ETHYL TRIFLUOROACETATE

Hazard statements (CLP)

H228, H302, H315, H318, H335

Code

Statements

H228

Flammable solid

SECTION 2: Hazards identification

-DSD Regulation EC 1272/2008 (CLP)] Classification of the substance or mixture

Health hazards

Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP STOT SE 3) H335 Acute toxicity, Oral - Category 4 - Warning (CLP Acute Tox. 4) H302 Serious eye damage - Category 1 - Danger (CLP Eye Dam. 1) H318 Skin irritation - Category 2 - Warning (CLP Skin Corr. 2) H315

Physical hazards

Flammable solids - Category 1 - Danger (CLP Flam. Sol. 1) H228

Hazard pictograms

F Highly flammable Xn Harmful

R-phrase(s)

R11 Highly flammable. R22 Harmful if swallowed. R37 Irritating to respiratory system. R38 Irritating to skin. R41 Risk of serious damage to eyes.

S-phrase(s)

S16 Keep away from sources of ignition - No smoking. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/39 Wear suitable protective clothing and eye/face protection.

Signal word

Danger

Hazard statements

H228 Flammable solid. H318 Causes serious eye damage. H302 Harmful if swallowed. H315 Causes skin irritation. H335 May cause respiratory irritation.

Prevention

P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating, lighting, …, equipment. P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking. P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust, fume, gas, mist, vapours, spray. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product.

Response

P302+P352: IF ON SKIN Wash with plenty of soap and water. P301+P312: IF SWALLOWED Call a POISON CENTER or doctor if you feel unwell. P332+P313: If skin irritation occurs Get medical advice. P305+P351+P338: IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340: IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P363: Wash contaminated clothing before reuse. P370+P378 In case of fire Use for extinction

Storage

P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up. • Disposal considerations P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards

The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.

2.1 Classification of the substance or mixture

Classification EC 67/548 or EC 1999/45 Classification : F; R11 Xn; R22 Xi; R37-41 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP : STOT SE 3) H335 Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302 Serious eye damage - Category 1 - Danger (CLP : Eye Dam. 1) H318 Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315 Physical hazards : Flammable solids - Category 1 - Danger (CLP : Flam. Sol. 1) H228