METHYL IODIDE FOR SYNTHESIS 99%

Hazard statements (CLP)

H301, H312, H315, H331, H335, H351

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

-DSD Regulation EC 1272/2008 (CLP)] Classification of the substance or mixture

Health hazards

Carcinogenicity - Category 2 - Warning (CLP Carc. 2) H351 Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP STOT SE 3) H335 Acute toxicity, Oral - Category 3 - Danger (CLP Acute Tox. 3) H301 Acute toxicity, dermal - Category 4 - Warning (CLP Acute Tox. 4) H312 Acute toxicity, Inhalation - Category 3 - Danger (CLP Acute Tox. 3) H331 Skin irritation - Category 2 - Warning (CLP Skin Corr. 2) H315

Hazard pictograms

T Toxic

R-phrase(s)

R21 Harmful in contact with skin. R23/25 Toxic by inhalation and if swallowed. R37/38 Irritating to respiratory system and skin. R40 Limited evidence of a carcinogenic effect.

S-phrase(s)

S1/2 Keep locked up and out of reach of children. S36/37 Wear suitable protective clothing and gloves. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S45 In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible).

Signal word

Danger

Hazard statements

H301 Toxic if swallowed. H331 Toxic if inhaled. H351 Suspected of causing cancer. H312 Harmful in contact with skin. H315 Causes skin irritation. H335 May cause respiratory irritation.

Precautionary statements

• General P102: Keep out of reach of children. P103: Read label before use. P101: If medical advice is needed, have product container or label at hand. P201: Obtain special instructions before use.

Prevention

P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust, fume, gas, mist, vapours, spray. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product.

Response

P301+P310: IF SWALLOWED Immediately call a POISON CENTER or doctor. P302+P352: IF ON SKIN Wash with plenty of soap and water. P308+P313: If exposed or concerned get medical advice. P332+P313: If skin irritation occurs Get medical advice. P304+P340: IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P363: Wash contaminated clothing before reuse.

Storage

P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up. • Disposal considerations P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards

The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.

2.1 Classification of the substance or mixture

Classification EC 67/548 or EC 1999/45 Classification : Carc. Cat. 3; R40 T; R23/25 Xn; R21 Xi; R37/38 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Carcinogenicity - Category 2 - Warning (CLP : Carc. 2) H351 Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP : STOT SE 3) H335 Acute toxicity, Oral - Category 3 - Danger (CLP : Acute Tox. 3) H301 Acute toxicity, dermal - Category 4 - Warning (CLP : Acute Tox. 4) H312 Acute toxicity, Inhalation - Category 3 - Danger (CLP : Acute Tox. 3) H331 Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315