Dichlofenthion Formulation

Hazard statements (CLP)

H226, H302, H304, H314, H317, H335, H341, H350, H361d, H370, H373, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification GHS Classification Flammable liquids Category 3 Acute toxicity (Oral) Category 4 Skin corrosion/irritation Category 1B Serious eye damage/eye irri- tation Category 1 Skin sensitisation Category 1 Germ cell mutagenicity Category 2 Carcinogenicity (Oral) Category 1A Reproductive toxicity Category 2 Specific target organ toxicity - Category 1 (Nervous system) single exposure Specific target organ toxicity - Category 3 single exposure Specific target organ toxicity - Category 2 (Nervous system, Respiratory Tract) repeated exposure

Aspiration hazard

Category 1 Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 1 hazard

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H350 May cause cancer if swallowed. H361d Suspected of damaging the unborn child. H370 Causes damage to organs (Nervous system). H373 May cause damage to organs (Nervous system, Respira- tory Tract) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting equip- ment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection.

Response

P301 + P330 + P331 + P310 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 + P310 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. Immediately call a POISON CENTER/ doctor. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON P308 + P311 IF exposed or concerned: Call a POISON P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

Vapours may form explosive mixture with air.

2.1 Classification of the substance or mixture

Flammable liquids : Category 3 Acute toxicity (Oral) : Category 4 Skin corrosion/irritation : Category 1B Serious eye damage/eye irri- : Category 1 tation Skin sensitisation : Category 1 Germ cell mutagenicity : Category 2 Carcinogenicity (Oral) : Category 1A Reproductive toxicity : Category 2 Specific target organ toxicity - : Category 1 (Nervous system) single exposure Specific target organ toxicity - : Category 3 single exposure Specific target organ toxicity - : Category 2 (Nervous system, Respiratory Tract) repeated exposure Aspiration hazard : Category 1 Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 1 hazard