FRONTLINE COMBO

Merial Limited

Revision date : 2013-04-01

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GHS02 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 2
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

120068-37-3

Name of the chemical

Fipronil; 5-Amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile

Concentration

N/A

EC/CAS

64-17-5

Name of the chemical

Ethanol

Concentration

N/A

General Information

Revision date

2013-04-01

Product name

FRONTLINE COMBO

Chemical name

Mixture - NA

1.2.1 Relevant identified uses

Fipronil (10%)/S-methoprene (9%) Spot-On Solution is used in veterinary

Manufacturer Name

storage and transport of the mixture. Professional and non-professional users

Icons in SDS

Company Information

company name

Merial Limited

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H302, H313, H316, H320, H370, H372, H400

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Danger! Emergency Overview Flammable liquid and vapor. Harmful if swallowed. May be harmful in contact with skin. Causes mild skin irritation. Causes eye irritation. Causes damage to central nervous system through single or prolonged/repeated exposure. Very toxic to aquatic life. Do not eat, drink, or smoke when handling this mixture. Wash hands thoroughly after handling.

Hazard statements

R10 Flammable R21 Harmful In Contact With Skin R36 Irritating To Eyes R38 Irritating To Skin R48 Danger Of Serious Damage To Health By Prolonged Exposure R25 Toxic If Swallowed R50 Very Toxic To Aquatic Organisms

Precautionary statements

S2 Keep Out Of The Reach Of Children S7/9 Keep Container Tightly Closed And In A Well-Ventilated Place S16 Keep Away From Sources Of Ignition - No Smoking S29 Do Not Empty Into Drains S33 Take Precautionary Measures Against Static Discharges S24 Avoid Contact With Skin S28 After Contact With Skin, Wash Immediately With Plenty Of Water S25 Avoid Contact With Eyes S26 In case Of Contact With Eyes, Rinse Immediately With Plenty Of Water And Seek Medical Advice S46 If Swallowed, Seek Medical Advice Immediately And Show The Container Or Label S60 Avoid Release To The Environment The following three boxes are relevant to GHS classification and are not labeling guides.

Physical hazards

Category

2.1 Classification of the substance or mixture

Flammable liquid and Flammable liquid 3 Warning vapor (H226) Harmful if swallowed Acute Oral Toxicity 4 Warning (H302) Acute Dermal May be harmful in 5 No Symbol Warning Toxicity contact with skin (H313) Causes mild skin Dermal Irritation 3 No Symbol Warning irritation (H316) Causes eye irritation Ocular Irritation 2B No Symbol Warning (H320) SPECIFIC TARGET Causes damage to ORGAN TOXICITY – 1 Danger SINGLE EXPOSURE: organs (CNS) (H370) SPECIFIC TARGET Causes damage to ORGAN TOXICITY – organs (CNS) through 1 Danger REPEATED prolonged or repeated EXPOSURE: exposure (H372) Environmental Acute Aquatic Very toxic to aquatic life 1 Warning (H400)

Health hazards

Category

Potential health effects

The following potential human health effects are the results of the exposure to the mixture or extrapolated from the individual ingredients of the mixture. EYE: The mixture is irritating to the eyes. SKIN: The mixture produces mild skin irritation. The mixture is not anticipated to produce skin sensitization. INHALATION: The mixture is not anticipated to produce vapors in a sufficient quantity that would be irritating to eyes, skin, nose and/or throat. INGESTION: The mixture is harmful if swallowed. The following potential human health effects are the results of the exposure to the mixture or extrapolated from the individual ingredients of the mixture. SIGNS AND SYMPTOMS OF Signs and symptoms of exposure may include sweating, nausea, EXPOSURE: vomiting, headache, abdominal pain, dizziness, agitation, weakness and/or tonic-clonic seizures.

Potential chronic health

The mixture is not anticipated to be carcinogenic, mutagenic, a reproductive toxin or a developmental toxin.

Medical Conditions Generally Aggravated by Exposure

None known.

Environmental effects

Some ingredients of this mixture are very toxic to aquatic life. Avoid release to the environment.

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