Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
>95
General Information
Version
8.1
Revision date
2020-03-07
Product name
Metz 20B Hardener
Product Synonyms
MDI methylene diisocyanate hardener
1.2.1 Relevant identified uses
Material is mixed and used in accordance with manufacturers directions
Emergency telephone
+61 0417 691 909
Icons in SDS
Company Information
company name
Metz Specialty Materials Pty Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
info@metz.net.au
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
No 1272/2008 Classification of the substance or mixture
Signal word
Danger
Hazard statements
H315 Causes skin irritation. Page 1 continued... H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. H332 Harmful if inhaled.
Prevention
P201 Obtain special instructions before use. P260 Do not breathe mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, protective clothing, eye protection and face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P264 Wash all exposed external body areas thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace.
Response
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician/first aider. P302+P352 IF ON SKIN: Wash with plenty of water and soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse.
Storage
P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Disposal
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.
2.1 Classification of the substance or mixture
[1] Category 1, Carcinogenicity Category 2, Specific Target Organ Toxicity - Single Exposure (Respiratory Tract Irritation) Category 3, Specific Target Organ Toxicity - Repeated Exposure Category 2, Acute Toxicity (Inhalation) Category 4 Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI