4-NITROANILINE

Hazard statements (CLP)

H301, H311, H331, H412

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

-DSD Regulation EC 1272/2008 (CLP)] Classification of the substance or mixture

Health hazards

Acute toxicity, Oral - Category 3 - Danger (CLP Acute Tox. 3) H301 Acute toxicity, dermal - Category 3 - Danger (CLP Acute Tox. 3) H311 Acute toxicity, Inhalation - Category 3 - Danger (CLP Acute Tox. 3) H331

Environmental hazards

Hazardous to the aquatic environment - Chronic hazard - Category 3 (CLP Aquatic Chronic 3) H412

Hazard pictograms

T Toxic

R-phrase(s)

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R33 Danger of cumulative effects. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s)

S28 After contact with skin, wash immediately with S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label when possible). S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.

Signal word

Danger

Hazard statements

H301 Toxic if swallowed. H311 Toxic in contact with skin. H331 Toxic if inhaled. H412 Harmful to aquatic life with long lasting effects.

Prevention

P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust, fume, gas, mist, vapours, spray. P273: Avoid release to the environment. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product.

Response

P301+P310: IF SWALLOWED Immediately call a POISON CENTER or doctor. P302+P352: IF ON SKIN Wash with plenty of soap and water. P304+P340: IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P363: Wash contaminated clothing before reuse. P361: Remove immediately all contaminated clothing.

Storage

P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up. • Disposal considerations P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards

The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.

2.1 Classification of the substance or mixture

Classification EC 67/548 or EC 1999/45 Classification : T; R23/24/25 R33 R52-53 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Acute toxicity, Oral - Category 3 - Danger (CLP : Acute Tox. 3) H301 Acute toxicity, dermal - Category 3 - Danger (CLP : Acute Tox. 3) H311 Acute toxicity, Inhalation - Category 3 - Danger (CLP : Acute Tox. 3) H331 Environmental hazards : Hazardous to the aquatic environment - Chronic hazard - Category 3 (CLP : Aquatic Chronic 3) H412