Diazinon Formulation

Hazard statements (CLP)

H302, H304, H313, H315, H317, H318, H336, H340, H350, H361, H370, H373, H410

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Emergency Overview Appearance : liquid Colour : yellow Odour : characteristic Harmful if swallowed. May be fatal if swallowed and enters airways. May be harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye dam- age. May cause drowsiness or dizziness. May cause genetic defects. May cause cancer. Sus- pected of damaging fertility or the unborn child. Causes damage to organs. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting ef- fects. GHS Classification Acute toxicity (Oral) Category 4 Acute toxicity (Dermal) Category 5 Skin corrosion/irritation Category 2 Serious eye damage/eye irri- tation Category 1 Skin sensitisation Category 1 Germ cell mutagenicity Category 1B Carcinogenicity Category 1B Reproductive toxicity Category 2 Specific target organ toxicity - Category 1 single exposure Specific target organ toxicity - Category 3 single exposure Specific target organ toxicity - Category 2 repeated exposure

Aspiration hazard

Category 1 Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 1 hazard

Signal word

Danger

Hazard statements

H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H313 May be harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H361 Suspected of damaging fertility or the unborn child. H370 Causes damage to organs. H373 May cause damage to organs through prolonged or re- peated exposure. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P203 Obtain, read and follow all safety instructions before use. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection/ hearing protection.

Response

P301 + P316 + P330 IF SWALLOWED: Get emergency medi- cal help immediately. Rinse mouth. P302 + P352 + P317 IF ON SKIN: Wash with plenty of water. Get medical help. P304 + P340 + P319 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Get medical help if you feel unwell. P305 + P354 + P338 + P317 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if pre- sent and easy to do. Continue rinsing. Get medical help. P308 + P316 IF exposed or concerned: Get emergency medi- cal help immediately. P331 Do NOT induce vomiting. P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P333 + P317 If skin irritation or rash occurs: Get medical help. P362 + P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.

Storage

P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Not classified based on available information.

Health hazards

Harmful if swallowed. May be harmful in contact with skin. Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction. May cause genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs. May cause drows- iness or dizziness. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways

Environmental hazards

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Acute toxicity (Oral) : Category 4 Acute toxicity (Dermal) : Category 5 Skin corrosion/irritation : Category 2 Serious eye damage/eye irri- : Category 1 tation Skin sensitisation : Category 1 Germ cell mutagenicity : Category 1B Carcinogenicity : Category 1B Reproductive toxicity : Category 2 Specific target organ toxicity - : Category 1 single exposure Specific target organ toxicity - : Category 3 single exposure Specific target organ toxicity - : Category 2 repeated exposure Aspiration hazard : Category 1 Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 1 hazard