O-Tolidine (Reagent) For Chlorine Estimation

Hazard statements (CLP)

H314, H319, H350

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

-DSD Regulation (EC) No. 1272/2008] Classification of the substance or mixture

Health hazards

Carcinogenicity - Category 1A - Danger (CLP Carc. 1A) H350 Skin corrosion - Category 1B - Danger (CLP Skin Corr. 1B) H314 Eye irritation - Category 2A - Warning (CLP Eye Irrit. 2) H319

Hazard pictograms

T Toxic

R-phrase(s)

R22: Harmful if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin. R45 May cause cancer. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s)

S4 Keep away from living quarters. S22 Do not breathe dust. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with S35 This material and its container must be disposed of in a safe way. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label when possible). S53 Avoid exposure - obtain special instructions before use. S59 Refer to manufacturer/supplier for information on recovery/recycling. S61 avoid release to the environment . refer to special instruction/safety data sheets.

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage. H350 May cause cancer. H319 Causes serious eye irritation.

Precautionary statements

• General P201: Obtain special instructions before use.

Prevention

P280: Wear protective gloves, protective clothing, eye protection, face protection. P260: Do not breathe dust, fume, gas, mist, vapours, spray. P264: Wash thoroughly after handling.

Response

P301+P330+P331: IF SWALLOWED Rinse mouth. Do NOT induce vomiting. P308+P313: If exposed or concerned get medical advice. P305+P351+P338: IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P303+P361+P353: IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water/shower. P363: Wash contaminated clothing before reuse. P337+P313 If eye irritation persists Get medical advice/attention

Storage

P405: Store locked up. • Disposal considerations P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. Special labelling Restricted to professional users. (Substances which appear in Part 3 of Annex VI to

Other hazards

The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.

2.1 Classification of the substance or mixture

Classification EC 67/548 or EC 1999/45 Classification : Carc. Cat. 2; R45 Xi; R36/37/38 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Carcinogenicity - Category 1A - Danger (CLP : Carc. 1A) H350 Skin corrosion - Category 1B - Danger (CLP : Skin Corr. 1B) H314 Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319