tert-Butyl hydroperoxide solution

Merck S.A

Revision date : 2025-04-24

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GHS09 GHS06 GHS02 GHS08 GHS05
Health risk rating 5
Safety risk rating 4
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-915-7/75-91-2

Name of the chemical

tert-Butylhydroperoxid (2016/1179)

Concentration

>=50-<70

General Information

Version

7.1

Revision date

2025-04-24

Product name

tert-Butyl hydroperoxide solution

Emergency telephone

+56 2 2581 4934

Icons in SDS

GHS02 GHS05 GHS06 GHS08 GHS09

Company Information

company name

Merck S.A

e-mail address of the competent person responsible for the Safety Data Sheet

atencionclientes@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H242, H302, H304, H311, H314, H317, H318, H330, H335, H341, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture Flammable liquids, (Category 3) H226: Flammable liquid and vapor Organic peroxides, (Type D) H242: Heating may cause a fire Acute toxicity, (Category 4) H302: Harmful if swallowed Acute toxicity, (Category 2) H330: Fatal if inhaled Acute toxicity, (Category 3) H311: Toxic in contact with skin Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1C) damage Serious eye damage, (Category H318: Causes serious eye damage Skin sensitization, (Category 1) H317: May cause an allergic skin reaction Germ cell mutagenicity, H341: Suspected of causing genetic Category 2) defects Specific target organ toxicity - H335: May cause respiratory irritation single exposure, (Category 3), Respiratory system Aspiration hazard, (Category 1) H304: May be fatal if swallowed and enters airways Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects

Signal word

Danger Danger

Hazard statements

H226 Flammable liquid and vapor. H242 Heating may cause a fire. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H330 Fatal if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H411 Toxic to aquatic life with long lasting effects. Reduced Labeling (<= 125 ml) H330 Fatal if inhaled. H311 Toxic in contact with skin. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Flammable liquids, (Category 3) H226: Flammable liquid and vapor. Organic peroxides, (Type D) H242: Heating may cause a fire. Acute toxicity, (Category 4) H302: Harmful if swallowed. Acute toxicity, (Category 2) H330: Fatal if inhaled. Acute toxicity, (Category 3) H311: Toxic in contact with skin. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1C) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Skin sensitization, (Category 1) H317: May cause an allergic skin reaction. Germ cell mutagenicity, H341: Suspected of causing genetic (Category 2) defects. Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, (Category 3), Respiratory system Aspiration hazard, (Category 1) H304: May be fatal if swallowed and enters airways. Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects.

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