Timesaver Lapping Compound - Green Label for Hard Metals

Hazard statements (CLP)

H227, H302, H315, H319, H320, H331, H332, H335, H350, H372

Code

Statements

H227

Combustible liquid

Hazard pictograms

>

Signal word

Danger

Hazardous Ingredients

Quartz (SiO2) Almandite and Pyrope Garnet sodium dodecylbenzenesulphonate CAS: 1302-62-1 Almandite and Pyrope Garnet 60-70% <> Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320 CAS: 7727-43-7 barium sulphate, natural 10-20% RTECS: CR 0600000 CAS: 14808-60-7 Quartz (SiO2) 10-20% RTECS: VV 7330000 @ Carc. 1A, H350; STOT RE 1, H372; <> Acute Tox. 4, H332; STOT SE 3, H335; Eye Irrit. 2B, H320 CAS: 7757-82-6 Sodium Sulphate 1-5% CAS: 25155-30-0 sodium dodecylbenzenesulphonate 1-2.5% Acute Tox. 3, H331; < Acute Tox. 4, H302: Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335; Flam. Lig. 4, H227

Hazard statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H350 May cause cancer. H335 May cause respiratory irritation. H3/72 Causes damage to the lung through prolonged or repeated exposure. Route of exposure: Inhalation.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P2771 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 If on skin: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P312 Call a poison center/doctor if you feel unwell. P321 Specific treatment (see supplementary first aid instructions on this Safety Data Sheet). P314 Get medical advice/attention if you feel unwell. P362+P364 Take off contaminated clothing and wash it before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P33/7+P313 If eye irritation persists: Get medical advice/attention. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. - Unknown acute toxicity: This value refers to Knowledge of known, established toxicological or ecotoxicological values. 20 % of the mixture consists of component(s) of unknown toxicity. Classification system: NFPA/HMIS Definitions O-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme NFPA ratings (scale Health = 2 Fire Reactivity = 0 HMIS-ratings (scale 0 HEALTH Health = *2 FIRE 0} Fire = 0 Physical Hazard = 0 Hazard(s) not otherwise classified (HNOC): None known Chemical characterization: Substance Description: Mixture of substances listed below with non-hazardous additions

Additional information

The exact percentages of the ingredients of this mixture are considered to be proprietary and are withheld in The lists that were valid during the creation of this SDS were used as basis - Exposure controls: - Personal protective equipment - General protective and hygienic measures: Ensure that eyewash stations and safety showers are close to the workstation location. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing and wash before reuse. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. ‘ Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure, use respiratory protective device that is independent of circulating air. o-) NIOSH/OSHA approved breathing apparatus. - Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. - Material of gloves: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary and ensure during use that the gloves are still retaining their protective properties. - Penetration time of glove material: The exact break-through time has to be determined and observed by the manufacturer of the protective gloves. - Eye protection: Tightly sealed goggles ‘ Body protection: Protective work clothing - Limitation and supervision of exposure into the environment: None - Information on basic physical and chemical properties - General Information - Appearance: Form: Powder Color: Green - Odor: Odorless - Odor threshold: Not determined. ' pH-value: Not determined. - Change in condition Melting point/Melting range: Not determined. Boiling point/Boiling range: 22,230 °C (23630 °F) ‘ Flash point: None ‘ Flammability (solid, gaseous): Not determined. - Ignition temperature: Not applicable ‘ Decomposition temperature: Not determined. ‘ Auto igniting: Product is not self-igniting. - Danger of explosion: Product does not present an explosion hazard. - Explosion limits: Lower: Not determined. Upper: Not determined. - Vapor pressure @ 1732 °C (3,149.6 °F): <13.5 hPa (<10.1 mm Hg) - Density @ 20 °C (68 °F): 23.6038-<3.7928 g/cm? (230.0737-s31.6509 Ibs/gal) - Relative density: Not determined. - Vapor density: Not applicable. - Evaporation rate: Not applicable. ‘ Solubility in / Miscibility with: Water: Insoluble. - Partition coefficient (n-octanol/water): Not determined. - Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. - Solvent content: VOC content: 0.00 % Solids content: 100.0 %

Storage

- Requirements to be met by storerooms and receptacles: Store in a cool, dry place in tightly closed receptacles. - Information about storage in one common storage facility: Not required. - Further information about storage conditions: Keep receptacle tightly sealed. - Specific end use(s): Obtaining precision finishes on machined components. - Additional information about design of technical systems: No further data; see section 7. - Control parameters: ‘ Components with occupational exposure limits: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 7727-43-7 barium sulphate, natural PEL Long-term value: 15* 5** mg/m? *total dust **respirable fraction REL Long-term value: 10* 5** mg/m? *total dust **respirable fraction TLV Long-term value: 5* mg/m? *inhalable fraction; E 14808-60-7 Quartz (SiO2) PEL Long-term value: 0.05* mg/m? *resp. dust; 30mg/m3/%Si02+2 REL Long-term value: 0.05* mg/m? *respirable dust; See Pocket Guide App. A TLV Long-term value: 0.025* mg/m? *as respirable fraction 7757-82-6 Sodium Sulphate TLV Short-term value: NIC-0.2 mg/m? thoracic fraction of aerosol

Further information

No further relevant information available. - Reactivity: No further relevant information available. - Chemical stability: Product is stable under normal conditions. - Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. ‘ Possibility of hazardous reactions: No dangerous reactions known. - Conditions to avoid: Dust generation. Incompatible Materials - Incompatible materials: Strong oxidizing agents. Strong acids Contact with fluorine, oxygen dilfuoride, and chlorine trifluoride will cause fire. - Hazardous decomposition products: Burning produces obnoxious and toxic fumes. In the event of fire the following can be released: Sulphur oxides; Carbon oxides; Sodium oxides; hydrogen sulphide. - Information on toxicological effects: - Acute toxicity: - LD/LC50 values that are relevant for classification: 14808-60-7 Quartz (SiO2) Oral LD50 >22,500 mg/kg (Rat) mg/kg (Rabbit) Inhalative LC50/96 hours 1,033 mg/l (Trout) 25155-30-0 Sodium dodecylbenzenesulphonate Oral LD50 438 mg/kg (Rat) Dermal LD50 >2,000 mg/kg (Rabbit) Inhalative LC50/96 hours 3.2 mg/l (Cyprinodon variegatus (minnow)) - Primary irritant effect: - On the skin: Irritant to skin and mucous membranes. - On the eye: Irritating effect. - Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant ‘ Carcinogenic categories: - [ARC (International Agency for Research on Cancer): “In 1997, IARC (the International Agency for Research on Cancer) concluded that crystalline silica inhaled from occupational sources can cause lung cancer in humans. However in making the overall evaluation, IARC noted that "carcinogenicity was not detected in all industrial circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its polymorphs." (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to humans, Silica, silicate dust and organic fibres, 1997, Vol. 68, IARC, Lyon, France.) In June 2003, SCOEL (the EU Scientific Committee on Occupational Exposure Limits) concluded that the main effect in humans of the inhalation of respirable crystalline silica dust is silicosis. "There is sufficient information to conclude that the relative risk of lung cancer is increased in persons with silicosis (and, apparently, not in employees without silicosis exposed to silica dust in quarries and in the ceramic industry). Therefore, preventing the onset of silicosis will also reduce the cancer risk." (SCOEL SUM Doc 94-final, June 2003) According to the current state of the art, worker protection against silicosis can be consistently assured by respecting the existing regulatory occupational exposure limits. May cause cancer. Occupational exposure to respirable dust and respirable crystalline silica should be monitored and controlled” Group 1 - Carcinogenic to humans Group 2A - Probably carcinogenic to humans Group 2B - Possibly carcinogenic to humans Group 3 - Not classifiable as to its carcinogenicity to humans Group 4 - Probably not carcinogenic to humans 14808-60-7 Quartz (SiO2) 1 ‘ NTP (National Toxicology Program): 14808-60-7 Quartz (SiO2) K ‘ OSHA-Ca (Occupational Safety & Health Administration): None of the ingredients are listed. - Toxicity: - Aquatic toxicity: 14808-60-7 Quartz (SiO2) EC50 218 mg/l (Green algae) 7757-82-6 Sodium Sulphate EC50 2,564 mg/l (Water flea) - Persistence and degradability: No further relevant information available. - Behavior in environmental systems: - Bioaccumulative potential: No further relevant information available. - Mobility in soil: No further relevant information available. - Additional ecological information: ‘ General notes: Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. - Results of PBT and vPvB assessment: - PBT: Not applicable. - VPvB: Not applicable. - Other adverse effects: No further relevant information available. - Waste treatment methods - Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Observe all federal, state and local environmental regulations when disposing of this material. - Uncleaned packaging - Recommendation: Disposal must be made according to official regulations. - Recommended cleansing agent: Water, if necessary with cleansing agents. - UN-Number: - DOT, ADR/ADN, IMDG, IATA Non-Regulated Material - UN proper shipping name: - DOT, ADR/ADN, IMDG, IATA Non-Regulated Material - Transport hazard class(es): ‘ DOT, ADR/ADN, ADN, IMDG, IATA - Class: Non-Regulated Material - Packing group: - DOT, ADR/ADN, IMDG, IATA Non-Regulated Material - Environmental hazards: Not applicable. - Special precautions for user: Not applicable. - Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable. - UN "Model Regulation": Non-Regulated Material - Safety, health and environmental regulations/legislation specific for the substance or mixture: - SARA (Superfund Amendments and Reauthorization): - Section 355 (extremely hazardous substances): None of the ingredients are listed. - Section 313 (Specific toxic chemical listings): 7727-43-7 barium sulphate, natural - TSCA (Toxic Substances Control Act): 7727-43-7 barium sulphate, natural ACTIVE 14808-60-7 Quartz (SiO2) ACTIVE 7/75/-82-6 Sodium Sulphate ACTIVE 25155-30-0 Sodium dodecylbenzenesulphonate ACTIVE 7647-14-5 Sodium Chloride ACTIVE - Hazardous Air Pollutants None of the ingredients are listed. - California Proposition 65: ‘} WARNING: This product can expose you to chemicals including the listed chemicals which are known to the State of California to cause cancer, birth defects and/or other reproductive harm. For more information, go to www.P65Warnings.ca.gov. -‘ Chemicals known to cause cancer: 14808-60-7 Quartz (SiO2) - Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. - Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed. - Chemicals known to cause developmental toxicity: None of the ingredients are listed. - New Jersey Right-to-Know List: 1/2/-43-/ barium sulphate, natural 14808-60-7 Quartz (SiO2) 25155-30-0 Sodium dodecylbenzenesulphonate - New Jersey Special Hazardous Substance List: 14808-60-7 Quartz (SiO2) CA - Pennsylvania Right-to-Know List: 1/2/-43-/ barium sulphate, natural 14808-60-7 Quartz (SiO2) 7/75/-82-6 Sodium Sulphate - Pennsylvania Special Hazardous Substance List: 7/75/-82-6 Sodium Sulphate E - Carcinogenic categories: - EPA (Environmental Protection Agency): 112/-43-7 barium sulphate, natural D, CBD(inh), NL(oral) - TLV (Threshold Limit Value established by ACGIH): 14808-60-7 Quartz (SiO2) A2 - NIOSH-Ca (National Institute for Occupational Safety and Health): 14808-60-7 Quartz (SiO2) ‘ GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). - Hazard pictograms: <7 - Signal word: Danger - Hazard-determining components of labeling: Quartz (SiO2) Almandite and Pyrope Garnet sodium dodecylbenzenesulphonate - Hazard statements: H315 Causes skin irritation. H319 Causes serious eye irritation. H350 May cause cancer. H335 May cause respiratory irritation. H3/72 Causes damage to the lung through prolonged or repeated exposure. Route of exposure: Inhalation. - Precautionary statements: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P2771 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 If on skin: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P312 Call a poison center/doctor if you feel unwell. P321 Specific treatment (see supplementary first aid instructions on this Safety Data Sheet). P314 Get medical advice/attention if you feel unwell. P362+P364 Take off contaminated clothing and wash it before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P33/7+P313 If eye irritation persists: Get medical advice/attention. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

2.1 Classification of the substance or mixture

O-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme - NFPA ratings (scale 0 - 4) Health = 2 Fire = 0 Reactivity = 0 - HMIS-ratings (scale 0 - 4) HEALTH Health = *2 FIRE 0} Fire = 0 Physical Hazard = 0 - Hazard(s) not otherwise classified (HNOC): None known - Chemical characterization: Substance - Description: Mixture of substances listed below with non-hazardous additions.