. May cause allergic respiratory reaction. Inhalation Harmful if inhaled. May cause lung injury. Causes nose and throat irritation. Vapors may affect the brain or nervous system causing dizziness, headache or nausea Eyes Causes severe eye irritation. Avoid contact with eyes Skin Causes skin irritation. May be harmful if absorbed through the skin Ingestion Harmful if swallowed. May cause abdominal pain, nausea, vomiting, diarrhea, or drowsiness. Chronic effects None known Tub Refinishing Inc., DBA Munro Products 5. Firefighting 5.1. Extinguishing CAUTION: This product has a very low flashpoint. Use of water spray when fighting fire media may be inefficient. CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more effective. SMALL FIRES: Use dry chemical, CO2, water spray or regular foam. LARGE FIRES: Use water spray, fog, or regular foam. Do not use straight streams. Move containers from fire area if you can do so without risk. 5.2. Special hazards HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. arising from the Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and substance or mixture flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. 5.3. Advice for fire- Cool closed containers exposed to fire by spraying them with water. Do not allow run off fighters water and contaminants from fire fighting to enter drains or water courses. 5.4. ERG Number 128 6. Accidental Release 6.1. Personal precautions, ELIMINATE ALL IGNITION SOURCES (no smoking, flares, sparks or flames protective equipment and in immediate area). Use only non-sparking equipment to handle spilled material emergency procedures and absorbent. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to containers. Use non-sparking tools to collect absorbed material. 6.2. Environmental precautions Do not allow spills to enter drains or watercourses. 6.3. Methods and material for CALL CHEMTREC at (800)-424-9300 for emergency response. Isolate spill or containment and cleaning up leak area immediately for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. LARGE SPILLS: Consider initial downwind evacuation for at least 300 meters (1000 feet). 7. Handling & Storage 7.1. Precautions for safe handling Handling Vapors may cause flash fire or ignite explosively. In Storage Keep away from heat, sparks and flame 7.2. Conditions for safe Store between 40-100F (4-38C). storage, including any Avoid contact with eyes, skin and clothing. incompatibilities Strong oxidizing agents. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone 7.3. Specific end use(s) Close container after each use. Wash thoroughly after handling. Prevent build-up of vapors by opening all windows and doors to achieve cross- ventilation. 8. Exposure Controls & Personal Protection 8.1. Control parameters CAS No. Ingredient Source Value Tub Refinishing Inc., DBA Munro Products 0000123-86-4 BUTYL ACETATE OSHA 150 ppm TWA; 710 mg/m3 TWA 200 ppm STEL; 950 mg/m3 STEL ACGIH 150 ppm TWA 200 ppm STEL NIOSH 150 ppm TWA; 710 mg/m3 TWA 200 ppm STEL; 950 mg/m3 STEL 1700 ppm IDLH (10% LEL) Supplier No Established Limit OHSA, CAN 150 ppm TWA 200 ppm STEL Mexico 150 ppm TWA LMPE-PPT; 710 mg/m3 TWA LMPE-PPT 200 ppm STEL [LMPE-CT]; 950 mg/m3 STEL [LMPE-CT] Brazil No Established Limit 0000822-06-0 Hexamethylene diisocyanate OSHA No Established Limit ACGIH 0.005 ppm TWA NIOSH 0.005 ppm TWA; 0.035 mg/m3 TWA 0.020 ppm Ceiling (10 min); 0.140 mg/m3 Ceiling (10 min) Supplier No Established Limit OHSA, CAN 0.005 ppm TWA (designated substances regulation, listed under Isocyanates, organic compounds); 0.02 ppm Ceiling (designated substances regulation, listed under Isocyanates, organic compounds0.005 ppm TWA (listed under Isocyanates, organic compounds (Hexamethylene diisocyanate (HDI))); Mexico No Established Limit Brazil No Established Limit 0028182-81-2 Hexamethylene diisocyanate OSHA No Established Limit homopolymer ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, CAN No Established Limit Mexico No Established Limit Brazil No Established Limit 0064742-95-6 Petroleum naphtha OSHA No Established Limit ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, CAN No Established Limit Mexico No Established Limit Brazil No Established Limit Health Data CAS No. Ingredient Source Value 0000123-86-4 BUTYL ACETATE NIOSH Mucous membrane and eye irritation; high concentrations cause nervous system effects in animals 0000822-06-0 Hexamethylene diisocyanate NIOSH Respiratory effects and sensitization pulmonary irritation (Listed under 0028182-81-2 Hexamethylene NIOSH No Established Limit diisocyanate homopolymer Tub Refinishing Inc., DBA Munro Products 0064742-95-6 Petroleum naphtha NIOSH No Established Limit Carcinogen Data CAS No. Ingredient Source Value 0000123-86-4 BUTYL ACETATE OSHA Select Carcinogen: No NTP Known No; Suspected No IARC Group 1 No; Group 2a No; Group 2b No; Group 3 No; Group 4: No; 0000822-06-0 Hexamethylene OSHA Select Carcinogen: No diisocyanate NTP Known No; Suspected No IARC Group 1 No; Group 2a No; Group 2b No; Group 3 No; Group 4: No; 0028182-81-2 Hexamethylene OSHA Select Carcinogen: No diisocyanate NTP Known No; Suspected No homopolymer IARC Group 1 No; Group 2a No; Group 2b No; Group 3 No; Group 4: No; 0064742-95-6 Petroleum naphtha OSHA Select Carcinogen: No NTP Known No; Suspected No IARC Group 1 No; Group 2a No; Group 2b No; Group 3 No; Group 4: No; 8.2. Exposure Controls Respiratory Select equipment to provide protection from the ingredients listed in Section 3 of this document. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates dust, vapor, or mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. FOR USERS OF 3M RESPIRATORY PROTECTION ONLY: For information and assistance on 3M occupational health and safety products, call OH&ESD Technical Service toll free in U.S.A. 1-800-243- 4630, in Canada call 1-800-267-4414. Please do not contact these numbers regarding other manufacturer's respiratory protection products. 3M does not endorse INDIVIDUALS WITH LUNG OR BREATHING PROBLEMS OR PRIOR REACTION TO ISOCYANATES MUST NOT BE EXPOSED TO VAPOR OR SPRAY MIST. Do not breathe vapor or spray mist. Wear an appropriate, properly fitted respirator (NIOSH approved) during and after application unless air monitoring demonstrates vapor/mist levels are below applicable limits. A supplied air respirator (either positive pressure or continous flow type) is required. Follow manufacturer's directions for respirator use and observe requirements specified in 29 CFR 1910.134. Eyes Avoid contact with eyes. Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, safety glasses, chemical goggles, and/or head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Skin Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, protective gloves, apron, boots, head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Engineering Controls Depending on the site-specific conditions of use, provide adequate ventilation. Other Work Practices Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use good personal hygiene practices. Wash hands before eating, drinking, using toilet facilities, etc. Promptly remove Tub Refinishing Inc., DBA Munro Products soiled clothing and wash clothing thoroughly before reuse. Shower after work using plenty of soap and water. 9. Physical & Chemical Properties Appearance Colored Liquid Odour threshold Not Measured pH No Established Limit Melting point / freezing point Not Measured Initial boiling point and boiling 145 (C) 293 (F) range Flash Point 27 (C) 80 (F) Evaporation rate (Ether = 1) Not Measured Flammability (solid, gas) Not Applicable Upper/lower flammability or Lower Explosive Limit: 0.6 explosive limits Upper Explosive Limit: No Established Limit vapor pressure (Pa) Not Measured Vapor Density Heavier than air Specific Gravity 1.12 Partition coefficient n-octanol/water Not Measured (Log Kow) Auto-ignition temperature Not Measured Decomposition temperature Not Measured Viscosity (cSt) No Established Limit VOC % Refer to the Technical Data Sheet or label where information is available. Other information No further information 10. Stability & Reactivity 10.1. Reactivity No data available 10.2. Chemical stability This product is stable and hazardous polymerization will not occur. Not sensitive to mechanical impact. Excessive heat and fumes generation can occur if improperly handled. 10.3. Possibility of hazardous No data available reactions 10.4. Conditions to avoid No data available 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or products flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. 11. Toxicological Information Acute toxicity NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be Tub Refinishing Inc., DBA Munro Products harmful or fatal. Ingredient Oral LD50, mg/kg Skin LD50, mg/kg Inhalation Vapor Inhalation Dust/Mist LD50, mg/L/4hr Hexamethylene diisocyanate 5,000.00, Rat - Category: No data available homopolymer - ( 28182-81-2) 5 BUTYL ACETATE - ( 123-86-4) 10,700.00, Rat - Category: 17,600.00, No data available NA Rabbit - Category: NA Petroleum naphtha - ( 64742-95-6) 6,800.00, Rat -Category: 3,400.00, No data available NA Rabbit - Category: 5 Hexamethylene diisocyanate - No data available ( 822-06-0) Item Category Hazard Acute Toxicity (mouth) Not Classified Not Applicable Acute Toxicity (skin) Not Classified Not Applicable Acute Toxicity (inhalation) Not Classified Not Applicable Skin corrosion/irritation Not Classified Not Applicable Eye damage/irritation Not Classified Not Applicable Sensitization (respiratory) 1 May cause allergy or asthma symptoms of breathing difficulties if inhaled. Sensitization (skin) 1 May cause an allergic skin reaction. Germ toxicity Not Classified Not Applicable Carcinogenicity Not Classified Not Applicable Reproductive Toxicity Not Classified Not Applicable Specific target organ systemic toxicity Not Classified Not Applicable (single exposure) Specific target organ systemic Not Classified Not Applicable Toxicity (repeated exposure) Aspiration hazard Not Classified Not Applicable 12. Ecological Information 12.1. Toxicity No additional information provided for this product. See Section 3 for chemical specific data. Aquatic Toxicity Ingredient 96 hr LC50 fish, mg/l 48 hr EC50 crustacea, ErC50 algae, mg/l mg/l Hexamethylene diisocyanate 100.00, Danio rerio 100.00, Daphnia homopolymer - ( 28182-81-2) magna 100.00 (72 hr), Scenedesmus subspicatus BUTYL ACETATE - ( 123-86-4) 18.00, Pimephales promelas 32.00, Artemia salina 674.70 (72 hr), Scenedesmus subspicatus Petroleum naphtha - 6.14, Daphnia magna 19.00 (72 hr), Selenastrum ( 64742-95-6) 9.22, Oncorhynchus mykiss capricornutum Hexamethylene diisocyanate – 82.80, Danio rerio 89.10, Daphnia 77.40 (72 hr), Desmodesmus ( 822-06-0) magna subspicatus 12.1. Persistence and degradability No data available 12.2. Bioaccumulative potential Not Measured 12.3. Mobility in soil No data available 12.4. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.5. Other adverse effects No data available 13. Disposal Information Tub Refinishing Inc., DBA Munro Products 13.1 Waste treatment methods Do not allow spills to enter drains or watercourses. Dispose of in accordance with local, state and federal regulations. (Also reference RCRA information in Section 15 if listed). 14. Transportation Information 14.1 UN number UN 1263 14.2 UN proper shipping name PAINT 14.3 Transport hazard class(es) DOT IMO / IMDG (Domestic Surface Transportation) (Ocean Transportation) Proper Shipping Name PAINT UN Number UN 1263 Hazard Class 3 3, Sub Class 3 Packaging Group III CERCLA/DOT RQ: 5359 gal. / 50000 lbs. System Reference Code: 1 14.4 Packing group III 14.5 Environmental hazards IMDG Marine Pollutant: No 14.6 Special precautions for user Not Not Applicable Applicable 14.7 Transport in bulk according to Annex Not Applicable II of MARPOL73/78 and the IBC Code 15. Regulatory Information Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All ingredients of this product are listed on the TSCA (Toxic Substance Control Act) Inventory or are not required to be listed on the TSCA Inventory. WHMIS Classification B2 D2A DOT Marine Pollutants (10%): (No Product Ingredients Listed) DOT Severe Marine Pollutants (1%): (No Product Ingredients Listed) EPCRA 311/312 Chemicals and RQs (>.1%): Benzene, ethyl- (1000 lb final RQ; 454 kg final RQ) Hexamethylene diisocyanate (100 lb final RQ; 45.4 kg final RQ) BUTYL ACETATE (5000 lb final RQ (listed under Butyl acetate); 2270 kg final RQ (listed under Butyl acetate)) EPCRA 302 Extremely Hazardous (>.1%): (No Product Ingredients Listed) EPCRA 313 Toxic Chemicals (>.1%): Benzene, ethyl- Hexamethylene diisocyanate Mass RTK Substances (>1%) : BUTYL ACETATE Penn RTK Substances (>1%) : BUTYL ACETATE Penn Special Hazardous Substances (>.01%): (No Product Ingredients Listed) RCRA Status: (No Product Ingredients Listed) N.J. RTK Substances (>1%): BUTYL ACETATE N.J. Special Hazardous Substances (>.01%): Benzene, ethyl- BUTYL ACETATE N.J. Env. Hazardous Substances (>.1%): Benzene, ethyl- Hexamethylene diisocyanate Proposition 65 - Benzene, ethyl- Carcinogens (>0%): Tub Refinishing Inc., DBA Munro Products Proposition 65 - Female Repro Toxins (No Product Ingredients Listed) (>0%): Proposition 65 - Male Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Developmental Toxins (No Product Ingredients Listed) (>0%): 16. Other Information SDS Revision Date: 3/11/2014 The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders. The full text of the phrases appearing in section 3 is: H226 Flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H331 Toxic if inhaled. H334 May cause allergy or asthma symptoms of breathing difficulties if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. Tub Refinishing Inc., DBA Munro Products 1. Identification 1.1 Product Name BATHWORKS® DIY White High Speed Filler BATHWORKS® Chip Filler 1.2 Distributor Munro Products (716) 741-9450 9150 Clarence Center Road Clarence Center, NY 14032 www.bath-works.net 1.3 Emergency Information CHEMTREC® (800) 424-9300 Poison Control Center (800) 854-6813 2. Hazard Identification 2.1 Classification of the substance or mixture: Flammable Liquids 3 Skin Corrosion/Irritation 2 Eye Damage/Irritation 2B Acute Toxicity-Inhalation 4 2.2 GHS label elements: Signal Word: Warning Hazard Statement: Flammable liquid and vapor Prevention: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Wear protective gloves/eye protection/face protection. Response: If on skin (or hair): remove/take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: use carbon dioxide, foam, dry chemical or water fog to extinguish fire. Storage: Store in a well-ventilated place. Keep cool. Disposal: Dispose of contents/container by incineration under controlled conditions in accordance with all local and national laws and regulations. Signal Word: Warning Hazard Statement: Causes skin irritation Prevention: Wash hands thoroughly after handling. Wear protective gloves. Response: If on skin wash with plenty of soap and water. If skin irritation occurs get medical advice/attention. Take off contaminated clothing and wash before reuse. Signal Word: Warning Hazard Statement: Causes eye irritation Prevention: Flush eyes thoroughly after eye contact. Response: If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: get medical advice/attention. Signal Word: Warning Hazard Statement: Harmful if inhaled Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well- ventilated area. Response: If inhaled: remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. 2.3 Other hazards which do not result in classification: N/A 2.4 HMIS Rating Health: 2 Flammability: 3 Reactivity: 1 3. Ingredient Composition