PHOSPHORUS TRICHLORIDE FOR SYNTHESIS

Hazard statements (CLP)

H300, H314, H330, H373

Code

Statements

H300

Fatal if swallowed

SECTION 2: Hazards identification

-DSD Regulation EC 1272/2008 (CLP)] Classification of the substance or mixture

Health hazards

Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (CLP STOT RE 2) H373 Acute toxicity, Inhalation - Category 2 - Danger (CLP Acute Tox. 2) H330 Acute toxicity, Oral - Category 1 - Danger (CLP Acute Tox. 1) H300 Skin corrosion - Category 1A - Danger (CLP Skin Corr. 1A) H314

Hazard pictograms

T+ Very toxic C Corrosive

R-phrase(s)

R14 Reacts violently with water. R26/28 Very toxic by inhalation and if swallowed. R35 Causes severe burns. R48/20 Harmful danger of serious damage to health by prolonged exposure through inhalation.

S-phrase(s)

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible).

Signal word

Danger

Hazard statements

H300 Fatal if swallowed. H330 Fatal if inhaled. H314 Causes severe skin burns and eye damage. H373 May cause damage to organs through prolonged or repeated exposure.

Prevention

P284: Wear respiratory protection. P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P260: Do not breathe dust, fume, gas, mist, vapours, spray. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product.

Response

P301+P330+P331: IF SWALLOWED Rinse mouth. Do NOT induce vomiting. P305+P351+P338: IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340: IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P303+P361+P353: IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water/shower. P363: Wash contaminated clothing before reuse. P314: Get medical advice if you feel unwell.

Storage

P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up. • Disposal considerations P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards

The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.

2.1 Classification of the substance or mixture

Classification EC 67/548 or EC 1999/45 Classification : R14 T+; R26/28 Xn; 48/20 C; R35 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (CLP : STOT RE 2) H373 Acute toxicity, Inhalation - Category 2 - Danger (CLP : Acute Tox. 2) H330 Acute toxicity, Oral - Category 1 - Danger (CLP : Acute Tox. 1) H300 Skin corrosion - Category 1A - Danger (CLP : Skin Corr. 1A) H314