Cumene hydroperoxide (80% solution in cu- mene) for synthesis

Hazard statements (CLP)

H226, H242, H302+H312, H304, H314, H331, H335, H350, H373, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids : Category 3 Self-reactive substances and mixtures : Type F Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 3 Acute toxicity (Dermal) : Category 4 Skin corrosion/irritation : Category 1B Serious eye damage/eye irritation : Category 1 Carcinogenicity : Category 1B Specific target organ tox- icity - single exposure : Category 3 (Respiratory system) Specific target organ tox- icity - repeated exposure (Inhalation) : Category 2 (Lungs)

Aspiration hazard

Category 1 Hazardous to the aquatic : Category 2

Environmental hazards

- chronic hazard

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapor. H242 Heating may cause a fire. H302 + H312 Harmful if swallowed or in contact with skin. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. H350 May cause cancer. H373 May cause damage to organs (Lungs) through prolonged or repeated exposure if inhaled. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P220 Keep/Store away from clothing/ combustible ma- terials. P233 Keep container tightly closed. P234 Keep only in original container. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ light- ing/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static dis- charge. P260 Do not breathe mist or vapors. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this prod- uct. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doc- tor/ physician. P305 + P351 + P338 + P310 IF IN EYES: Rinse cau- tiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physi- cian. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemi- cal or alcohol-resistant foam for extinction. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P420 Store away from other materials.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known. SECTION 3: Composition and information of the ingredients of the hazardous chemical