HYDRAZINE HYDRATE 80%

Hazard statements (CLP)

H226, H301, H311, H314, H317, H331, H400, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

-DSD Regulation EC 1272/2008 (CLP)] Classification of the substance or mixture

Health hazards

Skin corrosion - Category 1B - Danger (CLP Skin Corr. 1B) H314 Acute toxicity, Oral - Category 3 - Danger (CLP Acute Tox. 3) H301 Acute toxicity, Inhalation - Category 3 - Danger (CLP Acute Tox. 3) H331 Skin sensitisation - Category 1 - Warning (CLP Skin Sens. 1) H317 Acute toxicity, dermal - Category 3 - Danger (CLP Acute Tox. 3) H311

Physical hazards

Flammable liquids - Category 3 - Warning (CLP Flam. Liq. 3) H226

Environmental hazards

Hazardous to the aquatic environment - Acute hazard - Category 1 - Warning (CLP Aquatic Acute 1) H400 Hazardous to the aquatic environment - Chronic hazard - Category 1 - Warning ( CLP Aquatic Chronic 1) H410

Hazard pictograms

T Toxic N Dangerous for the environment

R-phrase(s)

R45 May cause cancer. R10 Flammable. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitization by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s)

S53 Avoid exposure - obtain special instructions before use. S45 In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible). S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H314 Causes severe skin burns and eye damage. H301 Toxic if swallowed. H311 Toxic in contact with skin. H331 Toxic if inhaled. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating, lighting, …, equipment. P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking. P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P260: Do not breathe dust, fume, gas, mist, vapours, spray. P273: Avoid release to the environment. P233: Keep container tightly closed. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P272: Contaminated work clothing should not be allowed out of the workplace.

Response

P302+P352: IF ON SKIN Wash with plenty of soap and water. P301+P330+P331: IF SWALLOWED Rinse mouth. Do NOT induce vomiting. P391: Collect spillage. P305+P351+P338: IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340: IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P303+P361+P353: IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water/shower. P333+P313: If skin irritation or rash occurs Get medical advice. P363: Wash contaminated clothing before reuse. P361: Remove immediately all contaminated clothing. P370+P378 In case of fire Use for extinction

Storage

P403+P233: Store in well-ventilated place. Keep container tightly closed. P403+P235: Store in well-ventilated place. Keep cool. P405: Store locked up. • Disposal considerations P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards

The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.

2.1 Classification of the substance or mixture

Classification EC 67/548 or EC 1999/45 Classification : R10 T; R23/24/25 C; R34 R43 N; R50-53 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Skin corrosion - Category 1B - Danger (CLP : Skin Corr. 1B) H314 Acute toxicity, Oral - Category 3 - Danger (CLP : Acute Tox. 3) H301 Acute toxicity, Inhalation - Category 3 - Danger (CLP : Acute Tox. 3) H331 Skin sensitisation - Category 1 - Warning (CLP : Skin Sens. 1) H317 Acute toxicity, dermal - Category 3 - Danger (CLP : Acute Tox. 3) H311 Physical hazards : Flammable liquids - Category 3 - Warning (CLP : Flam. Liq. 3) H226 Environmental hazards : Hazardous to the aquatic environment - Acute hazard - Category 1 - Warning (CLP : Aquatic Acute 1) H400 Hazardous to the aquatic environment - Chronic hazard - Category 1 - Warning ( CLP : Aquatic Chronic 1) H410