Dichlofenthion Formulation

Hazard statements (CLP)

H226, H302, H304, H313, H314, H317, H318, H335, H341, H350, H351, H361d, H370, H373, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Emergency Overview Appearance : viscous liquid Colour : dark, brown Odour : strong Flammable liquid and vapour. Harmful if swallowed. May be fatal if swallowed and enters airways. May be harmful in contact with skin. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause respiratory irritation. Suspected of causing genetic defects. May cause cancer if swallowed. Suspected of causing cancer. Suspected of damaging the unborn child. Causes damage to organs. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. GHS Classification Flammable liquids Category 3 Acute toxicity (Oral) Category 4 Acute toxicity (Dermal) Category 5 Skin corrosion/irritation Sub-category 1B Serious eye damage/eye irri- tation Category 1 Skin sensitisation Category 1 Germ cell mutagenicity Category 2 Carcinogenicity Category 2 Carcinogenicity (Oral) Category 1A Reproductive toxicity Category 2 Specific target organ toxicity - Category 1 single exposure Specific target organ toxicity - Category 3 single exposure Specific target organ toxicity - Category 2 repeated exposure

Aspiration hazard

Category 1 Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 1 hazard

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H313 May be harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H350 May cause cancer if swallowed. H351 Suspected of causing cancer. H361d Suspected of damaging the unborn child. H370 Causes damage to organs. H373 May cause damage to organs through prolonged or re- peated exposure. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P203 Obtain, read and follow all safety instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting equip- ment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection/ hearing protection.

Response

P301 + P330 + P331 + P316 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Get emergency medical help imme- diately. P302 + P361 + P354 + P316 IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for sev- eral minutes. Get emergency medical help immediately. P304 + P340 + P316 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Get emergency medical help immediately. P305 + P354 + P338 + P316 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if pre- sent and easy to do. Continue rinsing. Get emergency medical P308 + P316 IF exposed or concerned: Get emergency medi- cal help immediately. P331 Do NOT induce vomiting. P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P333 + P317 If skin irritation or rash occurs: Get medical help. P362 + P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Flammable liquid and vapour.

Health hazards

Harmful if swallowed. May be harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. May cause an allergic skin reaction. Suspected of causing genetic defects. Suspected of causing cancer. May cause cancer if swallowed. Suspected of damaging the unborn child. Causes damage to organs. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways

Environmental hazards

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

Vapours may form explosive mixture with air.

2.1 Classification of the substance or mixture

Flammable liquids : Category 3 Acute toxicity (Oral) : Category 4 Acute toxicity (Dermal) : Category 5 Skin corrosion/irritation : Sub-category 1B Serious eye damage/eye irri- : Category 1 tation Skin sensitisation : Category 1 Germ cell mutagenicity : Category 2 Carcinogenicity : Category 2 Carcinogenicity (Oral) : Category 1A Reproductive toxicity : Category 2 Specific target organ toxicity - : Category 1 single exposure Specific target organ toxicity - : Category 3 single exposure Specific target organ toxicity - : Category 2 repeated exposure Aspiration hazard : Category 1 Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 1 hazard