o-Phenylenediamine

Hazard statements (CLP)

H301, H312, H317, H319, H332, H341, H351

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

NFPA Rating Classification of the substance or mixture GHS06 Skull and crossbones Acute Tox. 3 H301 Toxic if swallowed GHS08 Health hazard Muta. 2 H341 Suspected of causing genetic defects Carc. 2 H351 Suspected of causing cancer GHS07 Acute Tox. 4 H312 Harmful in contact with skin Acute Tox. 4 H332 Harmful if inhaled Eye Irrit. 2 H319 Causes serious eye irritation Skin Sens. 1 H317 May cause an allergic skin reaction Classification according to Directive 67/548/EEC or Directive 1999/45/EC Toxic Toxic if swallowed Harmful Harmful by inhalation and in contact with skin. Limited evidence of a carcinogenic effect. Possible risk of irreversible effects Irritant Irritating to eyes. May cause sensitisation by skin contact Contd. of page 1) Dangerous for the environment Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Carc. Cat. 3, Muta. Cat. 3 Information concerning particular hazards for human and environment: Not applicable

2.2 Label elements

The substance is classified and labelled according to the Globally Harmonized System (GHS).

Hazard pictograms

GHS06 GHS08

Signal word

Danger

Hazardous Ingredients

o-phenylenediamine

Hazard statements

Toxic if swallowed. Harmful in contact with skin or if inhaled. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing genetic defects. Suspected of causing cancer.

Precautionary statements

If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see on this label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification system

· NFPA ratings (scale 0 - 4) Health = 3 1 Fire = 1 3 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH *3 Health = *3 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0

PBT Substances

Not applicable (Contd. of page 2)

vPvB Substances

Not applicable

2.1 Classification of the substance or mixture

GHS06 Skull and crossbones Acute Tox. 3 H301 Toxic if swallowed. GHS08 Health hazard Muta. 2 H341 Suspected of causing genetic defects. Carc. 2 H351 Suspected of causing cancer. GHS07 Acute Tox. 4 H312 Harmful in contact with skin. Acute Tox. 4 H332 Harmful if inhaled. Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Toxic Toxic if swallowed. Harmful Harmful by inhalation and in contact with skin. Limited evidence of a carcinogenic effect. Possible risk of irreversible effects. Irritant Irritating to eyes. May cause sensitisation by skin contact. (Contd. of page 1) Dangerous for the environment Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Carc. Cat. 3, Muta. Cat. 3 · Information concerning particular hazards for human and environment: Not applicable.