Hydroxylamine (50% solution in water) for synthesis

Hazard statements (CLP)

H290, H302, H315, H317, H318, H335, H351, H373, H400

Code

Statements

H290

May be corrosive to metals

SECTION 2: Hazards identification

Classification of the hazardous chemical Corrosive to metals Category 1 Acute toxicity (Oral) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitisation Category 1 Carcinogenicity Category 2 Specific target organ tox- icity - single exposure Category 3 (Respiratory system) Specific target organ tox- icity - repeated exposure Category 2 (Blood) Hazardous to the aquatic Category 1 environment - acute haz- ard

Signal word

Danger

Hazard statements

H290 May be corrosive to metals. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs (Blood) through prolonged or repeated exposure. H400 Very toxic to aquatic life.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P234 Keep only in original container. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this prod- uct. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be al- lowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face pro- tection. P281 Use personal protective equipment as required.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 + P310 IF IN EYES: Rinse cau- tiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physi- cian. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medi- cal advice/ attention. P362 Take off contaminated clothing and wash before reuse. P390 Absorb spillage to prevent material damage. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P406 Store in corrosive resistant container with a re- sistant inner liner.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known. SECTION 3: Composition and information of the ingredients of the hazardous chemical

2.1 Classification of the substance or mixture

Corrosive to metals : Category 1 Acute toxicity (Oral) : Category 4 Skin corrosion/irritation : Category 2 Serious eye damage/eye : Category 1 irritation Skin sensitisation : Category 1 Carcinogenicity : Category 2 Specific target organ tox- : Category 3 (Respiratory system) icity - single exposure Specific target organ tox- : Category 2 (Blood) icity - repeated exposure Hazardous to the aquatic : Category 1 environment - acute haz- ard