Triethylaluminum solution

Merck S.A

Revision date : 2024-09-30

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GHS09 GHS07 GHS02 GHS08
Health risk rating 3
Safety risk rating 4
Environmental risk rating 5

General Information

Version

7.0

Revision date

2024-09-30

Product name

Triethylaluminum solution

REACH No

This

1.2.2. Uses advised against

For R&D use only. Not for pharmaceutical, household or other uses

Emergency telephone

+56 2 2581 4934

Icons in SDS

GHS02 GHS07 GHS08 GHS09

Company Information

company name

Merck S.A

e-mail address of the competent person responsible for the Safety Data Sheet

atencionclientes@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H250, H252, H260, H304, H314, H318, H336, H400, H410

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture Flammable liquids, (Category 2) H225: Highly flammable liquid and vapor Pyrophoric liquids, (Category 1) H250: Catches fire spontaneously if exposed to air Self-heating substances and H252: Self-heating in large quantities; may mixtures, (Category 2) catch fire Substances and mixtures which H260: In contact with water releases in contact with water emit flammable gases which may ignite flammable gases, (Category 1) spontaneously Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1A) damage Serious eye damage, (Category H318: Causes serious eye damage Specific target organ toxicity - H336: May cause drowsiness or dizziness single exposure, (Category 3), Respiratory system Aspiration hazard, (Category 1) H304: May be fatal if swallowed and enters airways Short-term (acute) aquatic H400: Very toxic to aquatic life hazard, (Category 1) Long-term (chronic) aquatic H410: Very toxic to aquatic life with long hazard, (Category 1) lasting effects

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H250 Catches fire spontaneously if exposed to air. H252 Self-heating in large quantities; may catch fire. H260 In contact with water releases flammable gases which may ignite spontaneously. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H410 Very toxic to aquatic life with long lasting effects. H250 Catches fire spontaneously if exposed to air. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Supplemental label elements

EUH014 Reacts violently with water. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Flammable liquids, (Category 2) H225: Highly flammable liquid and vapor. Pyrophoric liquids, (Category 1) H250: Catches fire spontaneously if exposed to air. Self-heating substances and H252: Self-heating in large quantities; may mixtures, (Category 2) catch fire. Substances and mixtures which H260: In contact with water releases in contact with water emit flammable gases which may ignite flammable gases, (Category 1) spontaneously. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1A) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, (Category 3), Respiratory system Aspiration hazard, (Category 1) H304: May be fatal if swallowed and enters airways. Short-term (acute) aquatic H400: Very toxic to aquatic life. hazard, (Category 1) Long-term (chronic) aquatic H410: Very toxic to aquatic life with long hazard, (Category 1) lasting effects.

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