FURFURYL ALCOHOL FOR SYNTHESIS

Hazard statements (CLP)

H302, H312, H319, H331, H335, H351, H373

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

-DSD Regulation EC 1272/2008 (CLP)] Classification of the substance or mixture

Health hazards

Carcinogenicity - Category 2 - Warning (CLP Carc. 2) H351 Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP STOT SE 3) H335 Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (CLP STOT RE 2) H373 Eye irritation - Category 2A - Warning (CLP Eye Irrit. 2) H319 Acute toxicity, Inhalation - Category 3 - Danger (CLP Acute Tox. 3) H331 Acute toxicity, Oral - Category 4 - Warning (CLP Acute Tox. 4) H302 Acute toxicity, dermal - Category 4 - Warning (CLP Acute Tox. 4) H312

Hazard pictograms

T Toxic

R-phrase(s)

R21/22 Harmful in contact with skin and if swallowed. R23 Toxic by inhalation. R36/37 Irritating to eyes and respiratory system. R40 Limited evidence of a carcinogenic effect. R48/20 Harmful danger of serious damage to health by prolonged exposure through inhalation.

S-phrase(s)

S1/2 Keep locked up and out of reach of children. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible). S63 In case of accident by inhalation remove casualty to fresh air and keep at rest.

Hazard statements

H331 Toxic if inhaled. H351 Suspected of causing cancer. H302 Harmful if swallowed. H312 Harmful in contact with skin. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

• General P102: Keep out of reach of children. P103: Read label before use. P101: If medical advice is needed, have product container or label at hand. P201: Obtain special instructions before use.

Prevention

P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P260: Do not breathe dust, fume, gas, mist, vapours, spray. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product.

Response

P302+P352: IF ON SKIN Wash with plenty of soap and water. P301+P312: IF SWALLOWED Call a POISON CENTER or doctor if you feel unwell. P308+P313: If exposed or concerned get medical advice. P305+P351+P338: IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340: IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P363: Wash contaminated clothing before reuse. P314: Get medical advice if you feel unwell. P337+P313 If eye irritation persists Get medical advice/attention

Storage

P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up. • Disposal considerations P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards

The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.

2.1 Classification of the substance or mixture

Classification EC 67/548 or EC 1999/45 Classification : Carc. Cat. 3; R40 T; R23 Xn; R21/22-48/20 Xi; R36/37 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Carcinogenicity - Category 2 - Warning (CLP : Carc. 2) H351 Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP : STOT SE 3) H335 Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (CLP : STOT RE 2) H373 Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319 Acute toxicity, Inhalation - Category 3 - Danger (CLP : Acute Tox. 3) H331 Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302 Acute toxicity, dermal - Category 4 - Warning (CLP : Acute Tox. 4) H312