Diflubenzuron (25%) Formulation

Hazard statements (CLP)

H303, H315, H317, H318, H361, H373, H410

Code

Statements

H303

May be harmful if swallowed

SECTION 2: Hazards identification

Emergency Overview Appearance : Aqueous solution Colour : yellow Odour : No data available May be harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting ef- fects. GHS Classification Acute toxicity (Oral) Category 5 Skin corrosion/irritation Category 2 Serious eye damage/eye irri- tation Category 1 Skin sensitisation Category 1 Reproductive toxicity Category 2 Specific target organ toxicity - Category 2 repeated exposure Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 1 hazard

Signal word

Danger

Hazard statements

H303 May be harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H361 Suspected of damaging fertility or the unborn child. H373 May cause damage to organs through prolonged or re- peated exposure. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P203 Obtain, read and follow all safety instructions before use. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection/ hearing protection.

Response

P301 + P333 + P317 IF SWALLOWED or if skin irritation or rash occurs: Get medical help. P302 + P352 IF ON SKIN: Wash with plenty of water. P305 + P354 + P338 + P317 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if pre- sent and easy to do. Continue rinsing. Get medical help. P318 IF exposed or concerned, get medical advice. P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.

Storage

P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Not classified based on available information.

Health hazards

May be harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure

Environmental hazards

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects

Additional information

The following percentage of the mixture consists of ingredient(s) with unknown hazards to the aquatic environment: 3 %

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Acute toxicity (Oral) : Category 5 Skin corrosion/irritation : Category 2 Serious eye damage/eye irri- : Category 1 tation Skin sensitisation : Category 1 Reproductive toxicity : Category 2 Specific target organ toxicity - : Category 2 repeated exposure Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 1 hazard