Potassium dichromate solution for 1000 ml, c(K2Cr2O7) = 1/60 mol/l (0.1 N) Titrisol

SECTION 2: Hazards identification

EU Classification

CLASS regulations 2013 Oxidizing liquids (Category 2), H272 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 3), H331 Skin corrosion/irritation (Category 1B), H314 Serious eye damage/eye irritation (Category 1), H318 Respiratory sensitization (Category 1), H334 Skin sensitization (Category 1), H317 Germ cell mutagenicity (Category 1B), H340 Carcinogenicity (Category 1B), H350 Reproductive toxicity (Category 1B), H360Fd Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Specific target organ toxicity - repeated exposure (Category 2), Respiratory system, H373 Hazardous to the aquatic environment - acute hazard (Category 1), H400 Hazardous to the aquatic environment - chronic hazard (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according to CLASS regulations 2013

Signal word

Danger

Hazard statements

H272 May intensify fire; oxidizer. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H331 Toxic if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H340 May cause genetic defects. H350 May cause cancer. H360Fd May damage fertility. Suspected of damaging the unborn child. H373 May cause damage to organs (Respiratory system) through prolonged or repeated exposure. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat. P220 Keep/Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P260 Do not breathe mist or vapors. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards

- none SECTION 3: Composition and information of the ingredients of the hazardous chemical Substance / Mixture Mixture 3.2 Mixtures

Hazardous Ingredients

Component

Classifications

Concentration potassium dichromate CAS-No. 7778-50-9 Ox. Sol. 2; Acute Tox. 3; >= 5 - < 10 EC-No. 231-906-6 Acute Tox. 2; Acute Tox. % Index-No. 024-002-00-6 4; Skin Corr./Irrit. 1B; Eye Dam./Irrit. 1; Resp. Sens. 1; Skin Sens. 1; Muta. 1B; Carc. 1B; Repr. 1B; STOT SE 3; STOT RE 1; Aquatic Acute 1; Aquatic Chronic 1; H272, H301, H330, H312, H314, H318, H334, H317, H340, H350, H360Fd, H335, H372, H400, H410 Concentration limits: >= 5 %: STOT SE 3, H335; M-Factor - Aquatic Acute: 10 - Aquatic Chronic: 1 For the full text of the H-Statements mentioned in this Section, see Section 16.