Piperazine anhydrous for synthesis

Hazard statements (CLP)

H228, H314, H317, H318, H334, H361fd

Code

Statements

H228

Flammable solid

SECTION 2: Hazards identification

EU Classification

CLASS regulations 2013 Flammable solids (Category 1), H228 Skin corrosion/irritation (Category 1B), H314 Serious eye damage/eye irritation (Category 1), H318 Respiratory sensitization (Category 1), H334 Skin sensitization (Category 1), H317 Reproductive toxicity (Category 2), H361fd For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according to CLASS regulations 2013

Signal word

Danger

Hazard statements

H228 Flammable solid. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P260 Do not breathe dust. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection.

Response

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.

Storage

P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards

- none SECTION 3: Composition and information of the ingredients of the hazardous chemical