TOLUENE SPECIALLY DRIED AR

Hazard statements (CLP)

H225, H304, H315, H335, H336, H361, H361d, H373

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

-DSD Regulation EC 1272/2008 (CLP)] Classification of the substance or mixture

Health hazards

Reproductive toxicity - Unborn Child - Category 2 - Warning (CLP Repr. 2) H361 Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP STOT SE 3) H335 Specific Target Organ Toxicity - Single exposure - Narcotic effects - Category 3 - Warning (CLP STOT SE 3) H336 Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (CLP STOT RE 2) H373 Aspiration hazard - Category 1 - Danger (CLP Asp. Tox. 1) H304 Skin irritation - Category 2 - Warning (CLP Skin Corr. 2) H315

Physical hazards

Flammable liquids - Category 2 - Danger (CLP Flam. Liq. 2) H225

Hazard pictograms

F Highly flammable Xn Harmful

R-phrase(s)

R11 Highly flammable. R38 Irritating to skin. R48/20 Harmful danger of serious damage to health by prolonged exposure through inhalation. R63 Possible risk of harm to the unborn child. R65 Harmful may cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness.

S-phrase(s)

S2 Keep out of the reach of children. S36/37 Wear suitable protective clothing and gloves. S62 If swallowed, do not induce vomiting seek medical advice immediately and show this container or label.

Contains

Toluene

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H373 May cause damage to organs through prolonged or repeated exposure. H361d: Suspected of damaging the unborn child.

Precautionary statements

• General P102: Keep out of reach of children. P103: Read label before use. P101: If medical advice is needed, have product container or label at hand. P201: Obtain special instructions before use.

Prevention

P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating, lighting, …, equipment. P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking. P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P260: Do not breathe dust, fume, gas, mist, vapours, spray. P233: Keep container tightly closed. P264: Wash thoroughly after handling.

Response

P301+P310: IF SWALLOWED Immediately call a POISON CENTER or doctor. P302+P352: IF ON SKIN Wash with plenty of soap and water. P308+P313: If exposed or concerned get medical advice. P332+P313: If skin irritation occurs Get medical advice. P304+P340: IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P303+P361+P353: IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water/shower. P363: Wash contaminated clothing before reuse. P314: Get medical advice if you feel unwell. P370+P378 In case of fire Use for extinction

Storage

P403+P233: Store in well-ventilated place. Keep container tightly closed. P403+P235: Store in well-ventilated place. Keep cool. P405: Store locked up. • Disposal considerations P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards

The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.

2.1 Classification of the substance or mixture

Classification EC 67/548 or EC 1999/45 Classification : F; R11 Repr. Cat. 3; R63 Xn; R65-48/20 R67 Xi; R38 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Reproductive toxicity - Unborn Child - Category 2 - Warning (CLP : Repr. 2) H361 Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP : STOT SE 3) H335 Specific Target Organ Toxicity - Single exposure - Narcotic effects - Category 3 - Warning (CLP : STOT SE 3) H336 Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (CLP : STOT RE 2) H373 Aspiration hazard - Category 1 - Danger (CLP : Asp. Tox. 1) H304 Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315 Physical hazards : Flammable liquids - Category 2 - Danger (CLP : Flam. Liq. 2) H225