Fipronil Formulation

Hazard statements (CLP)

H226, H302, H311, H315, H319, H330, H373, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Emergency Overview Appearance : liquid Colour : yellow Odour : characteristic Flammable liquid and vapour. Harmful if swallowed. Toxic in contact with skin. Causes skin irrita- tion. Causes serious eye irritation. Fatal if inhaled. May cause damage to organs through pro- longed or repeated exposure. Very toxic to aquatic life with long lasting effects. GHS Classification Flammable liquids Category 3 Acute toxicity (Oral) Category 4 Acute toxicity (Inhalation) Category 2 Acute toxicity (Dermal) Category 3 Skin corrosion/irritation Category 2 Serious eye damage/eye irri- tation Category 2A Specific target organ toxicity - Category 2 repeated exposure Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 1 hazard

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H302 Harmful if swallowed. H311 Toxic in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H330 Fatal if inhaled. H373 May cause damage to organs through prolonged or re- peated exposure. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting equip- ment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection/ hearing protection. P284 Wear respiratory protection.

Response

P301 + P317 + P330 IF SWALLOWED: Get medical help. Rinse mouth. P303 + P361 + P353 + P316 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water. Get emergency medical help immediately. P304 + P340 + P316 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Get emergency medical help immediately. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P319 Get medical help if you feel unwell. P332 + P317 If skin irritation occurs: Get medical help. P337 + P317 If eye irritation persists: Get medical help. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. P391 Collect spillage.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Flammable liquid and vapour.

Health hazards

Harmful if swallowed. Fatal if inhaled. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure

Environmental hazards

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

Vapours may form explosive mixture with air.

2.1 Classification of the substance or mixture

Flammable liquids : Category 3 Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 2 Acute toxicity (Dermal) : Category 3 Skin corrosion/irritation : Category 2 Serious eye damage/eye irri- : Category 2A tation Specific target organ toxicity - : Category 2 repeated exposure Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 1 hazard